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Technological applications of photothermal spectroscopy.

Research Project

Project/Area Number 07305037
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業分析化学
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

OGAWA Teiichiro  Grad.School of Engineering Sciences, Kyushu University Professor, 大学院・総合理工学研究科, 教授 (50028156)

Co-Investigator(Kenkyū-buntansha) HATA Tomonobu  Fac.Engineering, Kanazawa Univ.Professor, 工学部, 教授 (50019767)
TOODA Taro  Univ.of Electricity & Communication Professor, 電気通信学部, 教授 (40217576)
TERAMAE Norio  Grad.Sch.Science, Tohoku Univ.Professor, 大学院・理学研究科, 教授 (70114569)
UCHIYAMA Katumi  Fac.Engineering, Tokyo Metropolitan Univ.Ass.Professor, 工学部, 助教授 (40151899)
IMASAKA Totaro  Grad.School.Engineering, Kyushu Univ.Professor, 大学院・工学研究科, 教授 (30127980)
升島 努  広島大学, 医学部, 教授 (10136054)
杉谷 嘉則  神奈川大学, 理学部, 教授 (80015552)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥12,600,000 (Direct Cost: ¥12,600,000)
Fiscal Year 1997: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 1996: ¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 1995: ¥5,200,000 (Direct Cost: ¥5,200,000)
Keywordsphotothermal / heat conversion / optoacoustic / thermal lens / non-radiative processes / laser / surface / high sensitive determination / フォトサーマル現象 / フォトサーマルスペクトル / 熱効果 / 超高速現象 / 信号増幅効果 / 生体情報
Research Abstract

(1) Purpose
In order to improve a highly sensitive and effective analytical technique based on photothermal spectroscopy, a comprehensive investigation on photothermal phenomena should be carried out from the following two points of view.
(1) New possibilities and prospects should be clarified on photothermal spectroscopy.
(2) Basic process in photothermal effects should be investigated to develop new techniques.
(2) Process of investigations
The present project was carried out on five important points of view and on a series of four discussion meetings as described below.
First meetings July 21-22,1995 Tokyo
Second meetings November 23-24,1995 Fukuoka
Third meetings August 20-21,1996 Kyoto
Fourth meetings November 10-11,1997 Tokyo
(3) Results
The results of this project is consisted of individual research efforts and joint discussion.
(1) Basic processes. /// Shape and size effect of small particles (Kitamura, Hokkaido). Detailed analysis of basic process based on new methods (Terashima, Kyoto). Diffusion length with a direct electric field (Toyoda, Elect.& Comm.).
(2) new instrumentation. /// Thermal conductivity in thin films (Hata, Kanazawa). X-ray photothermal spectroscopy using a SOR ring (Masujima, Hiroshima).
(3) Biological applications. /// High sensitive determination on skin (Uchiyama, Tokyo Met.).
(4) Surfacial applications. /// Hydrophobicity on water surface (Ogawa, Kyushu). Liquid-liquid interface (Kawazumi, Kinki). Adsorption isotherm at interfaces (Teramae, Tohoku).
(5) Practical applications. /// Ablation process (Ito, Nagaoka). Frequency dependence of dynamic heat capacity (Kojima, Tsukuba). Slab optical guide (sugitani, Kanagawa). Continuous monitoring of dioxine (Imasaka, Kyushu).

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (67 results)

All Other

All Publications (67 results)

  • [Publications] Takanori Inoue: "Determination of oxacyanine dyes and rhodamine by a SHG technique using a femto-second laser" Analytica Chimica Acta. 330. 117-121 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yao Qun Li: "Laser photoionization for highly sensitive detection of anthracene at the iol-water interface." Analytical Sciences. 12. 691-693 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Joon Myong Song: "Electron attenuation lenght in rhodamine B-arachidic acid LB film by laser two-photon ionization" Langmuir. 12. 6518-6520 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Ito: "Interaction of high power laser pulses on Al measured by photoacoustic methods:Effect of wavelenth" Proceeding of ICALWO'97. (in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] J.Matsumoto: "Enhancement of the molecular ion peak form halogenate benzenes and phenols using fs laser in SSB/MPI." Analytical Chemistry. 69. 4524-4529 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C.H.Lin: "Analysis of photoablation produces resulting foom polymer materials by SSB/MPI/time-of-flight mass." Analytical Chemistry. 68. 1153-1157 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kawazumi: "Monitoring of dissolving processes of amphipathic mole molecules from aqueous surface by laser two-photon ion" Analytical Sciences. 13. 49-52 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Yao: "Micrometer size effects on dye association in single laser-trapped water droplet." Journal Physical Chemistry. 100. 1494-1497 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.B.Kim: "In situ measurements of ion-exchange processes in single polymer particles:Laser trapping." Analytical Chemistry. 68. 409-414 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Nakatani: "Electrochemical studies on mass transfer across a single nitrobenzene microdroplet/water interface." Journal of Physical Chemistry. 100. 6749-6754 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Kojima: "Dependence of quasielastic light scattering intensisity and alpha-relaxation time." Physical Reviews B. 54. 222-226 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Kojima: "Light scattering of supercooled propylene glycol." Journal of Physics on Condensed Matters. 9. 6995-7002 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C.Amano: "Measurement of reflected and scattered light for monitoring fluctuation of structures." Spectroscopy Letters. 28. 417-428 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Radical molecular interactions as observed in time resolved resonance Raman band shape." Journal of Physical Chemistry. 99. 7891-7896 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Refractive index change by photothermal effect with constant density detected as temperature grating." Journal of Chemical Physics. 104. 4988-4998 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Ultrafast rise of translational temperature after photoexcitation to electronic excited state." Journal of Chemical Physics. 105. 6587-6595 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Two methods of two-step excitation thermal grating technique for detection of transient radicals." Journal of Physical Chemistry. 101. 3227-3234 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Okamoto: "Diffusion process of the benzyl radical created by photodissociation probed by the trnansient grating." Joural of Physical Chemistry. 101. 5269-5277 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Ysmaguchi: "Resonant SHG spsectrocopy of rhodamine B adsorbed onto fused silica." Analytical Sciences. 13. 85-88 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Bessho: "Microenvironments of anilino-naphthalenesulfocate at heptane-water interface:Time resolved spectroscopy" Chemical Physics Letters. 264. 381-386 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Toyoda: "Photoacoutic spectra of BaBiPbO3." Material Science and Engineering B. 41. 102-106 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Toyoda: "Photoacoustic spectroscopy of Cu impurities in ceramic ZnS." Hapanese Journal of Applied Physics. 36. 3300-3302 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Hata: "Evaluation of optical absorption coefficients of Si by Photothermal spectroscopy." Japanese Journal of Applied Physics. 34. 2911-2916 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Masujima: "New elemental photoexcitation processes" Spring-8 project. 4. 112-120 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Takanori Inoue, Masao Moriguchi, Teiichiro Ogawa: "Determination of Oxacyanine dyes and rhodamine by a second harmonic generation technique using a femto-second laser." Anal.Chem.Acta.330-1. 117-121 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yao Qun Li, Takanori Inoue, Teiichiro Ogawa: "Laser photoionization for sensitive detection of anthracene at the oil-water interface." Anal.Sci.12-5. 691-693 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Joon Myong Song, Takanori Inoue, Teiichiro Ogawa: "Electron attenuation length in rhodamine-arachidic acid LBfilm by laser photoionization." Langmuir. 12-26. 6518-6520 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Ito, M.Murayama, Y.Fukuzawa and S.Nakamura: "Interaction of high power laser pulses on aluminium measured by photoacoustic methods" Proc.ICALEO'97, LIA. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] J.Matsumoto, C.H.Lin, T.Imasaka: "Enhancement of the Molecular Ion Peak from Halogenated Benzenes & Phenols Using fs Laser Pulses in Conjunction with SS Beam/MPI Mass Spectrometry." Anal.Chem.69-22. 4524-4529 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C.H.Lin, Y.Murata, T.Imasaka: "Analysis of Photoablation Products Resulting from Polymer Materials by Supersonic Beam/MPI/Time-of-Flight Mass Spectrometry." Anal.Chem.68-7. 1153-1157 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kawazumi, T.Kaieda, K.Ohmukai, M.Sato, T.Inoue, T.Ogawa: "Monitoring of dissolving processes of amphipathic molecules from aqueous surface by laser-induced two-photon ionization" Anal.Sci.13-sup. 49 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Yao, Y.Inoue, H.Ikeda, K.Nakatani, H.-B.Kim, and N.Kitamura: "Micrometer Size Effects on Dye Association in Single Laser-Trapped Droplet" J.Phys.Chem.100-5. 1494-1497 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.-B.Kim, M.Hayashi, K.Nakatani, N.Kitamura, Sasaki, Hotta, H.Masuhara: "In Situ Measurements of Ion-Exchange Processes in Single Polymer Particles : Laser Trapping & Confocal Fluorescence Microspectroscopy" Anal.Chem.68-3. 409-414 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Nakatani, M.Wakabayashi, K.Chikama, and N.Kitamura: "Electrochemical Studies on Mass Transfer across a Single-Nitrobenzene-Microdroplet Water Interface" J.Phys.Chem.100-16. 6749-6754 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Kojima, H.Sato and A.Yoshihara: "Light Scattering of Supercooled Propylene Glycol" J.Phys.Conden.Matter. 9. 10079-10085 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Kojima and V.Novikov: "Dependence of Quasielastic Light S cattering Intensity and Relaxation Time" Phys.Rev.B. 54. 222 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C.Amano, 'Y.Sugitani, T.Takei, S.Fujiwara: "Measurement of reflected & scattered light for monitoring fluctuation structures." Spectroscopy Letters. 28. 417-428 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima, H.Hamaguchi: "Radical molecular interactions as observed in time-resolved Raman band shape." J.Phys.Chem.99. 7891-7896 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Refractive index change by photothermal effect with a constant density detected as temperature grating in various fluids." J.Chem.Phys.104. 4988-4998 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Ultrafast rise of translational temperature after photoexcitation to electronic excited state in solution : Transient lens study of Ni2+ aqueous solution" J.Chem.Phys.105. 6587-6595 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Terazima: "Two methods of two-step excitation thermal grating technique for detection radicals" J.Phys.Chem.A.101. 3227-3234 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Okamoto, N.Hirota, M.Terazima: "Diffusion process of the benzyl radical created by photodissociation probed by the transient grating method." J.Phys.Chem.A.101. 5269-5277 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Yamaguchi, T.Uchida, N.Teramae and H.Kaneta: "Resonant Second Harmonic Spectroscopy of Rhodamine Adsorbed onto Silica" Anal.Sci.13. 85-88 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Bessho, T.Uchida, A.Yamauchi, T.Shioya and N.Teramae: "Microenvironments of 8-Anilino-1-Naphthalenesulfonate at the Heptane-Water Interface : Time-Resolved Total Internal Refrection Fluorescence." Chem.Phys.Lett.264. 381-386 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Toyoda and I.Shiozaki: "Photoacoustic Spectra of BaBil-xPbO3 (x=0.0,0.65, and 1.0)" Matter.Sci.Eng.B.41. 102-106 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Toyoda and K.Shinoyama: "Photoacoustic Spectroscopy of Cu impurities in Ceramic ZnS." Jpn.J.Appl.Phys.36. 3300-3302 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Hata, H.Konishi, D.Iwai, K.Sasaki: "Evaluation of optical absorption coefficients of Si by photothermal spectroscopy using transparent pyroelectric transducer." Jpn.J.Appl.Phys.34. 2911-2916 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Masujima: "New Elemental Photoexcitation Processes." Spring-8 Project. 4. 112 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yao Qun Li,T.Ogawa: "Laser photoionization for highly sensitive detection of anthracene at oil-water interface." Analytical Sciences. 12.5. 691-693 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] J.Matumoto: "Enhancement of the molecular ion peak from halogenated benzenes using fs laser pulses with SS MPI spectrometry." Analytical Chemistry. 68.7. 1153-1157 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kawazumi,T.Kaieda T.Inoue,T.ogawa: "Monitoring of dissolving processes of amphipathic molecules from aqueous surface by photoionization." Analytical Sciences. 13-sup. 49-52 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Kojima,H.Sato,A.Yoshihara: "Light scattering of supercolled propylene glycol." Journal of Physics of Condensed Matter. 9.11. 10079-10085 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Terajima: "Two methods of two-step excitation thermal grating technique for detection of radicals." Journal of Physical Chemsitry A. 101-5. 3227-3234 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Bessho,T.Shioya,N.Teramae: "Microenvironments of 8-anilino-naphthalenesulfonate at heptane-water interface:time-resolved fluorescence." Chemical Physcics Letters. 264.2. 381-386 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Inoue,M.Moriguchi,T.Ogawa: "Determination of oxacyanine dyes and rhodamine by a second harmonic generation technique using a femto-second laser" Analytica Chimica Acta. 330,1. 117-121 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.M.Song,T.Inoue,T.Ogawa: "Electron attenuation length in rhodamine B-arachidic acid LB film by laser two-photon ionization" Langmuir. 12,26. 6518-6520 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] C.H.Lin,Y.Muuata,T.Imasaka: "Analysis of photoablation products resulting from polymer materials by supersonic/MPI/TFM spectroscopy" Analytical Chemistry. 68,7. 1153-1157 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Toyoda,K.Kato: "Photoacoustic spectra of CdInGaS4 with a DC electric field" Japanese Journal of Applied Physics. 35,. 2912-2915 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Shioya,S.Tsukahara,N.Teramae: "Complexation kinetics of 5-octyloxmethy-8-quinolinol with Ni(II)at the heptane water interface." Chemistry Letters. ,3. 469-470 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Bessyo,T.Uchida,T.Shioya,N.Teramae: "Microenvironments of 8-anilino-1-naphthalenesulfonate at the heptane-water interface:time resolved total internal reflection." Chmical Physics Letters. 264,2. 381-386 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Kawazumi, J. M. Song, T. Inoue, T. Ogawa.: "Laser fluorometry using a visible semiconductor laser and avalanche photodiode for capillary electrophoresis." Analytical Sciences. 11. 587-590 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Inoue, M. Moriguchi, T. Ogawa.: "Highly sensitive determination of dye molecules on a surface by the second harmonic generation technique." Analytical Sciences. 11. 671-672 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Furuya, A. Matsuo, M. Tokeshi, T. Ogawa.: "Rovibrational distributions of CH(B) produced in e-C2H2 collisions." Journal of Physical Chemistry. 99. 13772-13777 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Ogawa, S. Sumi, T. Inoue.: "Highly sensitive detection of pyrene in a flow jet by the surface laser twe-photon ionization." Instrumentation Science and Technology. 23. 311-315 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Imasaka, Y. Kawabata, T. Kaneta.: "Optical chromatography" Analytical Chemistry. 67. 1763-1765 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Ozawa, T. Masujima: "Real-time analysis of exocytosis and PKC-translocation in RBL-2H3 cells visualized by video-enhanced microscopy." Neurochemical Research. 20. 323-323 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Ogawa: "Trace determination of molecules by laser two-photon ionization in “Handbook of Advanced Material Testing"" Marcel Dekker Publisher Co., 27-40 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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