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Nonlinear Laser Spectroscopy of vibrationally excited molecules using a high-finesse cavity

Research Project

Project/Area Number 06640532
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 物理学一般
Research InstitutionKeio University

Principal Investigator

SASADA Hiroyuki  Keio University, Department of Physics, Assistant Professor, 理工学部, 専任講師 (30146576)

Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1995: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1994: ¥1,500,000 (Direct Cost: ¥1,500,000)
Keywordssaturated absorption spectroscopy / laser spectroscopy / optical resonator / methane / acertylene / overtonebands / semiconductor laser / 非線形レーザー分光 / 高振動励起分子
Research Abstract

In the first year, an external-cavity semiconductor laser was constructed for spectroscopy of the 1.65-mum region. This year an optical-cavity absorption cell having a finesse of 300 was made. Resonant radiation forms a standing wave in the cavity, and the radiation power at the antinode of the standing wave is enhanced by 150 times larger than tha incident power, which makes it easy to perform saturation spectroscopy. With a servo loop, laser frequency is always locked at the resonant frequency of the cavity. Saturation spectrum has been recorded on the overtone band of methane. Its spectral Iinewidth is about 0.5 MHz, which is much smaller than Doppler width of 290 MHz, hoence some lines overlapped in Doppler-limited spectroscopy are cleary resolved. Another opical-cavity absorption cell having a pair of Stark electrodes has been built to study Stark effects of methane. The magnitude of the vibrationally-induced permanent dipole moment detarmined from easurements of the Stark shift shows a clear dependence on the Coriolis sublevels.This dependence is observed for the first time, and a theoretical anlysis has been made.
An optical-cavity absorption cell was built using a pair of mirrors having a reflectivity of 99.97% around 790 nm. Using this cell, absorption spectroscopy of a weak combination band of acetylene was carried out. Because radiation is reflected many times in the cavity, an absorption length is effectively enhanced. Absorption strength in this cell is a thousand times larger than that in a single-pass absorption cell. A finesse of cavity is determined to be 1400, which is, however, far less than 10000 expected from the reflectivity of the mirrors. The main reason of this degrading is probably due to spots on the mirror surface. Frequency of a titanium-sapphire laser and the optical cavity resonance is not stable enough to observe saturation spectrum.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (5 results)

All Other

All Publications (5 results)

  • [Publications] H.Sasada: "Vibrationally Induced Dipole Moment of the v_3=2 State of Methane" Journal of Molecular Spectroscopy. 172. 573-575 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Suzumura: "Observation of Saturation Spectrum of the 2v_3 Band of Methane" Japanese Journal of Applied Physics. 34. L1620-L1621 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Sasada and Y.Kuba: "Vibrarionally Induced Dipole Moment of the v_3=2 State of Methane" Journal of Molecular Spectroscopy. Vol.172. 573-575 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Suzumura and H.Sasada: "Observation of Saturation Spectrum of the 2v_3 Band of Methane" Japaneses Journal of Applied Physics. Vol.34. L1620-L1621 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Suzumura and H. Sasada: "Observation of saturation spectrum of the 2v_3 band of methane" Japanese Journal of Applied Physics. 34. L1620-L1621 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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