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Tremophysical Properties of Component Materials of Molten Carbonates Fuel Cell

Research Project

Project/Area Number 06650266
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionKeio University

Principal Investigator

NAGASAKA Yuji  Keio University, Mechanical Eng., Associate Professor, 理工学部, 助教授 (40129573)

Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1995: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1994: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsMolten Carbonate Fuel Cell / Thermophysical Properties / Molten Carbonates / Thermal Diffusivity / Forced Rayleigh Scattering Method / High Temperature Melts
Research Abstract

The results obtained from the present research are summarized as follows.
(1) In order to develop a practical forced Rayleigh scattering apparatus applicable to a wide range of substances and conditions, we have invented a free-surface feating technique using CO_2 laser which does not require any cell windows.
(2) By measuring water at room temperature and molten caronates, it has been found the effect of two-dimensional heat conduction. We have analyzed the error factors, and attempted to apply new analysis to correct the errors.
(3) The thermal diffusivity of molten carbonates mixtures (Li_2CO_3-Na_2CO_3-K_2co_3 : 45.3-31.5-25.0mol% and Li_2CO_3-Na_2CO_3 : 53.3-46.7mol%) at temperatures up to 1030K.
(4) The thermal diffusivity of molten Li_2CO_3 (1130 to 1170K), Na_2CO_3 (1160 to 1260K) and K_2CO_3 (1170 to 1300K) has been measured by using sapphire glass as a sample cell. The accuracy of the present measurement is estimated to be <plus-minus> 25%. We found that the previous date by Egorov are larger than ours with a macximum deviation of about 170%.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 茨田高志: "CO_2レーザーを用いた強制レイリー散乱法の研究(第3報.光学系の改良及び自由表面加熱法の誤差要因の検討)" 第31回日本伝熱シンポジウム講演論文集. 283-285 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Ibata: "Experimental Study of the Thermal Diffusivity of Molden Carbonates by the Forced Rayletgh Scattering Method with CO_2 Laser" Proc. 4th Asian Thebmophysical Properties Conference. 85-88 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 茨田高志: "CO_2レーザーを用いた強制レイリー散乱法の研究(第4報 溶融炭酸塩の測定)" 第32回日本伝熱シンポジウム講演論文集. 771-772 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 大坪誠司: "CO_2レーザーを用いた強制レイリー散乱法の研究(第5報 溶融Li_2CO_3およびNa_2CO_3の測定)"

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ibata, T.: "Experimental Study of the Forced Rayleigh Scattering Method with CO_2 Laser (3rd Report ; Improvenment of the Optical System and Investigation of Error Factor due to Free Surface Heating Technique)" Proc.31st National Heat Transfer Symposium of Japan. 283. (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ibata, T.: "Experimental Study of the Forced Rayleigh Scattering Method with CO_2 Laser (4th Report ; Measurement of Molten Carbonates)" Proc.32nd National Heat Transfer Symposium of Japan. 771. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ibata, T.: "Experimental Study of the Thermal Diffusivity of Molten Carbobnates by the Forced Rayleigh Scatteing Method with CO_2 Laser" Proc.4th Asian Thermphysical Properties Conference. 85. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Otsubo, S.: "Experimental Study of the Forced Raleigh Scattering Method with CO_2 Laser (5th Report ; Measurement of Molten Li_2CO_3 and Na_2CO_3)" Proc.33rd. National Heat Transfer Symposium of Japan. (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Ibata: "Experimental Study of the Thermal Diffusivity of Molten Carbonates by the Forced Rayleigh Scattering Method with CO_2 Laser" Proc. 4th Asian Thermophysical Properties Conference. 85-88 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 茨田高志: "CO_2レーザーを用いた強制レイリー散乱法の研究(第4報,溶融炭酸塩の測定)" 第32回日本伝熱シンポジウム講演論文集. 771-772 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 大坪誠司: "CO_2レーザーを用いた強制レイリー散乱法の研究(第5報,溶融Li_2CO_3およびNa_2CO_3の測定)" 第33回日本伝熱シンポジウム講演論文集. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 茨田 高志: "CO_2レーザーを用いた強制レイリー散乱法の研究(第3報,光学系の改良及び自由表面加熱法の誤差要因の検討)" 第31回日本伝熱シンポジウム講演論文集. 283-285 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 茨田 高志: "CO_2レーザーを用いた強制レイリー散乱法の研究(第4報,溶融炭酸塩の測定)" 第32回日本伝熱シンポジウム講演論文集. (発表予定). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Ibata: "Experimental Study of the Thermal Diffusivity of Molten Carbonates by the Forced Rayleigh Scattering Method with CO_2 Laser" 4th Asian Thermophysical Properties Conference. (発表予定). (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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