• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of DeNO_x Catalysts for Diesel Engine Exhaust

Research Project

Project/Area Number 06558082
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field 環境保全
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

IWAMOTO Masakazu  Hokkaido Univ., Catalysis Research Center, Prof., 触媒化学研究センター, 教授 (10108342)

Co-Investigator(Kenkyū-buntansha) SHIMODA Masatoshi  Hino Motors, Ltd.Technical Research Laboratory, Chief (Research and Development), 技術研究所, 主管(研究開発担当)
MUKAI Kousaburo  Nissan Motor Co., Ltd.Central Research Laboratory, Chief Engineer, 中央研究所, 主任研究員
TANAKA Yasuhiro  Hokkaido Univ., Catalysis Research Center, Instructor, 触媒化学研究センター, 助手 (90281849)
ABE Takayuki  Hokkaido Univ., Catalysis Research Center, Ass.Prof., 触媒化学研究センター, 助教授 (90241546)
水野 哲孝  東京大学, 生産技術研究所, 助教授 (50181904)
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 1996: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1995: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 1994: ¥9,000,000 (Direct Cost: ¥9,000,000)
KeywordsEnvironmental Chemistry / Nitrogen Oxides / Zeolite / Acid Rain / Selective Reduction / Cu / Pt
Research Abstract

This study has been devoted to 1) collection of fundamental data for applying the selective catalytic reduction of NO with hydrocarbons, 2) clarification of the reaction mechanism, and 3) relation between NO_2 formation and catalytic activity for the eduction of NO.
1) Pt-ZSM-5 showed the highest catalytic activity for the conversion of NO into N_2 among various catalysts in H_2O and SO_2 at low temperature. Pt-ZSM-5 showed high durability during the continuous service of 1000 h in H_2O and SO_2.
2)The formation of N_2 in the selective catalytic reduction of NO over Cu-ZSM-5 was clarified to proceed through the reaction of NO+O_2 with surface adsorbates of C_2H_4. The redox properties of Cu ions in Cu-ZSM-5 were greatly dependent on the oxidation or evacuation temperature. In addition, it followed that there were three kinds of Cu^+ species with different adsorption properties in Cu-ZSM-5.
3) To divide the consecutive reactions of NO oxidation and NO_2 reduction, two reactors were used and hydrocarbons as reactant were introduced between them (IAR method). It was confirmed that this method was very effective for the selective reduction of NO when Pt- and In- catalysts were applied in the first and second reactor, respectively.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (130 results)

All Other

All Publications (130 results)

  • [Publications] N. Mizuno: "Amination of 2-Methylpropene over Proton-Exchanged ZSM-5 Zeolite Catalysts" J. Catal.146. 249-256 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Synthesis of [PW_9O_<37>{Fe_<3-X>Ni_X(OA_c)_3}]^<(9+X)->(x=predominantly 1) and Oxidation Catalysis by the Catalyst Precursor" J. Mol. Catal.88. L125-L131 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Highly Selective Epoxidation of Olefins on Mono-Trasition-Metal-Substituted Keggin-Type Heteropolytungstates by Molecular Oxygen in the Presence of Aldehyde" Stud. Sur. Sci. Catal.82. 593-601 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. Mori: "Active sites for Isotopic Exchange of Oxygen between Proton-Exchanged ZSM-5 Zeolites and Water" J. Chem. Soc., Chem. Commun.975-976 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 張文祥: "破過曲線の解析による金属イオン交換ゼオライト中のNOの有効拡散計数の測定" 日本化学会誌. 8. 748-751 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Direct Oxidation of Isobutane into Methacrylic Acid and Methacrolein over Cs_<2.5>Ni_<0.08->substituted H_3PMo_<12>O_<40>" J. Chem. Soc., Chem. Commun.1411-1412 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Direct Amination of Lower Alkenes with Ammonia over Zeolite Catalysts" Stud. Sur. Sci. Catal.90. 71-76 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] W. -X. Zhang: "Removal of Nitrogen Monoxide by Pressure Swing Adsorption on Metal Ion-Exchanged Zeolites" Trans. Mat. Res. Soc. Jpn.18A. 401-404 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. Yahiro: "Selective Catalytic Reduction of Nitrogen Monoxide by Hydrocarbon on Platinum-Zeolite" Trans. Mat. Res. Soc. Jpn.18A. 409-412 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Enhancement of Catalytic Activity of Cs_<2.5>Ni_<0.08>H_<0.34>PMo_<12>O_<40> by V^<5+>-substitution for Oxidation of Isobutane into Methacrylic Acid" Appl. Catal. A. 118. L1-L4 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Performance and Durability of Pt-MFI Zeolite Catalyst for Selective Reduction of Nitrogen Monoxide in Actual Diesel Engine Exhaust" Appl. Catal. B. 5. L1-L6 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. K. Chen: "Voltammetry of Adenosine after Electrochemical Treatment of Carbon-Fiber Electrodes" Electroanalysis. 6. 746-751 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. Abe: "Total Inhibition of the Oxygen Reduction Reaction at Au(111) by Copper Adlayers in Sulfuric Acid Solution" Bull. Chem. Soc, Jpn.67. 2075-2078 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 郭建威: "白金ZSM-5触媒のディーゼル排気中NO_X還元特性に関する研究" 自動車技術会論文集. 941. 221-224 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Time-Resolved FT-IR Study on Isotopic Exchange of Dinitrosyl Species Strongly Adsorbed on a Co-MFI Zeolite" Chem. Lett.729-730 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. Abe: "Non-Silica-Based Mesostructured Materials. 1. Synthesis of Vanadium Oxide-Based Materials" Chem. Mater.7. 1429-1430 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. Abe: "Preparation and Characterization of Fe_2O_3 Nanoparticles in Mesoporous Silicate" J. Chem. Soc., Chem. Commun.1617-1618 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J. Guo: "NO_X Reduction Characteristics of Pt-ZSM-5 Catalyst with Diesel Engine Exhaust" JSAE Review. 16. 21-25 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] W. X. Zhang: "Reversible and Irreversible Adsorption of Nitrogen Monoxide on Cobalt Ion-Exchanged ZSM-5 and Mordenite Zeolites at 273-523 K" J. Chem. Soc., Faraday Trans.91. 767-771 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. K. Shin: "Selective Catalytic Reduction of NO by Ethene in Excess Oxygen over Platinum Ion-Exchanged MFI Zeolites" Catal. Today. 26. 13-21 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Pronounced Catalytic Activity of Fe_<0.08>Cs_<2.5>H_<1.26>PVMo_<11>O_<40> for Direct Oxidation of Propane into Acrylic acid" Appl. Catal. A. 128. L165-L170 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. Abe: "Effect of Underpotential Deposition (UPD) of Copper on Oxygen Reduction at Pt(111) Surfaces" J. Electroanal. Chem.382. 73-83 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Pulse Study on Reactivity of Ethene Adsorbed on Cu-MFI with Nitrogen Oxides and Oxygen" Catal. Today. 27. 71-78 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. Takeda: "Reaction of Adsorbates Derived from Cyanuric Acid on a Cu-MFI Zeolite with Nitrogen Oxide and Oxygen" Catal. Lett.38. 21-25 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y. Hoshino: "Assignment of the 2177cm^<-7> Absorption Band Appearing upon Admission of CO on a Copper Ion-exchanged MFI Zeolite" Chem. Lett.631-632 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. Takeda: "Remarkable Difference between the Kinetic Parameters of a Selective Catalytic Reduction of NO by Ethene on a Copper Ion-Exchanged MFI Zeolite and Al_2O_3" Bull. Chem. Soc. Jpn.69. 2735-2738 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Mizuno: "Direct Oxidation of Isobutane into Methacrylic Acid over Cs, Ni, and V-substituted H_3PMo_<12>O_<40> Heteropoly Compounds" Stud. Sur. Sci. Catal.101. 1001-1010 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Assignment of Nonclassical [Cu(CO)_n]^+(n=1,2) Complex Ions in Zeolite Cages" Inorg. Chem.35. 6918-6921 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Hatanaka: "Single-Step Synthesis of Cyclopentenones from (3-Alkoxycarbonyl-2-oxopropylidene) triphenylphosphorane and 1,2-Diacylethylenes" Tetrahedron Lett.37. 401-404 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y. Tanaka: "Synthesis and Reactions of Ethyl 6-Aryl-3-ethoxy-6-oxo-2,4-hexadienoates" Chem. Pharm. Bull.44. 885-891 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Zeolites in Environmental Catalysis" Stud. Surf. Sci. Catal.84. 1395-1410 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Novel Catalytic Decomposition and Reduction of NO" Catal. Today. 22. 5-18 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "ゼオライトを用いるNOの接触除去" 化学総説. 21. 127-136 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 八尋秀典: "金属イオン交換ゼオライト上でのNOの選択還元" 化学工学シンポジウムシリーズ. 42. 95-104 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Metal Ion-Exchanged Zeolites as Highly Active Materials for Removal of Nitrogen Monoxide by Catalytic Decomposition, Selective Catalytic Reduction, or Adsorption" Trans. Mat. Res. Soc. Jpn.15A. 117-122 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "ゼオライト触媒によるNOx除去" 触媒. 37. 614-622 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "リーンバーンでのNOの選択的還元除去" ペトロテック. 18. 850-851 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 八尋秀典: "金属イオン交換ゼオライトによるNOの吸着除去" 表面. 33. 698-709 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Heterogeneous Catalysis for Removal of NO in Excess Oxygen Progress in 1994" Catal. Today. 29. 29-35 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "メゾスコピック多孔体の化学" ニューセラミックス. 9(10). 1-8 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "炭化水素によるNOの選択的接触還元反応の諸問題" 化学. 51. 204-205 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N. Nojiri: "Global Overview of Catalysis" Appl. Catal. A. 145. 419-428 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "セラミックデータブック" 工業製品技術協会, 334 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Catal. Today, 22" Elsevier, 169 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "エネルギーと地球環境" 日刊工業新聞社会, 195 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 岩本正和: "環境触媒" 共立出版, 219 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, M.Tabata, T.Uematsu andM.Iwamoto: "Amination of 2-Methylpropene over Proton-Exchanged ZSM-5 Zeolite Catalysts" J.Catal.146. 249-256 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, T.Hirose, M.Tateishi and M.Iwamoto: "Synthesis of [PW_9O_<37>{Fe_<3-X>Ni_X(OA_c)_3}]^<(9+X)-> (x=predominantly) and Oxidation Catalysis by the Catalyst Precursor" J.Mol.Catal.88. L125-L131 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, T.Hirose, M.Iwamoto: "Highly Selective Epoxidation of Olefins on Mono-Trasition-Metal-Substituted Keggin-Type Heteropolytungstates by Molecular Oxygen in the Presence of Aldehyde" Stud.Sur.Sci.Catal.82. 593-601 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Mori, K.Mineo, N.Mizuno and M.Iwamoto: "Active sites for Isotopic Exchange of Oxygen between Proton-Exchanged ZSM-5 Zeolites and Water" J.Chem.Soc., Chem.Commun.975-976 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] W.-X.Zhang, H.Yahiro, J.Izumi and M.Iwamoto: "Measurement of Intraparticle Effective Diffusion Coefficient of NO in Metal Ion-Exchanged Zeolites by Analysis of Breakthrough Curves" Nihon Kagakukaishi. (8). 748-751 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, M.Tateishi and M.Iwamoto: "Direct Oxidation of Isobutane into Methacrylic Acid and Methacrolein over Cs_<2.5> Ni_<0.08>-substituted H_3PMo_<12>O_<40>" J.Chem.Soc.Chem.Commun.1411-1412 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, M.Tabata, T.Uematsu and M.Iwamoto: "Direct Amination of Lower Alkenes with Ammonia over Zeolite Catalysts" Stud.Sur.Sci.Catal.90. 71-76 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] W.X.Zhang, H.Yahiro, N.Mizuno, J.Izumi and M.Iwamoto: "Removal of Nitrogen Monoxide by Pressure Swing Adsorption on Metal Ion-Exchanged Zeolites" Trans.Mat.Res.Soc.Jpn.18A. 401-404 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Yahiro, H.Hirabayashi, H.K.Shin, N.Mizuno and M.Iwamoto: "Selective Catalytic Reduction of Nitrogen Monoxide by Hydrocarbon on Platinum-Zeolite" Trans.Mat.Res.Soc.Jpn.18A. 409-412 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, M.Tateishi and M.Iwamoto: "Enhancement of Catalytic Activity of Cs_<2.5>Ni_<0.08>H_<0.34>PMo_<12>O_<40> by V^<5+>-substitution for Oxidation of Isobutane into Methacrylic Acid" Appl.Catal.A. 118. L1-L4 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto, H.Yahiro, H.K.Shin, M.Watanabe, J.Guo, M.Konno, T.Chikahisa and T.Murayama: "Performance and Durability of Pt-MFI Zeolite Catalyst for Selective Reduction of Nitrogen Monoxide in Actual Diesel Engine Exhaust" Appl.Catal.B.5. L1-L6 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.K.Chen, T.G.Strein, T.Abe and A.G.Ewing: "Voltammetry of Adenosine after Electrochemical Treatment of Carbon-Fiber Electrodes" Electroanalysis. 6. 746-751 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Abe, Y.Miki and K.Itaya: "Total Inhibition of the Oxygen Reduction Reaction at Au (III) by Copper Adlayrs in Sulfuric Acid Solution" Bull.Chem.Soc, Jpn.67. 2075-2078 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Guo, M.Konno, T.Chikahisa, T.Murayama and M.Iwamoto: "Removal of Nitrogen Oxides over Pt-ZSM-5 Catalyst in Diesel Engine Exhaust" Jidousya Gijyutsu-kai Ronbunsyu. 941. 221-224 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto and Y.Hoshino: "Time-Resolved FT-IR Study on Isotopic Exchange of Dinitrosyl Species Strongly Adsorbed on a Co-MFI Zeolite" Chem.Lett.729-730 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Abe, A.Taguchi and M.Iwamoto: "Non-Silica-Based Mesostructured Materials. 1. Synthesis of Vanadium Oxide-Based Materials" Chem.Mater.7. 1429-1430 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Abe, Y.Tachibana, T.Uematsu and M.Iwamoto: "Preparation and Characterization of Fe_2O_3 Nanoparticles in Mesoporous Silicate" J.Chem.Soc., Chem.Commun.1617-1618 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Guo, M.Konno, T.Chikahisa, T.Murayama and M.Iwamoto: "NOx Reduction Characteristics of Pt-ZSM-5 Catalyst with Diesel Engine Exhaust" JSAE Review. 16. 21-25 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] W.X.Zhang, H.Yahiro and M.Iwamoto: "Reversible and Irreversible Adsorption of Nitrogen Monoxide on Cobalt Ion- Exchanged ZSM-5 and Mordenite Zeolites at 273-523 K" J.Chem.Soc., Faraday Trans. 91. 767-771 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.K.Shin, H.Hirabayashi, H.Yahiro, M.Watanabe and M.Iwamoto: "Selective Catalytic Reduction of NO by Ethene in Excess Oxygen over Platinum Ion-Exchanged MFI Zeolites" Catal.Today. 26. 13-21 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, M.Tateishi and M.Iwamoto: "Pronounced Catalytic Activity of Fe_<0.08>Cs_<2.5>H_<1.26>PVMo_<11>O_<40> for Direct Oxidation of Propane into Acrylic acid" Appl.Catal.A. 128. L165-L170 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Abe, G.M.Swain, K.Sashikata and K.Itaya: "Effect of Underpotential Deposition (UPD) of Copper on Oxygen Reduction at Pt (111) Surfaces" J.Electroanal.Chem.382. 73-83 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto and H.Takeda: "Pulse Study on Reactivity of Ethene Adsorbed on Cu-MFI with Nitrogen Oxides and Oxygen" Catal.Today. 27. 71-78 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takeda and M.Iwamoto: "Reaction of Adsorbates Derived from Cyanuric Acid on a Cu-MFI Zeolite with Nitrogen Oxide and Oxygen" Catal.Lett.38. 21-25 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Hoshino and M.Iwamoto: "Assignment of the 2177 cm^<-1> Absorption Band Appearing upon Admission of CO on a Copper Ion-exchanged MFI Zeolite" Chem.Lett.631-632 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takeda and M.Iwamoto: "Remarkable Difference between the Kinetic Parameters of a Selective Catalytic Reduction of NO by Ethene on a Copper Ion-Exchanged MFI Zeolite and Al_2O_3" Bull.Chem.Soc.Jpn.69. 2735-2738 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Mizuno, W.Han, T.Kudo and M.Iwamoto: "Direct Oxidation of Isobutane into Methacrylic Acid over Cs, Ni, and V-substituted H_3PMo_<12>O_<40> Heteropoly Compounds" Stud.Sur.Sci.Catal.101. 1001-1010 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto and Y.Hoshino: "Assignment of Nonclassical [Cu(CO)_n]^+ (n=1,2) Complex Ions in Zeolite Cages" Inorg.Chem.35. 6918-6921 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Hatanaka, A.Ishida, Y.Tanaka and I.Ueda: "Single-Step Synthesis of Cyclopentenones from (3-Alkoxycarbonyl-2-oxopropylidene) triphenyl-phosphorane and 1,2-Diacylethylenes" Tetrahedron Lett.37. 401-404 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Tanaka, T.Kawano, S.M.Islam, H.Nishioka and I.Ueda: "Synthesis and Reactions of Ethyl 6-Aryl-3-ethoxy-6-oxo-2,4-hexadienoates" Chem.Pharm.Bull.44. 885-891 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: "Zeolites in Environmental Catalysis" Stud.Surf.Sci.Catal.84. 1395-1410 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto and H.Yahiro: "Novel Catalytic Decomposition and Reduction of NO" Catal.Today. 22. 5-18 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto, H.Yahiro: "Removal of Nitrogen Monoxide over Zeolite Catalysts" Kagaku Sousetsu. 21. 127-136 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Yahiro and M.Iwamoto: "Selective Catalytic Reduction of Nitrogen Monoxide over Metal Ion-Exchanged Zeolites" Kagaku Kougaku Symposium Series. 42. 95-104 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: "Metal Ion-Exchanged Zeolites as Highly Active Materials for Removal of Nitrogen Monoxide by Catalytic Decomposition, Selective Catalytic Reduction, or Adsorption" Trans.Mat.Res.Soc.Jpn.15A. 117-122 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: "Removal of Nitrogen Monoxide on Zeolite Catalysts" Shokubai. 37. 614-622 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: "Removal of Nitrogen Monoxide by Selective Catalytic Reduction in Lean-Burn Exhaust" Petrotech. 18. 850-851 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Yahiro and M.Iwamoto: "Removal of Nitrogen Monoxide by Adsorption on Metal Ion-Exchanged Zeolites" Hyoumen. 33. 698-709 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: "Heterogeneous Catalysis for Removal of NO in Excess Oxygen Progress in 1994" Catal.Today. 29. 29-35 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: "Chemistry of Mesoscopic Porous Materials" New Ceramics. 9(10). 1-8 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto and H.Yahiro: "Recent Studies on Selective Catalytic Reduction of Nitrogen Monoxide by Hydrocarbons" Kagaku. 51. 204-205 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Nojiri and M.Iwamoto: "Clobal Overview of Catalysis" Appl.Catal.A. 145. 419-428 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: New Catalytic System for Removal of Nitrogen Oxides Ceramic Data Book. Kougyou Seihin Gijyutsu Kyoukai, 334 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: Recent Progress in Novel Catalytic Removal of Nitrogen Monoxide. Catal.Today, 22, Elsevier, 169 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: Environmental Problems on the Earth and Diesel Engine Exhaust Emission Control Enerugi to Chikyu Kankyo. Nikkan Kougyou Shinbunsya, 195 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Iwamoto: Catalysts for Automobile Exhaust Gas Kankyo Shokubai. Kyouritsu Shuppan, 219 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Iwamoto: "Pulse Study on Reactivity of Ethene Adsorbed on Cu-MFI with Nitrogen Oxides and Oxygen" Catal. Today. 27. 71-78 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Takeda: "Reaction of adsorbates Derived from Cyanuric Acid on a Cu-MFI Zeolite with Nitrogen Oxide and Oxygen" Catal. Lett.38. 21-25 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Iwamoto: "Heterogeneous Catalysis for Removal of NO in Excess Oxygen Progress in 1994" Catal. Today. 29. 29-35 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Takeda: "Remarkable Difference between the Kinetic Parameters of a Selective Catalytic Reduction of NO by Ethene on a Copper Ion-Exchanged MFI Zeolite and Al_2O_3" Bull. Chem. Soc. Jpn.69. 2735-2738 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N. Mizuno: "Direct Oxidation of Isobutane into Methacrylic Acid over Cs NI, and V-substituted H_3PMo_<12>O_<40> Heteropoly Compounds" Studies in Surface and Catalysis. 101. 1001-1010 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Iwamoto: "Assignment of Nonclassical [Cu (CO) n] + (n=1, 2) Complex Ions in Zeolite Cages" Inorg. Chem.35. 1918-1921 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N. Nojiri: "Global Overview of Catalysis" Appl. catal. A. general. 419-428 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "窒素酸化物除去触媒の現状と課題" ケミカルエンジニヤリング. 1. 51-56 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "メゾスコピック多孔体の化学" ニューセラミックス. 9. 1-8 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "炭化水素によるNOの選択的還元反応の諸問題" 化学. 64-65 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y. Tanaka: "Synthesis and Reactions of Ethyl 6-Aryl-3-ethoxy-6-oxo-2, 4-hexadienoates" Chem. Pharm. Bull.44. 885-891 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M, Hatanaka: "Single-Step Synthesis of Cyclopentenounes from (3-Alkoxycarbonyl-2-oxopropylidene) triphenylphosphorane and 1, 2-Diacylethylenes" Tetrahedron Lett.37. 401-404 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "エネルギーと地球環境" 日刊工業新聞社, 195 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Iwamoto: "Time-Resolved FT-IR Study on Isotopic Exchange of Dinitrosyl Species Strongly Adsorbed on a Co-MFI Zeolite" Chemistry Letters. 8. 729-730 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Iwamoto: "Pulse Study on Reactivity of Ethene Adsorbed on Cu-MFI with Nitrogen Oxides and Oxygen." Catalysis Today. (in press). (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Abe: "Non-Silica-Based Mesostructured Materials.1.Synthesis of Vanadium Oxide-Based Material" Chem.Mater.7. 1429-1430 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Abe: "Preparation and Characterization of Fe_2O_3 Nanoparticles in Mesoporous Silicate" J.Chem.Soc.,Chem.Commun.1617-1618 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] J.Guo: "NOx Reduction Characteristics of Pt-ZSM-5 Catalyst with Diesel Engine Exhaust" JSAE Review. 16. 21-25 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] W.-X.Zhang: "Reversible and Irreversible Adsorption of Nitrogen Monoxide on Cobalt Ion-Exchanged ZSM-5 and Mordenite Zeolites at 273-523K" J.Chem.Soc.Faraday Trans. 91. 767-771 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.K.Shin: "Effect of Support on Activity of Platinum Catalysts for NO Reduction by Ethene in Excess Oxygen" Appl.Catal.B. (in press). (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Abe: "Effect of Underpotential Deposition (UPD) of Copper on Oxygen Reduction at Pt(111) Surfaces" J.Electroanal. Chem.382. 73-83 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 岩本正和: "ゼオライト触媒によるNOx除去" 触媒. 8巻. 614-622 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 岩本正和: "リーンバーンでのNOの選択還元除去" ペトロテック. 38巻. 850-851 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 八尋秀典: "金属イオン交換ゼオライトによるNOの吸着除去" 表面. 33巻. 44-55 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.K.Shin: "Selective Catalytic Reduction of NO by Ethene in Excess Oxygen Over Platinum Ion-Exchanged.MFI Zeolites" Catalysis Today. 26. 13-21 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] W.X.Zhang: "Removal of nitrogen monoxide by pressure swing adsorption on metal ion-exchanged zeolites" Trans.Mat.Res.Soc.Jpn.18A. 401-404 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hidenori Yahiro: "Selective catalytic reduction of nitrogen monoxide by hydrocarbon on platinum-zeolite" Trans.Mat.Res.Soc.Jpn.18A. 409-412 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Masakazu Iwamoto: "Performance and durability of Pt-MFI zeolite catalyst for selective reduction of nitrogen monoxide in actual diesel engine exhaust" Applied Catalysis B:Environmental. 5. L1-L5 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 武田博嗣: "炭化水素によるNO選択還元反応機構の検討" 触媒. 36. 68-71 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 郭建威: "白金ZSM-5触媒のディーゼル排気中のNOx還元特性に関する研究" 自動車技術会論文集. 941. 1395-1410 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Masakazu Iwamoto: "Zeolites in environmental Catalysis" Stud.Surf.Sci.Catal. 84. 1395-1410 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Masakazu Iwamoto: "Novel catalytic decomposition and reduction of NO" Catalysis Today. 22. 5-18 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 岩本正和: "ゼオライトを用いるNOの接触除去" 化学総説. 21. 127-136 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 八尋秀典: "金属イオン交換ゼオライト上でのNOの選択還元" 化学工学シンポジウムシリーズ. 42. 95-104 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Masakazu Iwamoto: "Metal ion-exchanged zeolites as highly active materials for removal of nitrogen monoxide by catalytic decomposition,selective catalytic reduction,or adsorption" Trans.Mat.Res.Soc.Jpn. 15A. 117-122 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Wen-Xiang Zhang: "Reversible and Irreversible Adsorption of Nitrogen Monoxide on Cobalt Ion-exchanged ZSM-5 and Mordenite Zeolites at 273-523K" J.Chem.Soc.Faraday Trans. 91. 767-771 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 岩本正和: "NOx除去のための新しい触媒システム" セラミックデータブック、工業製品技術協会, 334 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Masakazu Iwamoto: "Recent progress in novel catalytic removal of nitrogen monoxide" Elsevier,Amsterdam, 169 (1994)

    • Related Report
      1994 Annual Research Report

URL: 

Published: 1994-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi