| Project/Area Number |
06640752
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
機能・物性・材料
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| Research Institution | Himeji Institute of Technology |
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Principal Investigator |
YAMADA Jun-ichi Himeji Institute of Technology, Faculty of Science, Assistant, 理学部, 助手 (90191311)
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| Co-Investigator(Kenkyū-buntansha) |
ANZAI Hiroyuki Himeji Institute of Technology, Faculty of Science, Professor, 理学部, 教授 (40222773)
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| Project Period (FY) |
1994 – 1995
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| Project Status |
Completed (Fiscal Year 1995)
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| Budget Amount *help |
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1995: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1994: ¥1,700,000 (Direct Cost: ¥1,700,000)
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| Keywords | Tetrathiafulvalene / Organotin compounds / Lewis acid / Electrophiles / DHTTF derivative / DSDTF derivative / TTFs-fused donors / BEDT-TTF derivative / TTF有機合成金属 / 対称TTF誘導体 / 非対称TTF誘導体 / ノン-カップリング反応 / 結晶育成 / 制御電流法 / 単結晶 / 電荷移動錯体 |
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| Research Abstract |
The efficient syntheses of unsymmetrical tetrathiafulvalenes (TTFs), as well as symmetrical TTFs, were accomplished by the Lewis acid-mediated reactions of organotin compounds with electrophiles. The synthesis of unsymmetrical TTFs could be carried out by the Me_3Al-promoted noncoupling reactions without tedious separation procedure. In addition, this synthetic method could also be applicable to the preparation of TTFs-fused donors. Moreover, BEDT-TTF derivatives condensed with heterocycles could be synthesized systematically via the BF_3-promoted reaction. We have accomplished the development of new organic metals based on (1) the DHTTF (dihydrotetrathiafulvalene) derivative, (2) the DSDTF (diselenadithiafulvalene) derivative, (3) TTFs-fused donors, and (4) the BEDT-TTF derivative fused with 1,4-dioxane ring.
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