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STUDY OF OPTICAL AND OPTO-ELECTRONIC PROPERTIES OF BETACAROTENE AND RELATED LINEAR CONJUGATED POLYMERS

Research Project

Project/Area Number 06640457
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionFaculyt of Science, Japan Women's University

Principal Investigator

KODA Takao  Department of Mathematical and Physical Sciences, Faculyt of Engineering, Japan Women's University, Professor, 理学部, 教授 (50010715)

Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1995: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1994: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsOptical Properties of Organic Matertials. / Conjugated Polymers. / Molecular Electronics. / Organic Nonlinear Optical Materials / Organic Thin Films.
Research Abstract

Optical and electro-optical properties have been investigated on beta-carotenes and related linear conjygated polyenes and polymers, inciuding diphenyl (DP) -octatetoraene, DP-hexatoriene, DP-butagene, poly silanes and polydiacetylenes, in the form of crystals and thin films, by means of third-order nonlinear optical spectroscopy such as electro-modu lated absorption spectroscopy, third-order harmonic generation spectroscopy, two-photon absorption spectroscopy and others. As a result, details of quasi-one-dimentional exciton structures in these linear conjugated molecules have been nelucideted. An important outcome is the first finding of specific polydiacetylenes which exhibit a reversible photo-induced phase transition between the two different electronic phases.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] 国府田隆夫ほか: "ポリシランとポリエンの励起子分光" 理化学研究所フォトダイナミクス研究センター・光反応フォーラム「ポリシランとポリエンの新物質科学」講演概要集. 9-10 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 国府田隆夫ほか: "Electro-modulation Spectroscopy on Excitons in β-carotene and Related polyenes" Synthefic metals. 71. 1723-1724 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 腰原伸也ほか: "光で起こす相転核-π共役高分子ポリジアセチレン-" 日本物理学会誌. 50. 548-555 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 腰原伸也ほか: "Nanosecond and Picosecond Dynamics of Photo-induced Phase-transition in Low Dimensional Crystals" Synthefic Metals. 70. 1225-1226 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 長谷川達生ほか: "Nonlinear Optical Spectroscopy on Polysilanes : Dependence of Exciton States on Podymer" Synthetic metals. 71. 1679-1680 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 腰原伸也ほか: "Dynamics of a Photo-induced Phase Transition in Polydiacetylene Crystals" Physical Review B. 52. 6265-6272 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 国府田隆夫: "物性科学辞典" 東京書籍, (8) (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Koda, A.Ishiguro, N.Kaneta, H.Kishida, Y.Tokura, and K.Ishikawa: "ELECTRO-MODULATION SPECTROSCOPY ON EXCITONS IN BETACAROTENE AND RELATED POLYENES" Synthetic Metals. 71. 1723-1724 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Hasegawa, Y.Iwasa, T.Koda, H.Kishida, Y.Tokura, S.Wada, H.Tashiro, H.Tachibana, M.Matsumoto, and R.D.Miller: "NONLINEAR OPTICAL SPECTROSCOPY ON POLYSILANES : De-PENDENCE OF EXCITON STATES ON POLYMER BACDKBONE CONFOMATIONS" Synthetic Metals. 71. 1679-1680 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Koshihara, Y.Tokura, K.Takeda, and T.Koda: "DYNAMICS OF A PHOTOINDUCED PHASE TRANSITION IN POLYDIACETYLENE CRYSTALS" Physical Review B. 52 (9). 6265-6272 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Koshihara, N.Sarukura, Y.Segawa, Y.Tokura, T.koda, and K.Takeda: "DYNAMICS OF PHOTO-INDUCED PHASE-TRANSITION IN LOW DIMENSIONAL ORGANIC CRYSTALS AMD THE ROLE OF PHOTOCARRIERS" Mol.Cryst.Liq.Cryst.252. 283-292 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Kishida, H.Hasegawa, Y.Iwasa, T.Koda, Y.Tokura, H.Tachibana, M.Matsumoto, S.Wada, T.T.Lay, and G.Tashiro: "ELECTRIC-FIELD-INDUCED SECOND HARMONIC GENERATION MEDIATED BY ONE-DIMENSIONAL EXCITONS IN POLYSILANES" Physical Review B. 50 (11). 7786-7792 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Koshihara, Y.Tokura, K.Takeda, and T.Koda: "PHOTO-INDUCED PHASE TRANSITION -PAICONJUGATED POLYMER POLYDI-ACETYSENES- (A Review Article in Japanese)" Butsuri. 50 (7). 548-554 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 国府田隆夫ほか: "Electro-modulation Spectroscopy on Exitons in β-carotene and Related Polyenes" Synthetic Metals. 71. 1723-1724 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 腰原伸也 ほか: "Nano second and Picosecond Dynqmics of Photo-induced Phase-Trausition Low Dimensional Crystats" Synthetic Metals. 70. 1225-1226 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 長谷川達生ほか: "Nonlinear Optical Spectroscopy on Polysilanes: Dependence of Exciton States on Polymer Backbone Stuctures" Synthetic Metals. 71. 1679-1680 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 腰原伸也ほか: "Dynamics of a Photo-induced Phase Transition in Polydiacetylene Crystals" Physical Review B. 52. 6265-6272 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 腰原伸也ほか: "光で起こす相転移-π共役高分子ポリジアセチレン-" 日本物理学会誌. 50. 548-555 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 国府田 隆夫: "Electro-modulation spectroscopy on excitons in β-carotene and related polyenes" synthetic metals. (印刷中). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 岩田 英夫: "Electric-field-induced second-harmonic generation mediated by one-dimensional excitons in polysilanes" Physical Review B. 50. 7786-7792 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 長谷川 達生: "Honlinear Optical Study of polysilanes" J.Phys.Soc.Japan,Suppl.B. 63. 64-81 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 国府田 隆夫: "ポリシランとポリエンの励起子分光" 理化学研究所フォトダイナミクス研究センター・光反応フォーラム「ポリシランとポリエンの新物質科学」. 9-10 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2020-05-15  

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