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Novel Environmental Catalysts for Practical Applications.

Research Project

Project/Area Number 07242101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

IWAMOTO Masakazu  HOKKAIDO UNIVERSITY, CATALYSIS RESEARCH CENTER, PROFESSOR, 触媒化学研究センター, 教授 (10108342)

Co-Investigator(Kenkyū-buntansha) MOCHIDA Isao  KYUSHU UNIVERSITY, INSTITUTE OF ADVANCED MATERIAL STUDY, PROFESSOR, 機能物質科学研究所, 教授 (20037758)
KAGAWA Shuichi  NAGASAKI UNIVERSITY, DEPARTMENT OF APPLIED CHEMISTRY, PROFESSOR, 工学部, 教授 (80037746)
EGUCHI Koichi  KYUSHU UNIVERSITY, GRADUATE SCHOOL OF ENGINEERING SCIENCES, PROFESSOR, 大学院・総合理工学研究科, 教授 (00168775)
YAMADA Muneyoshi  TOHOKU UNIVERSITY GRADUATE SCHOOL OF ENGINEERING, PROFESSOR, 大学院・工学研究所, 教授 (40091764)
荒井 弘道 (荒井 弘通)  九州大学大学院, 総合理工学研究科, 教授 (10011024)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥73,700,000 (Direct Cost: ¥73,700,000)
Fiscal Year 1997: ¥14,800,000 (Direct Cost: ¥14,800,000)
Fiscal Year 1996: ¥22,900,000 (Direct Cost: ¥22,900,000)
Fiscal Year 1995: ¥36,000,000 (Direct Cost: ¥36,000,000)
Keywordssolid catalyst / material catalyst / catalyst design / solid state reaction field / environmental catalyst / unique reaction field / design of active site / 分子ダイナミックス / 環境化学 / 深度脱硫 / 窒素酸化物 / 触媒 / ゼオライト / 環境科学 / 湿度脱硫
Research Abstract

In the research group for hydrodesulfurization, it has been found that a mixture of metal oxide and zeolite was active for the reaction and the active site in Co-Mo catalysts is the Co ion interacted with Mo ions. The researchers for deNOx systems have confirmed the two-stage oxidation of Cu+ ions to CuィイD22+ィエD2 ions depending on the reaction temperature and the degree of ion exchange. The new method in which a reductant is introduced between the oxidation catalyst of NO to NOィイD22ィエD2 and the reduction catalyst of NOx has been evidenced to be very useful to increase the effectiveness of the reductant.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (47 results)

All Other

All Publications (47 results)

  • [Publications] H.Takeda,et.al.: "Readtion of Adsorbates Derived from cyanuric Acid on a Cu-MFI Zeolite with Nitrogen Oxide and Oxygen"Catal.Lett.. 38. 21 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Iwamoto,et.al.: "Intermediate Addition of Reductant between an Oxidation and a Reduction Catalyst for Highly Selective Reduction of NO in Excexx Oxyggen"Appl.Catal.B. 17. 259 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Yonemitsu et.al.: "Catalytic Epoxidation of Sutilbene and Its Derivatives with tert-Butyl Hydroperoxide on Mn-MCM-41"J.Catal. 178. 207-213 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H. Takeda, et al: "Reaction of Adsorbates Derived from cyanuric Acid on a Cu-MFI Zeolite with Nitrogen Oxide and Oxygen"Catal. Lett.. 38. 21 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M. Iwamote, et al: "Intermediate Addition of Reductant between an Oxidation and a Reduction Catalyst for Highly Selective Reduction of NO in Excess Oxygen"Appl. Catal. B. 17. 259 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M. Yonemitsu et al.: "Catalytic Epoxidation of Stilbene and its Deiivativee with tert-Butyl Hydroperoxide on Mn-MCM-41"J. Catal.. 178. 207-213 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Iwamoto: "Oxidation of NO_2 on a Pt-MFI Zeolite and Subsequent Reduction of NOx by C_2H_4 on an In-MFI Zeolite:a Novel de-NOx Strategy in Excess Oxygen" J.Chem.Soc.,Chem.Commun.37-38 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Iwamoto: "Migration of copper ions in Cu-MFI without Destruction of Zeolite Lattice or Dealumination upon Hydrothermal Treatment at 923K" Chemistry Letters. 1281-1282 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Iwamoto: "Highly Selective Reduction of NO in Excess Oxygen through the Intermediate Addition of Reductant (IAR) between Pt-and Zn-MFI Zeolites" Chemistry Letters. 1283-1284 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 岩本正和: "ディーゼルNOx浄化触媒" ペトロテック. 20. 719-724 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] W.F.Shangguan: "Kinetics of soot-O_2,soot-NO and soot-O_2-NO reactions over spinel-type CuFe_2-O_4 catalyst" Applied Catalysis B:Environmental. 12(2-3). 237-247 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.M.Setoguchi: "Rapid Room Temperature Synthesis of Hexagonal Mesoporous Silica Using Inorganic Silicate Sources and Cationic Surfactants under Highly Acidic Conditions" Journal of Porous Materials. 4(2). 129-134 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Harada: "Perpovskite-type Oxides as Catalysts for Selective Reduction of Nitric Oxide by Ethylene" Applied Surface Science. 121/122. 505-508 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Widjaja: "Oxidation of methane over Pd-supported catalysts" Catalysis Today. 35. 197-202 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Inoue: "Thermal Stability of Hexaaluminate Film Coated on SiC Substrate for High Temoerature Catalytic Combustion" J.Am.Ceram.Soc.,. 80. 584-588 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Inoue: "Preparation of Hexaaluminate Catalyst Thick Films on α-SiC Substrate for High Temperature Appication" J.Materials.Science. 32. 4627-4632 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] X.Ma: "Determination of Sulfur Compounds in Non-polar Fraction of Vacuum Residue" FUEL. 76(4). 329-339 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] I.Mochida: "The Effects of Seeding in the Synthesis of Zeolite MCM-22 in the Presence of Hexa-methyleneimine" Zeolites. 18. 142-151 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] E.Lecrenay: "Catalytic Hydrodesulfurization of Gas Oil and Model Sulfur Compounds over Commercial and Laboratory-made CoMo and NiMo Catalysis:Activity and Reaction Scheme" Catalysis Today. 39. 13-20 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Kasahara: "Inhibiting effects of H_2S on HDS activity of CoMo-,NiMo-,and Mo/Al_2O_3" Catalysis Today. 35. 59-64 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Koizumi: "Effect of Sulfiding Pressure on the Formation on ni site on Ni-Mo/Al_2O_3 and Ni-W/Al_2O_3" Applied Surface Science. 121/122. 429-432 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山田 宗慶: "クリーンフューエルを目指して-水素化精製触媒表面研究の最前線-" 表面. 35(1). 4-12 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山田 宗慶: "深度脱硫を目指して" 触媒. 40(1). 33-44 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 岩本正和: "「自動車排ガス触媒」日本表面科学会:『環境触媒-実際と展望』" 共立出版株式会社, 214 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M. Iwamoto: "Pulse Study on Reactivity of Ethene Adsorbed on Cu-MFI with Nitrogen Oxides and Oxygen" Catal. Today. 27. 71-78 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Takeda: "Reaction of Adsorbates Derived from Cyanuric Acid on a Cu-MFI Zeolite with Nitrogen Oxide and Oxygen" Catal. Lett. 38. 21-25 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Iwamoto: "Heterogeneous Catalysis for Removal of NO in Excess Oxygen Progress in 1994" Catal. Today. 29. 29-35 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Takeda: "Remarkable Difference between the Kinetic Parameters of a Selective Catalytic Reduction of NO by Ethene on a Copper Ion-Exchanged MFI Zeolite and Al_2 O_3" Bull. Chem. Soc. Jpn.69. 2735-2738 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N. Mizuno: "Direct Oxidation of Isobutane into Methacrylic Acid over Cs Ni, and V-substituted H_3PMo_<12>O_<40> Heteropoly Compounds" Studies in Surface and Catalysis. 101. 1001-1010 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Iwamoto: "Assignment of Nonclassical [Cu(CO)n]+(n=1,2) Complex Ions in Zeolite Cages" Inorg. Chem.35. 1918-1921 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N. Nojiri: "Global Overview of Catalysis" Appl. Catal. A. General. 419-428 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "窒素酸化物除去触媒の現状と課題" ケミカルエンジニアリング. 1. 51-56 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "メゾスコピック多孔体の化学" ニューセラミックス. 9. 1-8 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "炭化水素によるNOの選択的還元反応の諸問題" 化学. 64-65 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岩本正和: "エネルギーと地球環境" 日刊工業新聞社, 195 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Iwamoto: "Time-Resolved FT-IR Study on Isotopic Exchange of Dinitrosyl Species Strongly Adsorbed on a Co-MFI Zeolite" Chemistry Letters. 8. 729-730 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Iwamoto: "Pulse Study on Reactivity of Ethene Adsorbed on Cu-MFI with Nitrogen Oxides and Oxygen." Catalysis Today. (in press). (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Abe: " Non-Silica-Based Mesostructured Materials, 1. Synthesis of Vanadium Oxide-Based Material" Chem. Mater.7. 1429-1430 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Abe: "Preparatoin and Characterization of Fe_2O_3 Nanoparticles in Mesoporous Silicate" J. Chem. Soc., Chem. Commun.1617-1618 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] J.Guo: "NOx Reduction Characteristics of Pt-ZSM-5 Catalyst with Diesel Engine Exhaust" JSAE Review. 16. 21-25 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] W. -X. Zhang: "Reversible and Irreversible Adsorption of Nitrogen Monoxide on Cobalt Ion-Exchanged ZSM-5 and Mordenite Zeolites at 273-523 K" J. Chem. Soc. Faraday Trans. 91. 767-771 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. K. Shin: "Effect of Support on Activity of Platinum Catalysts for NO Reduction by Ethene in Excess Oxygen" Appl. Catal.B. (in press). (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Abe: "Effect of Underpotential Deposition (UPD) of Copper on Oxygen Reduction at Pt(111)Surfaces" J. Electroanal. Chem.382. 73-83 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 岩本正和: "ゼオライト触媒によるNOx除去" 触媒. 8巻. 614-622 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 岩本正和: "リーンバーンでのNOの選択還元除去" ペトロテック. 38巻. 850-851 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 八尋秀典: "金属イオン交換ゼオライトによるNOの吸着除去" 表面. 33巻. 44-55 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. K. Shin: "Selective Catalytic Reduction of NO by Ethene in Excess Oxygen Over Pliatnum Ion-Exchanged.MFI Zeolites" Catalysis Today. 26. 13-21 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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