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Dynamics of Fast Ions in Solids and Its Evolution for Solid State Ionics

Research Project

Project/Area Number 07239105
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

OGUMI Zempashi  Graduate School of Engineering Kyoto University Prof., 工学研究科, 教授 (60110764)

Co-Investigator(Kenkyū-buntansha) KISHIMOTO Akira  Institute Industrial Science University of Tokyo Assoc. Prof., 生産技術研究所, 助教授 (30211874)
ESAKA Takao  Faculty of Engineering Tottori University Prof., 工学部, 教授 (70116317)
YAO Takeshi  Graduate School of Energy Science Kyoto University Prof., エネルギー科学研究科, 教授 (50115953)
WTANABE Masayoshi  Faculty of Engineering, Yokohama National Univ. Assoc. Prof., 工学部, 助教授 (60158657)
FUJINAMI Tatsuo  Faculty of Engineering, Shizuoka University Prof., 工学部, 教授 (80022010)
EGUCHIMKOICHI  Graduate School of Engineering Kyushu University Assoc. Prof. (00168775)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥140,700,000 (Direct Cost: ¥140,700,000)
Fiscal Year 1997: ¥34,400,000 (Direct Cost: ¥34,400,000)
Fiscal Year 1996: ¥75,100,000 (Direct Cost: ¥75,100,000)
Fiscal Year 1995: ¥31,200,000 (Direct Cost: ¥31,200,000)
Keywordsionic conductor / solid state ionics / polymer electrolyte / composite / oxide / HィイD1-ィエD1 conductor / high ionic conductivity / イオン伝導性 / フッ化物 / イオン伝導 / ハイドライドイオン / オキサイドイオン / 液相合成 / 気相合成 / イオンダイナミクス
Research Abstract

New ionic conductors with high ion mobility were synthesized. Furthermore, novel processing methods were invented.
1. Novel high-ionic conductors
(1) New solid solution of halide and hydride were prepared which were highly conductive for H ion.
(2) A series of PbィイD21-xィエD2LnWOィイD24+x/2ィエD2 were prepared which were highly conductive for oxide ion and different kind of lantanide were examined. The conduction mechanism was also clarified.
(2) New types of polymer electrolyte based on ate-type complex of Al and B were prepared. The electrolytes show a typical single ion conduction behavior. The influence of structure of side chain of oligo-ether group attached to aluminum via Si atom was.
(3) Extremely highly branched solid polymer electrolytes with high ionic conductivity was prepared and its conduction was discussed.
2. Designing of composite oxide conductive for oxide ion
(1) Zirconia ceramics was toughened by nano-size alumina. The addition of fine alumina up to 10% increased the ionic conductivity of YSZ.
(2) Pulverized ceria was dispersed in YSZ to enhance chemical stability of ceria against reduction while maintaining its high ionic conductivity.
3. Development of novel processing technology
(1) Silver iodide was prepared by vapor-phase electrolytic deposition employing RF plasma as conductive fluid.
(2) Hollow fibers of CeOィイD22ィエD2 and YSZ were prepared by a CVD-EVD method employing NiO as an oxygen source. Its rate determining step was clarified to be the oxygen transport through the sintered NiO.
2) Crystalline oxides were prepared directly from aqueous solution of fluoride complexes.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (110 results)

All Other

All Publications (110 results)

  • [Publications] Zempachi Ogumi: "Novel Method for Preparing Nickel/YSZ Cermet by a Vapor-Phase Process"J.Am.Ceram,Soc,. 78. 593-598 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Esaka: "Control of Oxygen Deficiency in Perovlkite-Type Oxide Ca_<0.9>La_<0.1>MnO_<3.8> and its Caithodic Property in KOH solution"Journal of Applied Electrochemistry. 26・4. 439-442 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Eguchi: "Effect of Concentration Overvoltage on Power Generation Characterstics of Solid Oxide Fuel Cells"Jouinal of Electrochemical Society. 143. 3699-3703 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Kishimoto: "Strength distributions oftitania ceramics after high voltage screening"Journal of Materials Science. 31. 3419-3425 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Watanabe: "Molecular Design of Ion and Ion/Electron Mixed Conducting Polymers"Macromolecular Symposia. 105. 229-233 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Fujinami: "Siloxyalminate Polymers with High Li+Ion Conducitivity"Chemistry of Materials. 9. 2236-2239 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 岸本 昭: "工業材料大辞典"産業調査会. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 岸本 昭: "セラミックス用語辞典"日刊工業新聞. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Z. Ogumi et al.: "Novel Method for Preparing Nickel/YSZ Cermet by a Vapor-Phase Process"J.Am.Ceram.Soc.. 78. 593-598 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A. Mineshige et al.: "Preparation of Yttria-Stabilized Zirconia Microtube by Electrochemical Vapor in KOH solution"J.Amer.Ceram.Soc.. 78. 3157-3159 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Esaka et al.: "Formation of Oxide Ion Conductive Phase in the Substututed Oxide System Based ZnTiOィイD24ィエD2"Solid State Ionics. 76. 237-242 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Esaka et al.: "Control of Oxygen Deficiency in Perovskite-type Oxide CaィイD20.9ィエD2LaィイD20.1ィエD2MnOィイD23-8ィエD2 and its Cathodic Property in KOH solutuion"Journal of Applied Electrochemistry. 26.4. 439-442 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H. Morinioto et al.: "Preparation of the Perovskite-type Oxide Ceramic CaィイD21-xィエD2LaィイD22x/3ィエD2MnOィイD23-λィエD2 as the Cathode Active Materials in Alkaline Batteries"Material Research Bulletin. 32. 1359-1366 (1977)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K. Eguchi et al.: "Power Generation and Steam Electrolysis Characteristics of Electrochemical Cell with a Zirconia-or Ceria-Based Electrolyte"Solid State Ionics. 86-88. 1245-1249 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K. Eguchi et al.: "Effect of Concentration Overvoltage on Power Generation Characteristics of Solid Oxide Fuel Cells"Journal of Electrochemical Society. 143. 3699-3703 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A. Kishimoto et al.: "Effect of high voltage screening on strength distribution for TiOィイD22ィエD2 ceramics"J.Am.Ceram.Soc.. 78. 2248-2250 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A. Kishimoto et al.: "Strength distributions of titania ceramics after high voltage screening"Journal of Materials Science. 31. 3419-3425 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y. Nakamura et al.: "Strain-Dependent Electrical Conduction in the System NiO-CaO"J. Am. Ceram. Soc.. 80. 1609-1611 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M. Watanabe et al.: "Molecular Design of Ion and Ion/Electron Mixed Conducting Polymers"Macromolecular Symposia. 105. 229-233 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M. Watanabe et al.: "Conductivity Study of Ionic Liquid/Polymer Complexes"Solid State Ionics. 86-88. 353-356 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Fujinami et al.: "Siloxyalminate Polymers with High Li+Ion Conductivity"Chemistry of Materials. 9. 2236-2239 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Yao et al.: "Novel Method for Zirconium Oxide Synthesis from Aqueous Solution"J. Am. Ceram. Soc.. 79. 3329-3330 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Esaka et al.: "Application of NR to Study the Lithium Ion Transfer Solid Ionic Conductors" Key Engineering Materials. 132-136. 1393-1396 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Kamata et al.: "Application of Neutron Radiography to the Study of Lithium Batteries" J.Power Sources. 68. 459-462 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Morimoto et al.: "Preparation of the Perovskite-type Oxide Ceramic Ca_<1-x>La_<x/3>MnO_<3/1A> as the Cathode Active Materials in Alkaline Batteries" Material Research Bulletin. 32. 1359-1366 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Kamata et al.: "Application of Neutron Radiography to the Research of Lithium Ion Conductors and Lithium Batteries" The Proceedings of 5th World Conference on Neutron Radiography. 650-656 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Takai et al.: "Mechanical Alloying of the Perovskite-type structured Powder of La_<2/3-x>Li_<3x>TiO_3 Showing lithium Ion Conduction" The proceedings of Int.Symposium on Metastable,Mechanically Alloyed and Nanocrystalline Materials (LSMANAM,97) in press.

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Takai et al.: "Conductivity Relaxation Studies on (Bi_1O_3)_<1-x>(Y_2O_3)_x and (Bi_2O_3)_<1-x>(Gd_2O_3)_x with the defect fluorite structure" Material Research Bulletin,in press.

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Kamata et al.: "Synthesis and Ionic Conductivity of LiBaF_<3rX>H_X" Denki Kagaku,in press.

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Esaka et al.: "Measurements to Study the Reversible Transfer of Lithium Ion in Lithium Titanium Oxide" The Proceedings of Materials Research Society 1997 Fall Meeting,in press.

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Harada et al.: "Nonlinear current-voltage characteristics of Homojunctions made by zinc oxide single crystals" J.Mat.Res.Soc.458. 343-347 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura et al.: "High Temperature Strain Sensor Using NiO-CaO Solid Solution" Jpn.Sensor Newsletter,Edison Sensor Technology Center. 11. 19-23 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura et al.: "Strain-Dependent Electrical Conduction in the System NiO-CaO" J.Am.Ceram.Soc.80. 1609-1611 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura: "Comparison of the Mechanical and Dielectric Strength Distribution for Hardened Gypsum" J.Mat.Sci.32. 115-118 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Fujinami et al.: "Siloxyalminate Polymers with High Li+Ion Conductivity" Chemistry of Materials. 9. 2236-2239 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 藤波達雄: "アート錯体型イオン伝導性高分子" 電池技術. 9. 30-37 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 藤波達雄: "有機無機ハイブリッド型イオン導電体" 高分子加工. 46. 450-454 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 渡邊正義: "高分子中のイオンダイナミクスと高分子固体電解質" 熱測定. 24. 12-21 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Ichikawa et al.: "Molecular Relaxation of a Branched Poly (ethylene oxide) Network Polymer" Polym.J.29. 429-433 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] A.Nishimoto et al.: "High Ionic Conductivity of New Polymer Electolytes based on High Molecular Weight Polyether Comb Polymers" Electrochim.Acta,. (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] A.Uedono et al.: "Open Spaces and Molecular Motions of Polyether-Based Network Polymers Probed by Positron Annihilatio" J.Polym.Sci,Part B,Polym.Phys. (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Kono et al.: "Network Polymer Electrolytes having Free Chain Ends as Internal Plasticizer" J.Electrochem.Soc,. (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] 渡邊正義: "ゴム状態とポリマーイオニクス材料" 日本ゴム協会誌. 70. 477-484 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 渡邊正義: "高分子固体電解質の最近の進展" 電気化学. 65. 920-925 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Yao et al.: "Novel Method for Zirconium Oxide Synthesis from Aqueous Solution" J.Am.Ceram.Soc.79. 3329-3330 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Oka et al.: "Crystal Structures of Cs_2V_4O_<11> with Unusual V-O Coordinations" J.Solid State Chem.134. 52-58 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Oka et al.: "Hydrothermal Synthesis and Structure Refinemient of Alkali-Metal Trivanadates AV_3O_8 (A=K,Rb,Cs)" Mater.Res.Bullet.32. 1201-1209 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Inaba et al.: "Growth Rate of Yttria-Stabilized Zircomia Thin Films Formed by Electrochemical Vapor-Deposition Using NiO as an Oxygen Soura" Solid State Ionics. 104. 303-310 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Inaba et al.: "Raman Study of Layered Rock-Salt LiCoO_2 and Its Electrochemical Lithium Deintercalation" J.Raman Spectrosc.28. 613-617 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Ioroi: "Preparation of Perovskite-Type La_<1-x> Sr_x MnO_3 Films by Vapor-Phase Processes and Their Electrochemical Proper" J.Electrochem.Soc.144. 1362-1370 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 岸本昭: "「工業材料大事典」" 産業調査会, (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 岸本昭: "「セラミックス用語辞典」" 日刊工業新聞, (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Atsushi Mineshige: "Crystal Structure and Metal-Insulator Transition of La_<1-x>Sr_xCoO_3" Journal of Solid State Chemistry. 121・2. 423-429 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tsutomu Ioroi: "Preparation and Characteristics of Ni/YSZ Cermet Anodes by Vapor-phase Deposition" Denki Kagaku. 64・6. 562-566 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Atsushi Mineshige: "Preparation of Hollow YSZ Fibre by Electrochemical Vapour Deposition" Solid State Ionics. 86-88. 1251-1254 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tsutomu Ioroi: "Preparation and Characteristics of LaMnO3 Thin Film Electrode on YSZ by a Vapor-Phase Process" Chemistry Letters. 1996・11. 949-950 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Horimoto: "Nonstoichiometry of Sintered Oxide Ca_<0.9>La_<0.1>MnO_<3-δ> and its Cathodic Properties in Alkaline Solutions" Journal of the Electrochemical Society. 143・2. 567-570 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Esaka: "Control of Oxygen Deficiency in Perovskite-type Oxide Ca_<0.9>La_<0.1>MnO_<3-δ> and its Cathodic Property in KOH solution" Journal of Applied Electrochemistry. 26・4. 439-442 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kamata: "Application of Neutron Radiography to Visualize the Motion of Lithium Ions in Lithium Ion Conducting Materials" Journal of the Electrochemical Society. 143・6. 1866-1870 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kamata: "Application of NR for Research in Electrochemical Systems" Journal of Nuclear Instruments and Methods in Physics Research. 377・1. 161-165 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kamata: "Thermoelectric Power in Ionic and Electronic Mixed Conductors" Denki Kagaku. 64・8. 897-902 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kamata: "Application of Cold Neutron Radiography to Study the Lithium Ion Movement in Li_<1.33>Ti_<1.67>O_4" Denki Kagaku. 64・9. 984-987 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Esaka: "Preparation of the Bi_2O_3-based Fluorite-type Solid Solution by Mechanical Alloying" Denki Kagaku. 64・9. 1012-1016 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Morimoto: "Preparation of the Perovskite-type Oxide Ca_<0.9>Nd_<0.1-y>MnO_<3-δ> and its Cathodic Property in Alkaline Solution" Denki Kagaku. 64・10. 1084-1089 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Esaka: "Alkali Ion Conduction in the Substituted Phase Based on Scheelite-type Oxide" Solid State Ionics. 86-88. 73-76 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kamata: "Studies on the Lithium Ion Conduction in Ca_<0.95>Li_<0.10>WO_4 using Cold Neutron Radiography" Solid State Ionics. 91,3-4. 303-306 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Esaka: "Oxide Ion Conduction in the Sm-substituted PbWO_4 Phases" Solid State Ionics. 92,1-2. 129-133 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Eguchi: "Power Generation Characteristics of Solid Oxide Fuel Cell with Internal Steam Reforming of Methane" Denki Kagaku. 64,6. 596-601 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Eguchi: "Power Generation and Steam Electrolysis Characteristics of Electrochemical Cell with a Zirconia-or Ceria-Based Electrolyte" Solid State Ionics. 86-88. 1245-1249 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Eguchi: "Effect of Concentration Overvoltage on Power Generation Characteristics of Solid Oxide Fuel Cells" Journal of the Electrochemical Sociey. 143. 3699-3703 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Watanabe: "Molecular Design of Ion and Ion/Electron Mixed Conducting Polymers" Macromolecular Symposia. 105. 229-233 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.M.Sukeshini: "Transport and Electrochemical Characterization of Plasticized Poly(vinyl chloride)Solid Electrolytes" Solid State Ionics. 86-88. 385-393 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Watanabe: "Conductivity Study of Ionic Liquid/polymer Complexes" Solid State Ionics. 86-88. 353-356 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 渡邉正義: "イオン導電性ポリマーの開発の現状" ソーダと塩素. 47. 313-317 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 渡邉正義: "高分子固体電解質-高分子中でのイオン移動・解離過程" 新素材. 7・11. 32-38 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Takeshi Yao: "Novel Method for Zirconium Oxide Synthesis from Aqueous Solution" Journal of the Amerian Ceramic Society.

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Oe: "Toughening of ion conductive zirconia ceramics utilizing non-linear effect" Solid State Ionics. 91. 131-136 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Jung: "Modified CuO Surface Appropriate for Selective CO Gas Sensing at Cuo/ZnO Heterocontact" Journal of Ceramic Society of Japan. 104・5. 415-421 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Ariga: "Electric Control the Chemical Reaction at the Ceramic pn Heterocontact" Japanese Sensor Newsletter. 10・4. 25-27 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N.Motohira: "Single Crystal Growth and Electric Properties of Lanthanum and Gadolinium Doped BaTiO_3" Journal of Ceramic Society of Japan. 104・4. 273-276 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Sone: "Reversible Electrochromic Performance of Prussian blue with Proton Conductive Ta_2O_5・nH_2O film" Solid State Ionics. 1-2. 135-143 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Kishimoto: "Strength distributions of titania ceramics after high voltage screening" Journal of Materials Science. 31. 3419-3425 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Zempachi Ogumi: "Novel Method for Preparing Nickel/YSZ Cermet by a Vapor-Phase Process" J.Am.Ceram.Soc.78. 593-598 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Minoru Inaba: "Raman Spectra of LiCo_<1-y>Ni_yO2" Chem.Lett.1995. 889-890 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Atsushi Mineshige: "Preparation of Yttria-Stabilized Zirconia Microtube by Electrochemical Vapor Deposition" J.Amer.Ceram.Soc.78. 3157-3159 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Tsutomu Ioroi: "Oxygen Reduction at the Interface YSZ/LaMnO_3 Prepared by a Vapor Phase Processes" Proceedings of the Fourth International Symposium on Solid Oxide Fuel Cell. PV95-1. 603-611 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Esaka: "Formation of Oxide Ion Conductive Phase in the Substututed Oxide System Based ZnTiO_4" Solid State Ionics,. 76. 237-242 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Kamata: "Application of Neutron Radiography to Visuallize the Distribution of Lithium in Lithium Battery" Denki Kagaku. 63. 1063-1065 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Kamata: "Application of NR for Research in Electrochemical Systems" Molten Salt. 38. 129-140 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 江坂享男: "イオン伝導性酸化物合成の最近の話題" 電気化学. 63. 789-793 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Horimoto: "Nonstrichiometry of Sintered Oxide Ca_<0.9>La_<0.1>MnO_<3-δ> and its Cathodic Properties in Alkaline Solutions" J.Electrochem.Soc.143. 567-570 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Esaka: "Alkali Ion Conduction in the Substituted Phase Based on Scheelite-type Oxide" Solid State Ionics. (発表予定).

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Eguchi: "An effect of anodic reaction on the current-voltage characteristics of solid oxide fuel cells" Chemistry Letters. 1995. 963-964 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Eguchi: "Power generation and steam electrolysis characteristics of electrochemical cell with a zirconia-or ceria-based electrolyte" Solid State Ionics. (発表予定).

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      1995 Annual Research Report
  • [Publications] 須貝和人: "同時荷重印加における見かけ強度分布への厚み偏差の影響" J.Ceram.Soc.Jpn.103. 1082-1084 (1995)

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  • [Publications] 遠藤是知: "双峰性強度分布をもつセラミックス部材への高電圧スクリーニング" J.Ceram.Soc.Jpn.103. 1090-1092 (1995)

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  • [Publications] A.Kishimoto: "Effect of high voltage screening on strength distribution for TiO_2 ceramics" J.Am.Ceram.Soc.78. 2248-2250 (1995)

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      1995 Annual Research Report
  • [Publications] K.Sugai: "Systematic evaluation of strength distribution in dielectric ceramics through simultaneous loading" J.Ceram.Soc.Jpn.103. 730-732 (1995)

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      1995 Annual Research Report
  • [Publications] A.Ishida: "Prediction of Fracture from Electrical Resistance Measurements in Electrically Conductive Composites" J.Ceram.Soc.Jpn.103. 576-581 (1995)

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  • [Publications] H.Nagasaka: "Electron Transfer Reaction between Fixed Redox Sites in Ion/Electron Mixed Conducting Polymers" Synthetic Metals. 69. 557-558 (1995)

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      1995 Annual Research Report
  • [Publications] H.Nagasaka: "Structural Effects of Redox Active Sites on Electron Hopping Ratein Mixed Conducting Copolymers" Polym.Adv.Tech.6. 190-196 (1995)

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      1995 Annual Research Report
  • [Publications] M.Watanabe: "Ionic Conductivity of Polymer Electrolytes Containing Room Temperature Molten Salts Based on Pyridinium Halide and Aluminium Chloride" Electrochim.Acta.40. 2285-2288 (1995)

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  • [Publications] M.Watanabe: "Effects of Network Structures and Incorporated Salt Species on Electrochemical Properties of Polyether-based Polymer Electrolytes" Solid State Ionics. 79. 306-312 (1995)

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      1995 Annual Research Report
  • [Publications] M.Watanabe: "Redox Activity of Vinylferrocene Copolymers by Electron Hoppping Reaction in the Absence of Fluid Solvents" J.Phys.Chem.99. 12294-12300 (1995)

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  • [Publications] A.M.Sukeshini: "Transport and Electrochemical Characterization of Plasticized Poly(vinyl chloride)Solid Electrolytes" Solid State Ionics. (発表予定).

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      1995 Annual Research Report
  • [Publications] M.Watanabe: "Conductivity Study on Ionic Liquid/Polymer Complexes" Solid State Ionics. (発表予定).

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  • [Publications] M.Watanabe: "Molecular Design of Ion and Ion/Electron Mixed Conducting Polymers" Macromolecular Symposia,. 46. 25-30 (1995)

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  • [Publications] 渡辺正義: "導電性高分子の新展開-化学エネルギー・情報変換を司る高分子" 化学工業. 46. 369-374 (1995)

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  • [Publications] 渡辺正義: "高分子イオニクス材料の挑戦-イオン導電率の最高値は?" 高分子. 44. 312-313 (1995)

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  • [Publications] 渡辺正義: "イオン/電子混合伝導性高分子錯体中の電子移動反応" 化学工業. 46. 369-374 (1995)

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Published: 1995-04-01   Modified: 2016-04-21  

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