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Studies on the development of selective separation and analyzes for the chemical speciation and characterization of trace elements and molecules

Research Project

Project/Area Number 07304048
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section総合
Research Field 分離・精製・検出法
Research InstitutionOKAYAMA UNIVERSITY

Principal Investigator

MOTOMIZU Shoji  OKAYAMA UNIVERSITY,FACULTY OF SCIENCE,PROFESSOR, 理学部, 教授 (50032826)

Co-Investigator(Kenkyū-buntansha) MATSUI Masakazu  KYOTO UNIV., INSTITUTE FOR CHEMICAL RESEARCH,PROF., 化学研究所, 教授 (90027037)
KUMAMARU Takahiro  HIROSHIMA UNIV., FACULTY OF SCIENCE,PROF., 理学部, 教授 (50033816)
KAWASHIMA Takuji  TSUKUBA UNIV., DEPARTMENT OF CHEMISTRY,PROF., 化学系, 教授 (50041760)
AKAIWA Hideo  GUNMA UNIV., FACULTY OF ENGINEERING,PROF., 工学部, 教授 (60008414)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥9,600,000 (Direct Cost: ¥9,600,000)
Fiscal Year 1996: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 1995: ¥5,600,000 (Direct Cost: ¥5,600,000)
Keywordstrace elements / speciation / characterization / separation methods / analytical methods / environmental samples / biological samples / new materials・highly pure reagents / 生体試料 / 化学的存在形態識別 / 選択的分離分析法 / 分子認識機能性試薬 / 高選択的高倍率濃縮分離法 / 重金属イオン / 窒素・リン・ヒ素 / 錯化容量
Research Abstract

Novel methodology for the speciation and characterization of trace elements and molecules was studied. The methods for the selective separation and the sensitive detection were developed for the analyzes of environmental samples, biological samples, new materials and highly pure materials. The project were carried out in main four fields described as follows : (a) synthesis and analytical utilization of novel organic reagents for the separation and detection were studied for developing excellent molecular-recognition reagents by. H.Nakamura, M.Matsui and S.Motomizu ; (b) the development of novel reactions and their reaction mechanisms for analytical chemistry were studied by T.Kawashima, S.Funahashi and T.Kumamaru ; (c) the development and analytical use of selective separation and concentraiton methods were studied by H.Akaiwa, K.Oguma, H.Nakamura and H.Watarai ; (d) the development of new instruments and methodologies for sensitive detection was studied by K.Matsumoto, S.Tsuge, K.Fugiwara and K.Yoshimura.
Two symposiums were held in November 1995 and in November 1996, and the meetings for discussing the proceeding of the project were held in September 1995 and in September 1996.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (66 results)

All Other

All Publications (66 results)

  • [Publications] Y.Suzuki: "Energy transfer luminescence of Tb^3'cmplexed with oxyethylene compounds containing Xanthene" Chemistry Letters. 1996. 547-548 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Teshima: "Effect of 2,2'-bipyridine and 1,10-phenanthroline on the redox reaction of metal ions and its application to…" Bulletin of the Chemical Society of Japan. 69巻. 1975-1979 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Tsunoda: "Sensitive spectrophotometric detection of silicic acid in pure water with slab optical waveguid detector" Chemistry Letters. 1996. 919-920 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hamase: "Curdlan gel as a bioinert support for the electrophoresis of biologically active proteins" Analytical Sciences. 12巻. 273-275 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Yuan: "Fluorescence enhancement by electron-withdrawing groups on bi-diketones in Eu(III)-β-diketonato-topo ternary complexes" Analytical Sciences. 12巻. 31-36 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Oshima: "Determination of phosphorus as aggregates of ion associates by light-scattering detection and application to flow…" Analast(London). 121巻. 1085-1088 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 本水昌二: "最新の分離・情製・検出法:イオン会合型試薬" エヌ・ティー・エス(印刷中), (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 赤岩英夫: "機器分析ガイドブック(編集委員)" 丸善, 1093 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Motomizu et al.: "Electrical conductivity detection/ion chromatography using a suppressor method based on ion association/micelle extraction" Bunseki Kagaku. 44. 1041-1048 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Motomizu et al.: "Ultratrace determination of phosphate ion based on filtraion-dissolution and flow-through spectrophotometric measurement" Anal.Sci.11. 155-160 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sugawara et al.: "Electrochemical behavior of sugar investigated using a carbon electrode modified with copper (II) -porphyrin" J.Electroanal.Chem.394. 263-265 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] R.Tahara et al.: "Synthesis and complexing behavior of a new fluorescent ligand using interaction between two substituents" Chem.Lett.1995. 753-754 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Itabashi et al.: "Flow-injection determination of chromium (VI) based on redox reaction of chromium (VI) with iron (II) and copper (II) with iron (II) in the presence of diphosphate and neocuproin" Anal.Sci.11. 693 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Suzuki et al.: "Distribution behavior of metal 4- (2-thienyl) -4-thioxo-1,1,1-trifluoro-2-butanonates in reversed HPLC" Anal.Sci.11. 39-43 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Q.Wang et al.: "Extraction chromatographic behavior of zirconium and hafnium using sulfoxides as stationary phases" Anal.Sci.11. 909-913 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Takayanagi and S.Motomizu: "Analysis of ion association property of aromatic divalent anions with quaternary ammonium ions in aqueous solution through mobility change of capillary electrophoresis" Chem.Lett.1995. 593-594 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Motomizu et al.: "Photo-induced reduction of nitrate to nitrite and its application to the sensitive determination of nitrate in natural waters" Anal.Chim.Acta. 308. 406-412 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Gao, S.Motomizu et al.: "Flow-injection spectrophotometric determination of magnesium with Xylylazo Violet I" J.Flow Injection.Anal.12. 77-84 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.P.Susanto, S.Motomizu et al.: "Adsorption-concentraion of ion associate formed between molybdosilicate and malachite green on a miniature filter : Its application to trace and ultratrace determination of silicon" Analyst (London). 120. 2605-2611 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Motomizu et al.: "Fluorimetric determination of phosphate in sea water by flow injection analysis" Anl.Sci.and Tech.8. 843-848 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Gao, S.Motomizu: "Determination of ionic surfactants based on ion association in an aqueous medium" Bunseki Kagaku. 45. 1065-1082 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Takayanagi, S.Motomizu et al.: "Separation and direct photometric determination of inorganic anions by capillary zone electrophoresis using suppressed electroosmosis" Anal.Sci.12. 575-579 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Takayanagi, S.Motomizu et al.: "Direct photometric detection of inorganic anions by capillary zone electrophoresis using stacking effect of sulfate ion on sample ions" Bunseki Kagaku. 45. 697-699 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Takayanagi, S.Motomizu et al.: "Ion association reaction between divalent anionic azo dyes and hydrophobic quaternary ammonium ions in aqueous solution as studied by capillary zone electrophoresis" Anal.Sci.13. 11-18 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Takayanagi, S.Motomizu et al.: "Electrophoretic mobility study of ion association formed between aromatic anions and quaternary ammonium ions in aqueous solution" Analyst (London). 122. 57-62 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Suzuki et al.: "Energy transfer luminescence of Tb^<31> complexed with oxyethylene compounds containing Xanthene" Chem.Lett.1996. 547-548 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Teshima et.al.: "Effect of 2,2' -bipyridine and 1,10-phenanthroline on the redox reaction of metal ions and its application to potentiometric titrations of vanadium (IV) and cobalt (II)" Bull.Chem.Soc.Jpn. 69. 1975-1977 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Tsunoda et al.: "Sensitive spectrophotometric detection of silicic acid in pure water with slab optical waveguid detector" Chem.Lett.1996. 919-920 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hamase et al.: "Curdlan gel as a bioinert support for the electrophoresis of biologically active proteins" Anal.Sci. 12. 273-275 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Yuan et al.: "Fluorescence enhancement by electron-withdrawing groups on bi-diketones in Eu (III) -beta-diketonato-topo ternary ・・・" Anal.Sci.12. 31-36 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Suzuki: "Energy transfer Iuminescence of Tb^<3+> complexed with oxyethylene compounds containing Xanthene" Chemistry Letters. 1996. 547-548 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N.Teshima: "Effect of 2,2′-bipyridine and 1,10-phenanthroline on the redox reaction of metal ions and its application to poteniometric ・・・・" Bulletin of the Chemical Society of Japan. 69. 1975-1979 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Tsunoda: "Sensitive spectrophotometric detection of silicic acid in pure water with slab optical waveguid detector" Chemistry Letters. 1996. 919-920 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Hamase: "Curdlan gel as a bioinert support for the electrophoresis of biologically active proteins" Analytical Sciences. 12. 273-275 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.Yuan: "Fluorescence enhancement by electron-withdrawing groups on bi-diketones in Eu(III)-β-diketonato-topo ternary complexes" Analytical Sciences. 12. 31-36 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Oshima: "Determination of phosphorus as aggregates of ion associates by light-scattering detection and application to flow injection" Analyst (London). 121. 1085-1088 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 本水昌二: "最新の分離・精製・検出法 : イオン会合型試薬" エヌ・ティー・エス(印刷中), (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 赤岩英夫: "機器分析ガイドブック(編集委員)" 丸善, 1093 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Sugawara: "Electrochemical behavior of sugar investigated using a carbon electrode modified with copper (II) -porphyrin" Journal of Electroanalytical Chemistry. 394. 263-265 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] R.Tahara: "Synthesis and complexing behavior of a new fluorescent ligand using interaction between two substituents" Chemistry Letters. 1995. 753-754 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Itabashi: "Flow-injection determination of chromium (VI) based on redox reaction of chromium (VI) with iron (II) and copper (II) with iron (II) in the・・" Analytical Sciences. 11. 693-694 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Nakano: "Flow-injection photometric determination of nanogram levels of iron based on the catalysis of oxidative coupling of・・・・・・" Talanta. 42. 1051-1056 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Suzuki: "Distribution hebavior of metal 4- (2-thieny1) -4-thioxo-1,1,1-trifluoro-2-butanonates in reversed-phase HPLC" Analytical Sciences. 11. 39-43 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Q.Wang: "Extraction chromatographic hebavior of zirconium and hafnium using sulfoxides as stationary phases" Analytical Sciences. 11. 909-913 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.-L.Wu: "A computer-controlled variable-volume injector for flow injection anlysis" Analysis Sciences. 11. 401-404 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.-Q.Feng: "Retention behavior of metal complexes with 5-sulphoquinoline-8-ol in reversed-phase ion pair liquid chromatography" Chromatographia. 41. 532-538 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] A.Sano: "Determination of L-ascorbic acid by a flow injection analysis with copper (II) -mediated electrochemical detection" Analytical Sciences. 11. 405-409 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Z.Long: "Chiral separation by curdlan gel electrophoresis" Analytical Sciences. 11. 663-665 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] J.Yuan: "Flurescence enhancement by electron-withdrawing groups on β-diketones in Eu (III) -β-diketonato-topo ternary complexes" Analytical Sciences. 12. 31-36 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Kagawa: "Kinetic study on complexation of boric acid with 4-isopropyltropolone in nonaqueous solvents" Inorganica Chimica Acta. 231. 115-119 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Aizawa: "Variable-temperature and-pressure multinuclear magnetic resonance studies on solvent exchange of cobalt (II),iron (II) and manganese (II)" Inorgainc Chemistry. 34. 2042-2047 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Tsurubou: "Improved extraction-separation of alkaline earths and lanthanides using crown ethers as ion size selective masking reagents" Analytical Chemistry. 67. 1465-1469 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Sohrin: "Control of ligand field strength through intra-and interligand contact. Octahedral iron (II) poly (pyrazolyl) borate complexes" Inorganic Chemistry. 34. 3928-3934 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Watarai: "Interfacial reaction in the synergistic extraction rate of Ni (II) with dithizone and 1,10-phenanthroline" Talanta. 42. 1691-1696 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Watarai: "Total internal reflection fluorescence measurements of ion-associat-ion adsorption of water-soluble porphyrins at liquid/liquid interface" Chemistry Letters. 1995. 283-284 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] J.P.Susanto: "Determination of microamounts of phosphorous with malachite green using a filtration-dissolution preconcentration method and flow・・・" Analyst (London). 120. 187-191 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Motomizu: "Ultratrace determination of phosphate ion based on filtration-dissolution and flow-through spectrophotometric measurement" Analytical Sciences. 11. 155-160 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Sakai: "Sensitivity enhancement in the determination of silicate by ion-exclusion chromatography using luminol chemiluminescence detection" Analytica Chimica Acta. 302. 173-177 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Fujiwara: "Effect of iron (III) on chemiluminescence from the neutralization reaction of nitric acid and potassium hydroxide" Photochem.Photobiol.62. 439-443 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Ono: "Thermal lens produced in a nematic liquid crystal" Appl.Spectrosc.49. 1189-1192 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Matsuoka: "Application of ion-exchanger phase absorptiometry to flow analysis. Determination of vanadium (V) in natural water" Analytica Chimica Acta. 317. 207-213 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 河嶌拓治,本水昌二他: "分析化学" 東京教学社, 217 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 舟橋重信他: "無機化学" 講談社サイエンティフィク, 292 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Matsui et al.: "Speciation of Organoarsenical Compounds in the Hydrosphere" Terra Scientific Publication Company, 129-138 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Fujiwara et al.: "Encyclopedia of Analytical Science" Academic Press, 3950-3956 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Yoshimura: "Encyclopedia of Analytical Science" Academic Press, 3286-3294 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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