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Preparation of high performance pitch based carbon fiber by controling spinning and carbonization conclitious

Research Project

Project/Area Number 06555275
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field 有機工業化学
Research InstitutionKYUSHU UNIVERSITIY

Principal Investigator

MOCHIDA Isao  Institute of Advanced Matcrial Sutudy, Professor, 機能物質科学研究所, 教授 (20037758)

Co-Investigator(Kenkyū-buntansha) TOSHIMA Hiroshi  Tonenn INC., Total Study Student, 総合研究所, 研究員
TAKASHIMA Hiroaki  Nihon Sekiyu INC., Center Study, Ldader, 中央研究所, 室長
SAKANISHI Kinya  Institute of Advanced Material Sutudy, kyushu University, Assistent, 機能物質科学研究所, 助手 (60183365)
KORAI Yozo  Institute of Advanced Material Study, kyushu University, Assistent Professor, 機能物質科学研究所, 助教授 (50122693)
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,000,000 (Direct Cost: ¥7,000,000)
Fiscal Year 1996: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1995: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1994: ¥4,500,000 (Direct Cost: ¥4,500,000)
KeywordsPitch / caron fiber / mesophase pitch / orientation / modulus / strength / micro-texture / graphite fiber / 紡糸 / マイクロドメイン / 黒鉛化性 / 結晶性 / 炭化 / Die Swell / ノズル
Research Abstract

Mesophase pitch has been successfully prepared at very highly yield from aromatic hydroearbons with low contaminant levels using HF/BF_3 as a catalyst. The derived carbon fiber is expected to be of high performance and to be produced at reasonable cost. The synthesis, structure, and properties of the mesophase pitchs, which are strongly dependent upon the starting aromatic hydrocarbons and preparation conditions, will be described. The spinning process can control the shape and texture of the fiber, both of which are intimately related to performance. Fibers with a flat cross section, as thin as 1.5 micrometer, and round fibers with random texture can be produced when the spinning nozzle and the mesophase pitch are properly selected. Acceptable compression strength has been obtained with the ranbdomtexture in the round realized by slow heating during stabilization. Some other applications of mesophase pitch can be addressed.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] R.Fujita,T.Kojima,M.Komatsu and I.Mochida: "Mechanical properties of binderless carbon mould prepared from heat-treated mesophase pitch of contrllled grain size" Carbon. 33・8. 1061-1068 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.H.Yoon,Y.Korai,I.Mochida,K.Yanagida,S.Fukuyama and M.Yoshimura: "Axial nano scale microstructures ingraphitized fibers inherited from liquid crystal meshophase pitch" Carbon. 34・1. 83-88 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] I.Mochida,K.H.An,K.sakanishi,Y.Korai: "Preparation of Nitrogen-rich Pitches from Diazanaphtalenes Using AlC3" Carbon. 34・5. 601-608 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] I.Mochida,S.H.Yoon,N.Takano,F.Fprtin,Y.Korai and K.Yokogawa: "Microstructure of Mesophase Pitch-based Carbon Fiber and its Control" Carbon. 34・8. 941-956 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Korai,Y.G.Wang,S.H.Yoon,S.Ishida and I.Mochida: "Preparation of Meso-carbon microbeads with uniform diameter from AR isotropic pitch in the presence" Carbon. 34・9. 1156-1159 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Korai,S.Ishida,S.H.Yoon,Y-G.Wang,I.Mochida,Y.Nakagawa,Y.Sakai and M.Komatsu: "Efficient Preparation of Meso-Carbon Microbeads from Synthetic Isotropic Pitch Derived from Naphthal" Carbon. 34・12. 1569-1576 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] R.Fujiura, T.Kojima, M.Komatsu, and I.Mochida: "Mechanical properties of binderless carbon mold prepared from head-treated mesophase pitch of controlled grain sizo" Carbon. Vol.33, No.8. 1061-1068 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S-H.Yoon, Y.Korai, I.mochida, K.Yokogawa, S.Fukuyama and M.Yoshimura: "Axial nano-scale microstructures in graohitized fibers inherited from liquid crystal mesophase pitch" Carbon. Vol.34, No.1. 83-88 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] I.Mochida, K.H.An.K.Sakanish and Y.Korai: "Preparation of Nitrogen-rich Pitches from Diazanaphathalcnes Using AICI_3" Carbon. Vol.34, No.5. 601-608 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] I.Mochida, S-H.Yoon, N.Takano, F.fortin, Y.Korai and K.yokogawa: "Microstructure of Mesophase Ptich-based Carbon Fiber and its Control" Carbon. Vol.34, No.8. 941-956 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Korai, Y-G.wang, S-H.Yoon, S.Ishida and I.mochida: "Preparation of meso-carbon microbeads with uniform diameter from AR-isotropic pitch in the prescnce of carvon black" Carbon. Vol.34, No.9. 1156-1159 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Korai, S.Ishida, S-H.Yoon, Y-G.WAng, I.Mochida, Y.Nakagawa, Y.Sakai and M.Komatsu: "Efficient of Meso-Carbon Microbeads from Synthetic Isotropic Pitch Derived from Naphthalene" Carbon. Vol.34, No.12. 1569-1576 (1966)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] R.Fujita,T.Kojima,M.Komatsu and I.Mochida: "Mechanical properties of binderless carbom mould prepared from heat-treated mesophase pitch of contrllled grain size" Carbon. 33. 1061-1068 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.H.Yoon,Y.Korai,I.Mochida,K.Yanagida,S.Fukuyama and M.Yoshimura: "Axial nano-scale microstructures ingraphitized fibers inherited from liquid crystal meshophase pitch" Carbon. 3. 83-88 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I.Mochida,K.H.An,K.sakanishi,Y.Korai: "Preparation of Nitrogen-rich Pitches from Diazanaphtalenes Using AlC3" Carbon. 34. 601-608 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I.Mochida,S.H.Yoon,N.Takano,F.Fprtin,Y.Korai and K.Yokogawa: "Microstructure of Mesophase Pitch-based Carbon Fiber and its Control" Carbon. 34. 941-956 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Korai,Y-G.Wang,S-H.Yoon,S.Ishida and I.Mochida: "Preparation of Meso-carbon microbeads with uniform diameter from AR isotropic pitch in the presence" Carbon. 34. 1156-1159 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Korai,S.Ishida,S-H.Yoon,Y-G.Wang,I.Mochida,Y.Nakagawa,Y.Sakai and M.Komatsu: "Efficient Preparation of Meso-Carbon Microbeads from Synthetic Isotropic Pitch Derived from Naphthal" Carbon. 34. 1569-1576 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.-H.Yoon,Y.Korai,I.Mochida: "Assessment and optimization of the stabilization process of mesophase pitch fibers by thermal analyses" Carbon. 32. 281-287 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.E.Yoon,E.S.Lee,Y.Korai,I.Mochida,K.Yanagida,K.Take: "Comparison of mesophase pitches derived from C8 and C9 aromatic hydrocarbons" Carbon. 32. 453-459 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] F.Fortin,S.-H.Yoon,Y.Korai,I.Mochida: "Reorganization of molecular alignment in naphthalene and methyl-naphthalene derived pitches" Carbon. 32. 979-989 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.-H.Yoon,Y.Korai,I.Mochida,: "Pleat structure of the mesophase pitch-based carbon fiber" Carbon. 32. 1182-1185 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] I.Mochida,K.H.An.Y.Korai: "Preparation of nitrogen containing pitches from quinoline and isoquinoline by aid of AlCl_3" Carbon. 33. 1069-1077 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I.Mochida,K.H.An,Y.Korai: "Catalytic condensation of isoquinoline into pitch in higher yield in the presence of nitro solvents" Carbon. 33. 1079-1084 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I.Mochida,S.-H.Yoon,Y.Korai,K.Kanno,Y.Sakai,M.Komatsu: "Chemtech" Carbon fibers from aromatic hydrocarbons, 29-37 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Isao Mochida,Seong-Ho Yoon,Yozo Korai: "Preparation and Structure of Mesophase Pitch Based Thin Carbon Tape" J.Mater.Sci.28. 2135-2142 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] Isao Mochida,Seong-Ho Yoon,Yozo Korai: "Control of Transversal Texture in Circular Mesophase Pitch Based Carbon Fiber Using Circular Spinning Nozzles" J.Mater.Sci.28. 2331-2342 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] Seong-Ho Yoon,Yozo Korai,Isao Mochida: "Spinng Characteristics of Mesophase Pitches Derived from Naphthalene and Methylnaphthalene with HF/BF3" Carbon. 31. 849-863 (1992)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.Sakanishi,X.Ma,I.Mochida: "Three Step Deep Hydrodesulfurization of Diesel Fuel under 30kg/cm2 H2 Pressure without Color Development" Sekkiyu Gakkaishi. 36. 145-151 (1993)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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