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Electron-transfer Control on Molecular-Functional Conductor Surfaces and Its Application

Research Project

Project/Area Number 07305038
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業物理化学
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

OYAMA Noboru  Tokyo University of Agriculture & Technology, Faculty of Technology, Professor, 工学部, 教授 (40134845)

Co-Investigator(Kenkyū-buntansha) YAMAZOE Noboru  Kyushu University, Graduate School of Engineering Sciences, Professor, 大学院総合理工学研究科, 教授 (40037817)
FUJISHIMA Akira  University of Tokyo, Faculty of Engineering, Professor, 大学院工学系研究科, 教授 (30078307)
TANIGUCHI Isao  Kumamoto University, Faculty of Engineering, Professor, 工学部, 教授 (90112391)
UOSAKI Kohei  Hokkaido University, Guraduate School of Science, Professor, 大学院理学研究科, 教授 (20133697)
AIZAWA Masuo  Tokyo Institute of Technology, Faculty of Bioscience and Biotechnology, Professo, 生命理工学部, 教授 (00016742)
大坂 武男  東京工業大学, 大学院・総合理工学研究科, 助教授 (80152099)
末永 智一  東北大学, 工学部, 助教授 (70173797)
米山 宏  大阪大学, 工学部, 教授 (80029082)
藤平 正道  東京工業大学, 生命理工学部, 教授 (40013536)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥12,400,000 (Direct Cost: ¥12,400,000)
Fiscal Year 1997: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1996: ¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 1995: ¥5,300,000 (Direct Cost: ¥5,300,000)
KeywordsMolecular Function / Conductor Surface / Electron-transfer Control / Electrode Reaction / Surface Evaluation Method / Electroactive / Electrochemical Sensor / Battery Material / 電子移動反応 / 界面修飾 / 触媒作用 / センシング / マイクロ電極 / エネルギー変換 / 電気化学 / 修飾電極 / 電子移動
Research Abstract

This research project has focused on electrodes functionalized with ad-atoms and electroactive molecules, such as transition metals, redox polymers, conducting films LB films, self-assembled films, etc. Emphasis was placed on those topics dealing with the creation of new electrode surface, the synthesis of new electroactive materials and novel characterization methods associated with chemically modified electrode surfaces and the analysis and contro of electron transfer and mass transport processes within the films. The project demonstrated the performance results of these new materials and electrode surfaces in batteries, sensors, and other, electronic devices.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] Tetsu Tatsuma: "Electrochemical Polymerization and Depolymerization of 2,5-Dimercapto-1,3,4-thiadiazole.QCM and Spectroscopic Analysis" Journal of Physical Chemistry B. 101. 7556-7562 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Eiry Kobatake: "A Fluoroimmunoassaay Based on Immunoliposomes Containing Genetically Enginnered Lipid-Tagged Antibody" Analytical Chemistry. 69. 1295-1298 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kohei Uosaki: "Electrochemical Epitaxial Growth of a Pt(111)Phase on an Au(111)Electrode" Journal of Physical Chemistry B. 101. 7566-7572 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Isao Taniguchi: "Electrochemical Study of Biological Functions of Particular Evolutionary Conserved Amino Acid Residues Using Mutated Molecules of Maize Ferredoxin" Chemistry Letters. 1997. 929-930 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tadashi Enomoto: "Electrostatically induced Isomerization of Azobenzene Derivatives in Langmuir-Blodgett Films" Journal of Physical Chemistry B. 101. 7422-7427 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Geyu Lu: "High-Temperature for NO and NO_2 Based on Stabilized Zirconia and Spinel-Type Oxide Electrodes" Journal of Material Chemistry. 7. 1445-1449 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tetsu Tatsuma: ""Electrochemical Polymerization and Depolymerization of 2,5-Dimercapto-1,3,4-thiadiazole.QCM and Spectroscopic Analysis"" J.Phys.Chem.B. 101. 7556-7562 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Eiry Kobatake: ""A Fluoroimmunoassaay Based on Immunoliposomes Containing Genetically Enginnered Lipid-Tagged Antibody"" Anal.Chem.69. 1295-1298 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kohei Uosaki: ""Electrochemical Epitaxial Growth of a Pt(111)Phase on an Au(111)Electrode"" J.Phys.Chem.B. 101. 7566-7572 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Isao Taniguchi: ""Electrochemical Study of Biological Functions of Particular Evolutionaly Conserved Amino Acid Residues Using Mutated Molecules of Maize Ferredoxin"" Cem.Lett.1997. 929-930 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tadashi Enomoto: ""Electrostatically induced Isomerization of Azobenzene Derivatives in Langmuir-Blodgett Films"" J.Phys.Chem.B. 101. 7422-7427 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Geyu Lu: ""High-Temperature Sensors for NO and NO_2 Based on Stabilized Zirconia and Spinel-Type Oxide Electrodes"" J.Mater.Chem.7. 1445-1449 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tetsu Tatsuma: "Electrochemical Polymerization and Depolymerization of 2,5-Dimercapto-1,3,4-thiadiazole.QCM and Spectroscopic Analysis" Journal of Physical Chemistry B. 101. 7556-7562 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Eiry Kobatake: "A Fluoroimmunoassaay Based on Immunoliposomes Containing Genetically Enginnered Lipid-Tagged Antibody" Analytical Chemistry. 69. 1295-1298 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kohei Uosaki: "Electrochemical Epitaxial Growth of a Pt (111) Phase on an Au (111) Electrode" Journal of Physical Chemistry B. 101. 7566-7572 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Isao Taniguchi: "Electrochemical Study of Biological Functions of Particular Evolutionary Conserved Amino Acid Residues Using Mutated Molecules of Maize Ferredoxin" Chemistry Letters. 1997. 929-930 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Tadashi Enomoto: "Electrostatically induced Isomerization of Azobenzene Derivatives in Langmuir-Blodgett Films" Journal of Physical Chemistry B. 101. 7422-7427 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Geyu Lu: "High-Temperature Sensors for NO and NO_2 Based on Stabilized Zirconia and Spinel-Type Oxide Electrodes" Journal of Material Chemistry. 7. 1445-1449 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 藤嶋昭: "Molecular-Level Design of a Photoinduced Magnetic Spin Coupling System : Nickel Nitroprusside" The Jounal of Physical Chemistry. 47. 18289-18291 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 末永智一: "Detection of Microspotted Carcinoembryonic Antigen on a Glass Substrate by Scanning Electrochemical Microscopy" Analytical Chemistry. 7. 1276-1278 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 大坂武男: "Water-Induced Disproportionation of Superoxide Ion in Aprotic Solvents" The Jounal of Physical Chemistry. 51. 20134-20137 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 大澤雅俊: "In Situ Real-Time Surface-Enhanced Infraed Study of Electrochemical Reactions" Applied Spectroscopy. 51・4(印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 魚崎浩平: "Electrochemical in situ FT-IRRAS studies of a self-assembled monolayer of 2-(11-mercaptoundecyl) hydroquinone" J.Chem.Soc.,Faraday Trans. 92・20. 3813-3821 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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