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Arrangements, Reactivities and Functions of Organic and Organometallic Molecules in Inorganic Layred Spaces

Research Project

Project/Area Number 06640721
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionOsaka University

Principal Investigator

MATSUBAYASHI Genetsu  Osaka University, Faculty of Engineering, Professor, 工学部, 教授 (90029182)

Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1995: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1994: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsIntercalation compound / Vanadium oxide / Vanadyl phosphate / Ferrocenyl compound / Zirconium phosphate / Pyridine dervative / Spin-crossover complex / Pyrrole derivative / ジピリジル誘導体 / バナジルホスフェート / 4-アニリノアノリン / 2,2′ジピリジルジスルフィド / ジルコニウムホスホネート / イソキノリニウム
Research Abstract

We have intercalated organic, organometallic molecules and metal complexes into the interlayr spaces of inorganic compounds and studied molecular arrangements and electronic states of guest molecules in the interlayr spaces and found unique physical properties and reactivities of them characteristic of those in the interlayr spaces.
1) Intercalation of ferrocenyl derivatives into the interlayr spaces of mixed vanadyl-niobyl phosphates and behaviors of the guest molecules in the spaces have clarified the fundamental characteristics of them in arrangements and electronic states in the interlayr space of the VOPO_4-intercalation compounds formed by redox reactions.
2) 3-Methyl-and 3.5-dimethylpyrrole have been intercalated into the VOPO_4 interlayr space, accompanied with polymerization, to afford intercalation compounds. 4-Anilinoaniline has been also polymerized in the VOPO_4 and V_2O_5 interlayr spaces and the polymerization process has been clarified.
3) Substituted quinolinium and isoqu … More inolinium cations and the acridinium cation have been intercalated into the interlayr space alpha-zirconium phoshate. Fluorescence spectra and fluorescence lifetimes of them have been measured. The lifetimes are somewhat shortened in the interlayr space compared with in solution, and components having short lifetimes of 4-5 ns are present in the interlayr space.
4) Several substituted pyridine derivatives and dipyridyl compounds have been intercalated into the V_2O_5 interlayr space, where pyridyl nitrogen atoms have been partially protonated. The abundances of the protonated nitrogen atoms do not depend on strengths of basicity of a guest molecule. Protonation is affected by the charge separation due to dissociation of water molecules in the interlayr space. The interlayr distances have been clarified to be lengthened with the increase of the abundances of protonated nitrogen atoms per vanadium of the host layr.
5) NaTMS clay-intercalation compounds containing spin-crossover iron (II or II) complexes have been prepared. ESR spectra and temperature-dependence of magnetic susceptibilities of them have clarified that these metal complexes have two or three surroundings in the clay interlayr space, the changes between high spin and low spin states occurring in the wide temperature range. Thermodynamic parameters of the equilibria in the spin states have been estimated. Less

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 奥野昌二、松林玄悦: "Intercalation of Ferrocene and Its Derivatives into V_xNb_<1-x>OPO_4(x=0, 0.06, 0.11, and 0.21) Interlayer Spaces" Bulletin of the Chemical Society of Japan. 67. 398-404 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 中島 洋,松林玄悦: "Intercalation of Polymerized 3-Methyl-and 3, 4-Dimethyl-pyrrole in the VOPO_4 Interlayer Space" Jounal of Materials Chemistry. 4. 1325-1329 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 中島 洋,松林玄悦: "Intercalation and Polymerization of 4-Anilinoaniline and 4-Anilinoanilinium Iodide in the VOPO_4 and V_2O_5 Interlayer Spaces" Jounal of Materials Chemistry. 5. 105-108 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 奥野昌二、松林玄悦: "Preparation and Spectroscopies of Layered Zirconium Organo-phosphonates Containing Pyridinium and its Derivative cations" Inorganica Chimica Acta. 233. 173-177 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 奥野昌二、松林玄悦: "Direct Intercalation of Pyridinium-derivative Cations into the α-Zirconium Phosphate Interlayer by a Redox Reaction and Fluorescence Behavior of the Intercalation Compounds" Inorganica Chimica Acta. (印刷中). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 1) S.Okuno and G.Matsubayashi: "Intercalation of Ferrocene and Its Derivative into V_xNb_<1-x>OPO_4 (x=0,0.06,0.11, and 0.21) Interlayr Spaces" Bull.Chem.Soc.Jpn.67. 398-404 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 2) H.Nakajima and G.Matsubayashi: "Intercalation of Polymerized 3-Methyl-and 3,4 Dimethyl-pyrrole in the VOPO_4 Interlayr Space" J.Mater.Chem.4. 1325-1329 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 3) H.Nakajima and G.Matsubayashi: "Intercalation and Polymerization of 4-Anilinoaniline and 4-Anilinoanilinium Iodide in the VOPO_4 and V_2O_5 Interlayr Spaces" J.Mater.Chem.5. 105-108 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 4) S.Okuno and G.Matsubayashi: "Preparation and Spectroscopies of Layred Zirconium Organophosphonates Containing Pyridinium and Its Derivative Cations" Inorg.Chim.Acta. 233. 173-177 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 5) S.Okuno and G.Matsubayashi: "Direct Intercalation of Pyridinium-derivative Cations into the *-Zirconium Phosphate Interlayr by a Redox Reaction and Fluorescence Behavior of the Intercalation Compounds" Inorg.Chim.Acta. (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 奥野昌二、松林玄悦: "Preparation and Spectroscopies of Layered Zirconium Organophosphonates Containing Pyridinium and its Derivative cations" Inorganica Chimica Acta. 233. 173-177 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 奥野昌二、松林玄悦: "Direct intercalation of pyridinium-derivative cations into the α-zirconium phosphate interlayer by a redox reaction and fluorescence behavior of the intercalation compounds" Inorganica Chimica Acta. (印刷中). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 中島洋,松林玄悦: "Intercalation and Polymerization of 4-Anilinoaniline and 4-Anilinoanilinium lodide in the VOPO_4 and V_2O_5 Interlayer Spaces" Journal of Materials Chemistry. 5. 105-108 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 奥野昌二,松林玄悦: "Preparation and spectroscopies of lavered zirconium organophosphates containing the pyridinium and its derivative cations" Inorganica Chimica Acta. (印刷中). (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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