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Standardization of Catalyst Preparations using Reference Catalysts

Research Project

Project/Area Number 07305035
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 触媒・化学プロセス
Research InstitutionUniversity of Tsukuba

Principal Investigator

UCHIJIMA Toshio  University of Tsukuba, Institute of Materials Science, Professor, 物質工学系, 教授 (30010804)

Co-Investigator(Kenkyū-buntansha) MIURA Hiroshi  Saitama University, Facluty of Engineering, Professor, 工学部, 教授 (60092574)
TANAKA Tsunehiro  Kyoto University, Graduate School of Engineering, Associate Professor, 大学院工学研究科, 助教授 (70201621)
UENO Akifumi  Shizuoka University.Faculty of Engineering, Professor, 工学部, 教授 (30135420)
OKAMOTO Yasuaki  Shimane University, Faculty of Science and Engineering, Professor, 総合理工学部, 教授 (80029553)
NIWA Miki  Tottori University, Faculty of Engineering, Professor, 工学部, 教授 (10023334)
片田 直伸  鳥取大学, 工学部, 講師 (00243379)
薩摩 篤  名古屋大学, 工学部, 講師 (00215758)
瀬川 幸一  上智大学, 理工学部, 教授 (60053675)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥4,600,000 (Direct Cost: ¥4,600,000)
Fiscal Year 1997: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1996: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1995: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsReference Catalyst / Preparation Conditions / Molybdena / Vanadia / Cobalt Oxide / Impact Index / 調製條件 / 触媒調製 / モリブデン-アルミナ / バナジウム-チタニア / コバルト-アルミナ / 標準化 / 酸化モリブテン / 酸化バナジウム / アルミナ / チタニア
Research Abstract

In order to establish the standardization of catalyst preparations by one of the reference catalyst project, we selected three kinds of supported metal oxide catalysts : molybdena-alumina, vanadia-titania and cobalt-alumina, all of which are appreciated to be important as environmental catalysts.
Only catalyst composition was indicated as a common parameter, and project members were expected to prepare catalysts by their own methods and make their characterization from the standpoint of their own interest.
By repeating discussions on the obtained results, we aimed to make clear the key factors on the catalyst preparations and their characterization. The method of impregnation, pH of impregnation solution, suface area of alumina, temperature and atomosphere of drying process, calcination temperature and so on were investigated extensively and intensively, and the effect of these conditions on catalyst performance were compared.
Because this project was based on the cooperative research woks by many independent researchers, there were applied the wide variety of available inspection methods for characterization, including conventional ones to the newest surface science techniques, and the results were fed back to the improvement of catalyst preparations.
Finally, the research were brought to a conclusion by introducing the concept of "impact index", which means a measure for the intensity of preparation conditions onto the catalyst efficiencies.
All the results were published or are now in printing on several international journals as 16 papers.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] Y.Okamoto・et al.: "Preparation of Molybdena-Alumina Catalyst.Part 1.Surface Area of Alumina" Applied Catalysis. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto・et al.: "Preparation of Molybdena-Alumina Catalyst.Part 2.Volume of Impregnation Solution" Applied Catalysis. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto・et al.: "Preparation of Molybdena-Alumina Catalyst.Part 3.Drying Process" Applied Catalysis. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto・et al.: "Preparation of Molybdena-Alumina Catalyst.Part 4.Preparation Parameters and Impact Index." Applied Catalysis. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H., Hamada・et al.: "Effect Co Ion Dispersion on Selective Catalytic Reduction of NO on CoO/Alumina Catalysts" Chemistry Letters. 1997. 887-888 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Satsuma・et al.: "Activity of Surfacc Species of (VO)_2P_2O_7 in the Oxidation of n-Butane." Applied Surface Science. 1997. 496-499 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 1.Surface Area of Alumina." Applied Catalysis. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 2.Volume of Impregnation Solution." Applied Catalysis. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 3.Drying Process." Applied Catalysis. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 4.Preparation Parameters and Impact Index." Applied Catalysis. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Hamada et.al.: "Effect of Co Ion Dispersion on Selective Catalytic Reduction of NO on CoO/Alumina Catalysts." Chemistry Letters. 1997. 887-888 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Satsuma et.al.: "Activity of Surface Species of (VO) _2P_2O_7 in the Oxidation of n-Butane" Applied Surface Science. 1997. 496-499 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 1.Surface Area of Alumina" Applied Catalysis. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 2.Volume of Impregnation Solution" Applied Catalysis. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 3.Drying Process" Applied Catalysis. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Okamoto et.al.: "Preparation of Molybdena-Alumina Catalyst.Part 4.Preparation Parametors and Impact Index" Applied Catalysis. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Hamada et.al.: "Effect of Co Ion Disporsion on Selective Catalytic Reduction of NO on CoO/Alumina Catalysts" Chemistry Letters. 1997. 887-888 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] A.Satouma et.al.: "Activity of Surface Species of (VO)_2P_2O_7 in the Oxidation of n-Butane" Applied Surface Science. 1997. 496-499 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] J.Nakamura et al.: "The Rde of ZnO in Cu/ZnO Methanol Synthesis Catalysts" Catalysis Today. 28. 223-230 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.Nakamura et al.: "A Surface Science Investigation of Methanol Synthesis over A Zn Deprosited Polycuystalline Cusuiface" Journal of Catalysis. 160. 65-75 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Uchijima et al.: "SMSI Effect in Some Reducunable Oxidfe including Nibia" Catalysis Today. 28. 105-117 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kanai et al.: "The Syneigy between Cu and ZnOin Methanol Synthesis Catalysts" Catalysis Letters. 38. 157-163 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.Nakamura et al.: "Model Studies of Methanol Synthesis on Copper Catalysis" Studies in Surface Science and Catalysis. 101. 1389-1399 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Takehira et al.: "Direct Portial Oxidation of Methare into Synthesis Gas ober Rh/YS Z/Ag" Catalysis Today. 29. 397-402 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.Nakamura ら: "Methanal Synthesis over a In-depasited Copper Madel Catabpt" Catalysis Letters. 31. 325-331 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Sato ら: "Partial Oxidation of CH_4 to Synthesis Gas Using a Rh/YSZ/Ag Flectrochemical Membrane Reactar" J. Chem, Soc., Faraday Trans.91. 1655-1661 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Niwa ら: "Structure and Activity of Molybdenam Oxide Mono-atomic dayer Farmed on Tin Oxide" J.Catalyris. 151. 285-291 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Okamoto ら: "Cobalt-Molybdenum Sulfide Catalysts Sapported on Alamina" Ird. Erg. Chem., Research. 34. 3703-3712 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Z,Zhang ら: "Chemical Recycling of Waste Polyptyrene into Styrone over Solid Acids and Bases" Ird. Eng. Chem., Research. 34. 4514-4519 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] D.Ye ら: "Factars Determining the Selective Expasure of (010)Plane of V_2O_5 Catalysts Sitpparted on Various TiO_2" Res, Chem, Intermed.21. 95-114 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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