| Project/Area Number |
06650375
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Electronic materials/Electric materials
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| Research Institution | SHIZUOKA INSTITUTE OF SCIENCE & TECHNOLOGY |
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Principal Investigator |
OGAWA Toshio SHIZUOKA INSTITUTE OF SCIENCE & TECHNOLOGY DEPARTMENT OF ELECTRONIC ENGINEERING ASSOCIATE PROFESSOR, 理工学部, 助教授 (40247573)
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| Project Period (FY) |
1994 – 1996
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| Project Status |
Completed (Fiscal Year 1996)
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| Budget Amount *help |
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1996: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1995: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1994: ¥1,000,000 (Direct Cost: ¥1,000,000)
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| Keywords | tetragonal PZT ceramics / poling field / ferroelectric domains / domain configuraion model / 90ﾟ rotation / 180ﾟ switching / planar coupling factor / frequency constant / 菱面体晶PZTセラミックス / 配向分極 / 180°回転 / 誘電・圧電特性 / 正方晶系PZTセラミック / 配向電極 / 90°ドメイン / 結晶配向度 |
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| Research Abstract |
Ferroelectric domain structures of tetragonal PZT ceramics were evaluated by the poling field (E) dependence of planar coupling factor (kp) and relative XRD intensity of (002) peak, I_<002>. We proposed typical domain configurations composed of 15 patterns. Furthermore, we picked out the two patterns to make a domain configuration model with 90ﾟ and 180ﾟ domains. It was thought that the change in the domain structure by poling could be explained to calculate the change in the area with the individula axis. Therefore, the total amount of the domains oriented to c axis was estimated by the relation between I_<002>, kp, normalized polarization and E.From our domain configuration model, it was confirmed that there were two peaks of 90ﾟ domain rotation and one peak of 180ﾟ domain rotation. After the 90ﾟ domain switching, the domains in c direction were changed mainly by 180ﾟ rotation. As a result, the 90ﾟ domain switching decreased and 180ﾟ domain switching increased. We believe our study on domain structures of bulk ceramics may be useful for understanding the degradation characteristics in PZT thin films.
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