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Research on Degree of Localization off-electrons in Uranium Monopnictides and Moncharcogenides

Research Project

Project/Area Number 06640464
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionTohoku University, Institute for Materials Research

Principal Investigator

OCHIAI Akira  Tohoku University, I.M.R., Research Associate, 金属材料研究所, 助手 (90183772)

Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1995: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1994: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsUranium monopnictides / Uranium monocharcogenides / 5f-electrons / de Haas-van Alphen effect / ウランモノカルコゲナイド / ド・ハ-ス-ファン・アルフェン効果 / f電子 / ド・ハ-ス・アルフェン効果 / 局在性
Research Abstract

Following single crystals were grown ;
1.High quality single crystals of USb were obtained by using highly purified uranium metal, precise control of stoichiometry and annealing etc.
2.Single crystal of UAs was grown by Bridgman technique.
3.High quality single crystal of ThSb which is reference material of USb was grown using highly purified Th metal.
4.Single crystals of uranium monocharcogenides from US to UTe were grown by Bridgman technique.
Using these single crystalsfollowing new results were obtained ;
1.Characteristic physical properties of USb compared to UAs and UP are considered to be due to its semimetallic character. Now by magnetic and acoustic de Haas effect two kind of ellipsoidal Femisurface and spherical Fermi surface are observed.
2.USb shows magnetic phase transition by magnetic field of about 40T.
3.Magnetic phase transition of USb under high pressure was observed by electric resistivity and neutron scattering measurement.
4.UAs shows sample dependent transport property.
5.The r.r.r.of ThSb is rather improved and its de Haas effect experiment is now in progress.
X-ray magnetic scattering and magnetic Compton scattering experiments were performed for UTe, and contrary our expectation its 5f orbital is rather broad. Same experiments for US and USe are now in progress.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] A.Ochiai: "Transport properties and specific heat of UTe and USb" Physica B. 199&200. 616-618 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Suzuki: "Prepatliob of actinide compounds in the Oharai facility" J.Alloys.Conp.213/214. 178-184 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Ochiai: "Transport properties of USb and UTe" SCI.REP.RITU. A40. 5-7 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Ochiai: "De Haas-van Alphen effect in USb" Physica B. 206&207. 789-791 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Suzuki: "Anomalous physical properties of the low carrier concentration state in f-electron systems" Physica B. 206&207. 252-255 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Ito: "X-ray magnetic form factor of UTe" J.Phys.Soc.Jpn.64. 2333-2337 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Sakurai: "The magnetic Compton profile of UTe" J.Phys.Condens.Matter. 7. L599-L604 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 落合明: "希土類やウランのプニクタイト、カルコゲナイドの高品質単結晶育成" 固体物理. 29. 811-814 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Ochiai, Y.Suzuki, T.Shikama, E.Hotta, Y.Haga and T.Suzuki: "Transport properties and specific heat of UTe and USb" Physica B. 199&200. 616-618 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Suzuki, F.Wastin, A.Ochiai, T.Shikama, Y.Suzuki, Y.Shiokawa, T.Mitaugashira, T.Suzuki and T.Komatsubara: "Preparation of actinide compounds in the Oharaifacility" J.Alloys Comp. 213/214. 178-184 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Ochiai, Y.Suzuki, T.Shikama, K.Suzuki, E.Hotta, Y.Haga and T.Suzuki: "Transport properties of USb and UTe" SCI.REP.RITUA. 40. 5-7 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Cchiai, T.Shikama, K.Suzuki, E.Hotta and T.Suzuki: "Single crystal growth of rare earth pnictides and chalcogenides and of high quality uranium pnictides and chalcogenides (Japanese)" Solid State Physics. 29. 811-814 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Ochiai, E.Hotta, Y.Haga, T.Suzuki, Y.Suzuki, T.Shikama and K.Suzuki: "De Haas-van Alphen effect in USb" Physica B. 206&207. 789-791 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Suzuki et. al.: "Anomalous physical properties of the low carrier concentration state in f-electron systems" Physica B. 206&207. 771-779 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] E.Hotta, A.Ochiai, Y.Suzuki, T.Shikama, K.Suzuki, Y.Haga and T.Suzuki: "Purification of USb and its de Haas-van Alphen effect" J.Alloys Comp.219. 252-255 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Ito, F.Itoh, Y.Tanaka, A.Koizumi, H.Sakurai, T.Ohata, A.Ochiai and H.Kawata: "X-raymagnetic form factor of UTe" J.Phys.Soc.Jpn. 64. 2333-2337 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Sakurai, H.Hashimoto, A.Ochiai, T.Suzuki, M.Ito and F.Itoh: "The magnetic Compton profile ofUTe" J.Phys.Condens.Matter. 7. L559-L604 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A. Ochiai: "Transport properties and specific heat of UTe and USb" Physica B. 199&200. 616-618 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Suzuki: "Preparation of actinide compounds in the Ohami facility" J. Alloys Comp.213/214. 178-184 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] A. Ochiai: "Transport properties of USb and UTe" SCI. REP. RITV. A40. 5-7 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] A. Ochiai: "De Haas-van Alphen effect in USb" Physica B. 206&207. 789-791 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Suzuki: "Anomalous physical properties of the low carrier concentration state in f-electron system" Physica B. 206&207. 771-779 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] E. Hotta: "Purification of USb and its de Haas-van Alphen effect" J. Alloys Comp.219. 252-255 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Ito: "X-ray magnetic form factor of UTe" J. Phys. Soc. Jpn.64. 2333-2337 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Sakurai: "The magnetic Comptor profile of UTe" J. Phys. Condens. Matter. 7. L599-L604 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 落合明: "希土類やウランのプニクタイト,カルコゲナイドの高品質結晶育成" 固体物理. 29. 811-815 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Ochiai: "De Haas-van Alphen effect in USb" Physica B.

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Ochiai: "Transport properties and specific heat of UTe and USb" Physica B. 199&200. 616-618 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Kenji Suzuki: "Preparation of actinide compounds in the Oharai facility" Journal of Alloys and Compounds. 213/214. 178-184 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Akira Ochiai: "Transport Properties of USb and UTe" Sci.Rep.RITU. A40. 5-7 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2020-05-15  

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