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COMPREHENSIVE STUDIES ON DESIGNING OF FINE STRUCTURE AND FUNCTIONS OF THE INTERFACES

Research Project

Project/Area Number 07305034
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section総合
Research Field 化学工学一般
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

HARADA Makoto  KYOTO UNIVERSITY,INSTITUTE OF ADVANCED ENERGY,PROFESSOR, エネルギー理工学研究所, 教授 (90027128)

Co-Investigator(Kenkyū-buntansha) HIGASHITANI Ko  KYOTO UNIVERSITY,DEPARTMENT OF CHEMICAL ENGINEERING,PROFESSOR, 工学研究科, 教授 (10039133)
OKAZAKI Morio  KYOTO UNIVERSITY,DEPARTMENT OF CHEMICAL ENIGINEERING,PROFESSOR, 工学研究科, 教授 (90025916)
MIYAKE Yoshikazu  KANSAI UNIVERSITY,DEPARTMENT OF CHEMICAL ENGINEERING,PROFESSOR, 工学部, 教授 (70111995)
UEOKA Ryuichi  KUMAMOTO INSTITUTE OF TECHNOLOGY,DEPARTMENT OF APPLIED CHEMISTRY,PROFESSOR, 工学部, 教授 (70099076)
NAKASHIO Fumiyuki  KYUSYU UNIVERSITY,DEPARTMENT OF CHEMICAL SCIENCE AND TECHNOLOGY,PROFESSOR, 工学部, 教授 (70037729)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥15,000,000 (Direct Cost: ¥15,000,000)
Fiscal Year 1996: ¥4,800,000 (Direct Cost: ¥4,800,000)
Fiscal Year 1995: ¥10,200,000 (Direct Cost: ¥10,200,000)
KeywordsFINE STRUCTURE / MOLECULAR ASSEMBLIES / POLYMER SOLUTIONS / FINE PARTICLES / STRUCTURED FLUIDS / INTERACTIONS BETWEEN PARTICLES / PHENOMENOLOGICAL THEORIES OF STRUCTURE FORMATION / INTERFACE FUNCTIONS / 微細構造形成 / 高分子 / 複合材料 / 自己組織化 / 材料プロセス / 超微粒子 / パーコレーション / タンパク質 / 電気粘性流体
Research Abstract

The aims of this work are to elucidate the self-organized structure and the functions of the interfaces in each system of molecular assemblies, polymers, fine particles and composite materials, and also to extract the scientific and technological bases common to each system.
1.Fine structure formation and its functions : (1) Molecular assemblies systems ; The mechanism of molecular assemblies formation was elucidated for amphiphilic molecular systems. The functions of the molecular assemblies such as reversed micelles and vesicles were also elucidated by focussing on inorganic ultrafine particle formation, protein separations, enzymatic reactions and enantio-recognition. (2) Polymer systems ; The processes of reaction-and evaporation-induced fine structure formation and the structure of polymer-networks were elucidated. We also studied the separation abilities of polymer thin membranes, the inhomogeneous structure formation in the membrane and the polymer particle formation processes. (3) Fine particles systems : The structure near a particle and the interaction between particles in solutions were experimentally investigated, and also the origin of short and extra long-ranged interactions were theoretically elucidated. Ordering of fine particles induced by electric and shear fields was also elucidated with the aids of computer simulations. (4) Composite materials systems ; Percolation structure of grains, crystal growth process in plating and amorphous structure of sugars on proteins were elucidated.
2.Common bases for fine structure formations : We extracted the phenomenological methodology for integrating the fine structure formation, and finally proposed future development of this work to "molecular-and particulate-tectonics".

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report

Research Products

(61 results)

All Other

All Publications

  • [Publications] M. Kinoshita: "Interaction between Macroparticles in Aqueous Electrolytes" Journal of Chemical Physics. 105. 2487-2499 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Kinoshita: "Interaction between Macroparticles in Lennard-Jones Fluids or in Hard-Sphere Mixtures" Journal of Chemical Physics. 105. 7177-7183 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Kinoshita: "Interaction between Macropartcles in a Simple Model System of a Non-polar Liquid Containing Trace Amounts of Water" Journal of Chemical Physics. 105. 7184-7191 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A. Shioi: "Static Light Scattering from Oil-rich Microemulsions Containing Polydispersed Cylindrical Aggregates in Sodium Bis (2ethylhexyl) Phosphate System" Journal of Physical Chemistry. 99. 4750-4756 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A. Shioi: "Model for Geometry of Surfactant Assemblies in the Oil-rich Phase of Winsor II Microemulsions" Journal of Chemical Engineering of Japan. 29. 95-104 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A. Shioi: "X-ray and Light Scattering from Oil-rich Microemulsions Containing Sodium Bis (2ethylhexyl) Phosphate" Langmuir. 12. 3201-3205 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.KINOSHITA: "INTERACTION BETWEEN MACROPARTICLES IN AQUEOUS ELECTROLYTES" JOURNAL OF CHEMICAL PHYSICS. 105. 2487-2499 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.KINOSHITA: "INTERACTION BETWEEN MACROPARTICLES IN LENNARD-JONES FLUIDS OR IN HARD SPHERE MIXTURES" JOURNAL OF CHEMICAL PHYSICS. 105. 7177-7183 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.KINOSHITA: "INTERACTION BETWEEN MACROPARTICLES IN A SIMPLE MODEL SYSTEM OF A NON-POLAR LIQUID CONTAINING TRACE AMOUNTS OF WATER" JOURNAL OF CHEMICAL PHYSICS. 105. 7184-7191 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.SHIOI: "STATIC LIGHT SCATTERING FROM OIL-RICH MICRO-EMULSIONS CONTAINING POLYDISPERSED CYLINDRICAL AGGREGATES IN SODIUM BIS (2-ETHYLHEXYL) PHOS-PHATE SYSTEM" JOURNAL OF PHYSICAL CHEMISTRY. 99. 4750-4756 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.SHIOI: "MODEL FOR GEOMETRY OF SURFACTANT ASSEMBLIES IN THE OIL-RICH PHASE OF WINSOR II MICROEMULSIONS" JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 29. 95-104 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.SHIOI: "X-RAY AND STATIC LIGHT SCATTERING FROM OIL-RICH MICROEMULSIONS CONTAINING SODIUM BIS (2-ETHYLHEXYL) PHOSPHATE" LANGMUIRE. 12. 3201-3205 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Shioi: "X-ray and Light Scattering from Oil-Rich Microemulsions Containing Sodium Bis(2-ethylhexyl)Phosphate" Langmuir. 12・13. 3201-3205 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kurumada: "Dynamical Behavior and Structure of Concentrated Water-in-Oil Miaoenulsions in the Sodium Bis(2ethylhexyl)Sulfosuccimate syste" J.Phys.Chem.100・3. 1020-1026 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Goto: "Enzymatic Resolution of Racemic Ibuprofen by Surfactant-Coated Lipases in Organic Media" Biotechnol.Letters. 18・7. 839-844 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Ono: "Extraction Behavior of Hemoglobin Using Reversed Micelles by Dioleyl Phosphoric acid" Biotechnol.Prog.12・6. 793-800 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kinoshita: "Interaction between macroparticles in a simple model system of a nonpdar liquid containing trace a mount of water" J.Chem.Phys.105・16. 7184-7191 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kinoshita: "Interaction between macroparticles in aqueous electrolytes" J.Chem.Phys.105・6. 2487-2499 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Sato: "Mechanism of Foruration of Metal Sulfide Ultrafine Particles in Reverse Micelles Usiug a Gas Injection Metho" Ind.Eng.Chem.Res.36・1. 92-100 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Tobita: "Kinetics of Free-Radical Polymerization with Chain-Length-Dependent Bimolecular Termination Under Unstatio Conditions" Macro molecules. 29・9. 3073-3080 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Tobita: "Random Degradation of Branched Polymers.2.Multiple Branches" Macromolecules. 29・8. 3010-3021 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kondo: "AFM Study on Morphology Evaluation of Zinc Electrodeposits" ISIJ International. 37・2. 140-145 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] F.Cerwinski: "Atomic Force Microscopy Study of Surface Morphology of Zinc-Iron Electrodeposits" J.Electrochem.Soc.144・2. 481-484 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Mishima: "Prediction of Polyethylene Glycol Microcapsules of Flaronoids Using the Rapid Expansion of Super Critical CO_2" 2nd-International Conf.on Solvothermal Reactions. 69-70 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Higashitani: "Evaluation of Interaction Forces between Surfaces in Electrolyte Solutions by Atomic Force Microscope" J.Chem.Eng.Japan. 30・1. 52-58 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Yoshida: "The Electric Properties of Sintered Cermet as a Continuum Percolation Medium" Fractals. 4. 175-180 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Yoshida: "Effects of Quenching on the Grain Boundary in Sintereal Ag-BPSCCO" Physica Status Solidi. (a)153. K5-K7 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Okamoto: "Selective Permeation of Carbon Dioxide through Aminer Modified Polyimide Membrance" Chem.Lett.613-614 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Tanaka: "Permeation and Seperation Properties of Polyimide Membranes to Olefins and Paraffins" J.Membrane Sci.121. 197-207 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Sato: "Mechanism of Formation of Silver Halides Ultrafine Particles in Reversed Micellar Systems" J.Chem.Eng.Japan. 29・3. 501-507 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kato: "Water Permealility through the Lipid Membrane of a Giant Vesicle Prepared by a Two-Step Emulsification Technique" Solv.Extra.Res.Dev.,Japan. 3. 62-73 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kato: "Preparation of a hybrid-type Nesicle Moclified by concanavalin A for a drug delivery system" Chem.Eng.Symposium. 57. 71-75 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 森 康雄: "粒子分散系電気粘性流体における構造形成" 化学工学シンポジウムシリーズ. 54. 161-168 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Mishima: "Effect of Vinyl Alcohol+Sodium Acrylate Copolymer Gel on the Vapor-Liquid Equilibrium of 1・Propanol+Water" J.Chem.Enh.Data. 41・5. 953-955 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Abe: "Peptide Synthesis by Surfactant-Chymotrpsin Complexes in Organic Media" Biotechnol.Techniques. 11・1. 25-29 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kita: "Carbon Molecular Sieve Membrane Prepared from Phenolic Resin" Chem.Lett.179-180 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.W.Marczewski: "Modeling and analysis of experimental atomic force microscope images of hard colloidal particle" Computers Chem.(印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Ono: "Effect of Organic Solvent Behavior of Cytochrom C Using Reversed Micellar Solutions" Solv.Extr.Res.Dev.Japan. 3. 1-9 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 東谷 公: "化学工学の進歩30微粒子制御(化学工学会編)槙書店" 微粒子の表面ミクロ構造のin-situ 評価法と安定性, 13 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Kurumada: "Dynamical Beharion and Structure of Concentrated Water-in-Oil microemulsions in the Sodium Bis(2-ethylhexyl) phosphate Systems" Journal of Phupical Chemistry. 99. 16982-16990 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Goto: "Engymatic Interesterification of Triglyceride with Sufactant-Coated Lipare in Organic Media" Biotech. Bioeng.45. 27-32 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Goto: "Novel Surfactant-coated EngymesImmobiliyed in Poly (ethylene glycol) Microcapsules" Biotech. Techniques. 9. 81-84 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] N. Kamiya: "Surfactant-Coated Lipase Suitable for the Engymatic Resolution of Menthol as a Biocatalyst in Organic Media" Biotech. Prog.11. 270-275 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Sato: "Mechanism of Formation of Composite CdS-ZnS Ultrafine Partiles in Reverrse Micelles" Ind. Eng. Chem. Res. 34. 2493-2498 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Hirai: "Mechanism of Formation of Lead Sulfide Ultrafine Particles in Revese Micelar Suptems" J. Chem. Eng. Japan. 28. 468-473 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Mishima: "Polymeric Microspheres Formed by Rapid Expansion from Supercritical Carbon Dioxide Solution containing Antisolvent" Proceedings of 4th Asian Thermophysical Properties Conference. 3. 675-678 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Tobita: "Molecular Weight Distribution in Random Branching of Polymer Chains" Macromol. Theory Simul.5. 129-144 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Yoshida: "Precpitation of Impurity Phases and its Effect on the Intergrain Conducting Properties of Ag-Doped Bi(Pb)-Sr-Ca-Cu-O" Superconductor Science & Technology. 8. 329-335 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Yoshida: "Percolation Process in Anisotropic Cluster-Stuclure of a Two-Phase Composite" Materials Science Reseach International. 1. 114-119 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Yoshida: "The Electoric-Properties of Sintered Ceramics as a Continuum Percolation Medium" Fractals. 4. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Yoshida: "A Quenching Effect on the Grain Boundary in Sintered Ag-BPSCCO" Physica Status Solidi(a). 153. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Kato: "Reaction Characteristics of the Membrane Engyme Immobiliyed to a Large Lipid-Vesicle of Hybrid Type and Measuremento of the Vesicle Zeth-Potential" Chem. Eng. Symposium Series. 44. 31-36 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] R. Ueoka: "A Remarkably Enhanced Diastereoselectinity for the Hydrobpis of Dipeptide Esters Responding to pHand Temperature in Buffer Solution" Tetrahedrom Letters. 37. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Okamoto: "Gas Permeation Properties of Poly (ether imide) Segmented Copolymers" Macromolecules. 28. 6950-6956 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] N. Tanihara: "Pervapoation of Organic Liguid Mixtures through Poly (ether imide) Segmented Copolymer Membranes" J. Membr. Sci.104. 181-192 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 山外隆文: "スチレン系熱可塑性エラストマーノ選択溶媒系のキャスト法成膜における溶媒蒸発速度の影響" 日本ゴム協会誌. 68. 750-757 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Mishima: "Reconery of Eicosupentaenoic Acid Ethyl Ester and Docosahexaenoic Acid Ethyl Ester from an Aqueous Two-Phase System Using Supercuitical Fluid Extraction" Solvent Extraction Research and Development, Japan. 2. 204-212 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Kondo: "Morphology Evolution of Zinc-Nickel Binary Alloys Electrodeposited with Pure Current" Journal of Electrochemical society. 142. 2256-2261 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Kondo: "Morphology Evolution of Zino-Nickel Binary Alloys Electrodeposited with Cadmium Additive" Journal of Electrochemical Society. 10. L193-196 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Higashitani: "Simulation of the Ordered Structure LS5 of Binary Colloidal Particles L and S" Adv. Powder Tech.6. 1-9 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 上岡龍一: "超分子化学の基礎と応用" エヌ・ティ・エス, 623 (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1995-03-31   Modified: 2016-04-21  

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