| Project/Area Number |
06650780
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Structural/Functional materials
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| Research Institution | Osaka University |
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Principal Investigator |
NISHIURA Tetsuya Osaka University, ISIR,Rsearch Associate, 産業科学研究所, 助手 (50112066)
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| Project Period (FY) |
1994 – 1996
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| Project Status |
Completed (Fiscal Year 1996)
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| Budget Amount *help |
¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1996: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1995: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1994: ¥1,200,000 (Direct Cost: ¥1,200,000)
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| Keywords | Radiation / Stress / Synergistic effects / epoxy resin / epoxy based GFRP / Cryogenic temperature / Creep / Relaxation / 放射線照射下グリープ / 応力と放射線の同時効果 / ESR測定 / エポキシ系FRP / 放射線照射下クリープ / 活性化エネルギー |
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| Research Abstract |
Mechanical tests (creep and relaxation tests by bending) are made during irradiation in order to examine synergistic effects of radiation and stress on mechanical properties.
The 1994th period : 1.Samples are engineering plastics ie.epoxy resin and glass fiber reinforced epoxy resin. 2.Radiation sources are gamma-ray of Co-60 and electron beam of linac at ISIR.3.An alminum vessel for irradiation test was made, which was able to be filled with liquid nitrogen, in order to avoid thermal destruction of polymers by irradiation. 4.The material's degradation is found to be accelerated by snergestic effects of radiation and stress.
The 1995th period. 5.Examining chmical processes in polymers of synergistic effects of radiation and stress, the dependency of the creep rates during irradiation on the enviromental temperature was investigated. The appearent activate energy for the rate in the synergistic test is smaller than that of the irrdiatet only material. The difference of degradation mechansm is, therefore, assumed btween the synergistic condition and the only irradiated condition.
The 1996th period : 6.Radicals from ESR measurement in the synergistic test specimen are 10 % larger than those in the irrdiated one. 7.Scissions of molecular chain are found to be 10 % increased by synergistic effect according to vibrational tests and swelling tests. 8.The mechanism of acceleration in degradation of organic materials is proposed as followings ; 1) From macroscopic view point, decrease of the viscosity in Maxwell model. 2) Scissions increase and the effect of crosslinkage disappear in the synergistic condition.
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