• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Molecular/Atomic Design of Catalytic Sites of High-Performance

Research Project

Project/Area Number 07242103
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionUNIVERSITY OF TOKYO

Principal Investigator

MISONO Makoto  UNIVERSITY OF TOKYO, GRADUATE SCHOOL OF ENGINEERING, PROFESSOR, 大学院・工学系研究科, 教授 (20011059)

Co-Investigator(Kenkyū-buntansha) SEGAWA Koichi  SOPHIA UNIVERSITY, FACULTY OF SCIENCE AND ENGINEERING, PROFESSOR, 理工学部, 教授 (60053675)
IWASAWA Yasuhiro  UNIVERSITY OF TOKYO, GRADUATE SCHOOL OF SCIENCE, PROFESSOR, 大学院・理学系研究科, 教授 (40018015)
IZUMI Yusuke  NAGOYA UNIVERSITY, SCHOOL OF ENGINEERING, PROFESSOR, 大学院・工学研究科, 教授 (00115528)
YOSHIDA Satohiro  KYOTO UNIVERSITY, GRADUATE SCHOOL OF ENGINEERING, PROFESSOR, 大学院・工学研究科, 教授 (00025933)
上野 晃史  静岡大学, 工学部, 教授 (30135420)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥74,100,000 (Direct Cost: ¥74,100,000)
Fiscal Year 1997: ¥14,800,000 (Direct Cost: ¥14,800,000)
Fiscal Year 1996: ¥22,600,000 (Direct Cost: ¥22,600,000)
Fiscal Year 1995: ¥36,700,000 (Direct Cost: ¥36,700,000)
Keywordssolid catalyst / material for catalyst / catalyst design / solid state reaction field / environmental catalyst / unique reaction field / design of active site / molecular dynamics / 触媒 / 触媒表面 / 液相有機合成 / 層状構造の強酸 / 吸着反応性 / 構造の要因 / 構造元素の役割
Research Abstract

The purpose of A01 group was to design active centers for the unique reaction field at atomic/molecular levels, taking into account the clear descriptions of the active centers and actual conditions of environmental catalysis. Successful achievements have been obtained in (1) the fields of heteropolyacids catalysts for molecular design and the application, (2) surface science and theoretical chemistry as tools for catalyst design and (3) model reactions for the proposal of unique reaction fields and the indentification.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] K.Inumaru, et al.: "Porous Aggregates of Unidirectionally Oriented(NH_4)PW_<12>O_<40> Microcrystallites Epitacial Self-Assmply"Chem.Lett.. 7. 559-560 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Ito, et.al.: "Structure of Porous Aggregates of the ammonium Salt of dodecatugsrophosphoric Acid.(NH_4)PW_<12>W_<40>:Unidirectionally Oriented Self-Assembly of Nanocrystalites"J.Phys.Chem.B. 101. 9958-9963 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Kayano et.al.: "Structual Changes of Surface Layer of Vanady Pyrophosphate Catalyate by Oxidation-Reduction and Their Relationships with Selective Oxidation of n-Butane"J.Am.Chem,Soc.. 120. 767-774 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K. Inumaru, et al.: "Porous Aggregates of Unidirectionally Oriented (NHィイD24ィエD2)ィイD23ィエD2PWィイD212ィエD2OィイD240ィエD2 Microcrystallites : Epitaxial Self-Assemply"Chem. Lett.. 7. 559-560 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Ito, et al.: "Structure of Porous Aggregates of the Ammonium Salt of Dodecatungstophosphoric Acid, (NHィイD24ィエD2)ィイD23ィエD2PWィイD212ィエD2WィイD240ィエD2 : Unidirectionally Oriented Self-Assembly of Nanocrystalites"J. Phys. Chem B. 101. 9958-9963 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G. Koyano et al.: "Structural Changes of Surface Layer of Vanadyl Pyrophosphate Catalysts by Oxidation-Reduction and their Relationships with Selective Oxidation of n-Butane"J. Am. Chem. Soc.. 120. 767-774 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Ito et al: "Structure of Porous Aggregates of the Ammonium Salt of Dodecatungstophosphoric Acid,(NH_4)_3PW_<12>W_<40>:Unidirectionally Oriented Self-Assembly of Nanocrystalites" J.Phys.Chem.B. 101. 9958-9963 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Izumi: "Hydration/Hydrolysis by solid Acids" Catal.Today. 33. 371 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Okamoto, et al: "Zirconia-supported copper catalysts for NO-CO reactions.Surface copper species on zirconia" J.Chem.Soc.,Faraday Trans.93・21. 3879-3885 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Pophal,C, et al: "Selective catalyticreduction of N_2O by C_3H_6 over Fe-MFI" Catal.Lett.44. 271-274 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Iwasawa: "Surface Catalytic Reactions Assisted by Gas Phase Molecules" Acc.Chem.Res.30. 103-109 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Inumaru,et al: "Porous Aggregates of Unidirectionally Oriented(NH_4)_3PW_<12>O_<40> Microcrystallites:Epitaxial Self-Assemply" Chem.Lett.559-560 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Izumi: "Iminium Salt-catalyzed Liquid-phase Beckmann Rearrangement of Cyclohexanone Oxime" J.Mol Catal. 106. 43- (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Yoshida: "Study on the Dispersion of Nickle lons in NiO-MgO System by X-Ray Absortpion Fine Structure" J.Phys.Chem. 100. (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.C.Ilao: "Shape-Selective methylamine synthesis over small porezeolite catalysts" Journal of Catalysis. 161. 20-30 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Yamaguchi: "Catalytic Decomposition Reacrion of Formic Acid on an Ar^+-bombaraded TiO_2(110)Surface:Steady-state Kinetics and Microscopic Surface Structure" J.Chem.Soc.Faraday Trans. 91. 1663-1668 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Na, et al: "Skeletal isomerization of n-butane over cesium hydrogen salts of 12-tungstophosphoric acid" J. Chem. Soc. Faraday Trans.91. 367-373 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S. Takenaka, et al: "Photooxidation of propane over alkali-ion-modified V_2O_5/SiO_2 catalysts" J. Catal.155. 196-203 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Yoshida, et al: "Study of dehydration of magnesium hydroxide" J. Phys. Chem.99. 10890-10896 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 瀬川幸一ら: "層状フォスフォン酸ジルコニウムの分子設計と触媒作用" 触媒. 37. 623-629 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Sueyoshi, et al: "Catalytic CO oxidation on unreconstructed Cu (110) observed at low temperatures" Chem. Phys. Lett.241. 189-194 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] N. Kakuta, et al: "Preparation of spherical and porous SiO_2 particles by fume pyrolysis" Preparation of Catalysts. VI. 319-326 (1995)

    • Related Report
      1995 Annual Research Report

URL: 

Published: 1995-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi