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Preparation of Photo-Intelligent Coating Material

Research Project

Project/Area Number 06555258
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 工業物理化学
Research InstitutionThe University of Tokyo

Principal Investigator

HASHIMOTO Kazuhito  Graduate School of Eng..Univ.of Tokyo Associate Professo, 大学院・工学系研究科, 助教授 (00172859)

Co-Investigator(Kenkyū-buntansha) SAITO Toshio  Takenaka Co..Institute of Industrial Tokyo Chief Resercher, 東京技術研究所, 副主任研究員
MURASAWA Sadao  Ishihara Sangyo Co.Institute of Function Fmterial Chief Researcher, 機能材料研究所, 主任研究員
BABA Ryo  Graduate School of Eng., Univ.of Tokyo Assistant, 大学院・工学系研究科, 助手 (70198951)
斉藤 俊夫  (株)竹中工務店, 東京技術研究所, 副主任研究員
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥14,600,000 (Direct Cost: ¥14,600,000)
Fiscal Year 1995: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 1994: ¥11,000,000 (Direct Cost: ¥11,000,000)
KeywordsPhotocatalyst / Thin film / Deodrization / Sterlization / 防汚
Research Abstract

We aimed to develop new photofunctionalized materials which posess selfcleaning, sterlization and deodorizing functions under weak UV light existing in a living environment. We previously developed such materials by coating various type of building materials such as ceramic tile, soda lime glass, paper, etc, by photoactive TiO_2 film with a thickness of less than 1mum. Based on those experiences, we studied following five topics in the present study.
1.Development of transparent TiO_2 film with higly photocatalytic activity.
2.Development of coating paint containing photoactive TiO_2 powder but stable even under UV light.
3.Development of cement material containing photoactive TiO_2 powder.
4.Characterization of surface properties of TiO_2 photocatalyst and evaluation of photocatalytic activities of the above materials.
5.Development of the methods to disperse photoactive TiO_2 powder in fluorein binder or inorganic binder.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (40 results)

All Other

All Publications (40 results)

  • [Publications] R.Wang: "Selective In-Plare Photoetectrochmical Reaction of an Azobenzone Derivative in an Assembled Film" J.Phy. Chem.99. 3352-3356 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Nagashima: "Adsorption od Anionic and Cationic Dyes in Dilute Solitions onto a SnO_2 Surface measured by Total Internal Reflection Flecores cexce" Ber. Busenges, Phys, Chem.99. 609-616 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Sakai: "Local Detection of Photoelectrochemically Produced H1O_2 with a "Wired" Horseradesh Peroxidase Microsensor" J. Phys. Chem.99. 11869-11900 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Matsubara: "Photoactine TiO_2 Contaering Paper ; Preparation and Its Photocatalytic Activity under Weak UV Light Illuminotion" Chem.Lett.767-768 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Hashimoto: "Structural Analysis of a Diamond Filn Grown ox a Spectroscopy" J. Eletroanal. Chem.397. 339-341 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] I. Sopyan: "Effident TiO_2 Powder and Film photocatalysts with Ratile Crystal Structure" Chem.Lett.69-70 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] R.Wang: "Selective in-Plane Photoelectrochemical Reaction of an Azobenzene Derivative in an Assembled Film" J.Phy.Chem. 99 (10). 3352-3356 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Nakashima: "Adsorption of Anionic and Cationic Dyes in Dilute Solutions onto a SnO_2 Surface Measured by Total Intemal Reflection Fluorescence" Ber.Bunsenges.Phys.Chem.99 (4). 609-616 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Sakai: "Local Detection of Photoelectrochemically Produced H_2O_2 with a "Wired" Horseradish Peroxidase Microsensor" J.Phys.Chem.99 (31). 11869-11900 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Matsubara: "Photoactive TiO_2 Containing Paper : Preparation and Its Photocatalytic Activity under Weak UV Light Illumination" Chem.Lett.767-768 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Kawasaki: "Imaging of One-Dimensionla Conducting Pt Complexes Using Atomic Force Microscopy" Chem.Lett.879-880 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Morigaki: "Azobenzene-Derivative Langmuir-Blodgett Films Deposited on Vorious Thiol Monolayrs" J.Phys.Chem.99 (4). 14771-14777 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Ikeda: "Microscopic Observation of Photocatalytic Reaction Using Microelectrode : Special Resolution for Reaction Products Distribution" Chem.Lett.979-980 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K Ajito: "Study of the Photochromic Properties of Amorphous MoO_3 Films Using Raman Microscopy" J.Phys.Chem.99 (44). 16383-16388 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Hashimoto: "Structural Analysis of a Diamond Film Grown on a Spectroscopy" J.Electroanal.Chem.397. 229-341 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] I.Sopyan: "Efficient TiO_2 Powder and Film Photocatalysts with Rutile Crystal Structure" Chem.Lett.69-70 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] J.F.Zhi: "Photoelectrochromic Properties of a Spirobenzopyran Derivative" J.Photochem.Photobiol.A : Chem.92. 91-97 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] R. Wang and A. Fujishima etc.: "Selective In-Plane Photoelectrochemical Reaction of an Azobenzene Derivative in an Assembled Film" The Journal of Physical Chemistry. 99(10). 3352-3356 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Sakai and A. Fujishima etc.: "Local Detection of Photoelectrochemically Produced H2O2 with a "Wired" Horseradish Peroxidase Microsensor" The Journal of Physical Chemistry. 99(31). 11896-11900 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Matsubara and A. Fujishima etc.: "Photoactive TiO2 Containing Paper: Preparation and Its Photocatalytic Activity under Weak UV Light Illumination" Chemistry Letters. 767-768 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Kawasaki and A. Fujishima etc.: "Imaging of One-Dimensional Conducting Pt Complexes Using Atomic Force Microscopy" Chemistry Letters. 879-880 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Morigaki and A. Fujishima etc.: "Azobenzene-Derivative Langmuir-Blodgett Films Deposited on Various Thiol Monolayers" The Journal of Physical Chemistry. 99(40). 14771-14777 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Ikeda and A. Fujishima etc.: "Microscopic Observation of Photocatalytic Reaction Using Microelectrode: Special Resolution for Reaction Products Distribution" Chemistry Letters. 979-980 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Ajito and A. Fujishima etc.: "Study of the Photochromic Properties of Amorphous MoO3 Films Using Raman Microscopy" The Journal of Physical Chemistry. 99(44). 16383-16388 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Hashimoto and A. Fujishima etc.: "Structural Analysis of a Diamond Film Grown on a Photoelectrochemically Etched Silicon Substrate by Micro-Raman Spectroscopy" J. Electroanal. Chem.397. 339-341 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I. Sopyan and A. Fujishima etc.: "Efficient TiO2 Powder and Film Photocatalysts with Rutile Crystal Structure" Chemistry Letters. 69-70 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] J. F. Zhi and A. Fujishima etc.: "Photoelectrochromic Properties of a Spirobenzopyran Derivative" Journal of Photochemistry and Photobiology A: Chemistry. 92. 91-97 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] R. Wang and A. Fujishima etc.: "Polarized Photoelectrochemical Reaction of an Azobenzene Derivative in Langmuir-Blodgett Films" Journal of Photochemistry and Photobiology A: Chemistry. 92. 111-116 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials:--Part 4.Electrochemical Behavior of the Pd Electrode in Aqueous and Nonaqueous Electrolyte" J.Electroanal.Chem.369. 247-250 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Fujishima: "Thin Semiconductor Films:Photoeffects and New Applications" Electrochem.Acta. 39. 1229-1236 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Yoshiki: "Electroless Copper Plating Using ZnO Thin Film Coated on a Glass Substrate" J.Electrochem.Soc.141. L56-L58 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Yano: "Observation and Surfaces Modification of Electropolymerized Poly(N-Methylpyrrole) Using Atomic Force Microscopy" J.Vac.Sci.Technol.B,. 12. 1596-1599 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] L.A.Nagahara: "Mica Etch Pits as a Height Calibration Source for Atomic Force Microscopy" J.Vac.Sci.Technol.B,. 12. 1694-1697 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] O.Sato: "A Novel Approach to the Polydiacetylene Langmuir-Blodegett Film by the Surface-Specific Optical Third Harmonic Generation Based on the Angular Momentum Conservation Rule" J.Electroanal.Chem.372. 279-281 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Jin-Fang Zhi: "Conjugated Molecular System of Photochromism and Electrochromism.Photoelectrochemical Behavier of Nitrospirobenzopyran at Low Temperature" Chem.Lett.1521-1524 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] L.Jiang: "Surface Photovoltage Spectroscopy and Mapping by Atomic Force Microscopy" Chem.Lett.1975-1978 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] X.M.Yang: "In Situ Observation of the Au-Hg Alloy Formation on a Gold Electrode Surface by Atomic Force Microscopy" Chem.Lett.2059-2062 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Saeki: "Electrochemical Reduction of Liquid CO_2.---Drastic Enhancement of Current Density---" J.Electrochem.Soc.141. L130-L132 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Sakai,: "Intracellular Ca^<2+> Concentration Change of T24 Cell Under Irradiation in the Presence of TiO_2 Ultrafine Particles" Biochim.Biophys.Acta. 1201. 259-265 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Sakai.: "Separate Monitoring of Reaction Products Formed at Oxidation and Reduction Sites of TiO_2 Photocatalysts Using a Microelectrode" J.Electroanal.Chem.379. 199-205 (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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