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THE STUDY FOR THE MECHANISM OF ABNOMAL PHYSICAL PROPERTIES IN 4f-AND 3d-CHALCOGENIDES AND PNICTIDES

Research Project

Project/Area Number 07404016
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

SUZUKI Takashi  GRADUETE SCHOOL OF SCIENCE.TOHOKU UNIVERSITY.DEPARTMENT OF PHYSICS,PROFESSOR, 理学研究科, 教授 (30004344)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Hisao  GRADUETE SCHOOL OF SCIENCE.TOHOKU UNIVERSITY.DEPARTMENT OF PHYSICS : RESEARCH AS, 大学院・理学研究科, 助手 (40250675)
TAKAGI Shigeru  GRADUETE SCHOOL OF SCIENCE.TOHOKU UNIVERSITY.DEPARTMENT OF PHYSICS : ASSOCIATED, 大学院・理学研究科, 助教授 (20154750)
KASAYA Mituo  GRADUETE SCHOOL OF SCIENCE.TOHOKU UNIVERSITY.DEPARTMENT OF PHYSICS : PROFESSOR, 大学院・理学研究科, 教授 (20004351)
KAMIMURA Takashi  GRADUETE SCHOOL OF SCIENCE.TOHOKU UNIVERSITY.DEPARTMENT OF PHYSICS : PROFESSOR, 大学院・理学研究科, 教授 (30005813)
佐藤 正樹  東北大学, 大学院・理学研究科, 助教授 (50162475)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥39,000,000 (Direct Cost: ¥39,000,000)
Fiscal Year 1997: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1996: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1995: ¥32,100,000 (Direct Cost: ¥32,100,000)
Keywords4F ELECTRON SYSTEM / 3d ELECTRON SYSTEMS / CHALCOGENIDES / PNICTIDES / ABNORMAL MAGNETISM / LOW CARRIER SYSTEMS / METAL-INSULATOR TRANSITION / de Haas Alphen effect / 超高温結晶作製 / 希上類 / 3d金属 / 少数キャリヤ- / f電子 / d電子 / CeP / TmTe / 局在 / 非局在 / Lal-xCexP / DySb / 電気的四重極秩序 / 構造相転移 / 弾性定数
Research Abstract

The most important work in this project was to construct the furnace which can produced high quality single crystals of the chalcogenides and pnictides in f-and d- electron systems. The key points to successfully complete this furnace were how to attain ultra high temperature up to 3000C in stable because of the ultra high melting point of those chalcogenides and pnictides. The difficulty come from the strong increasing radiation loss at such a high temperature. There were not suitable radiation shield materials. After many efforts we could overcome this difficulty by finding the excellent radiation shield of p-BN cylinder coated inside wall with tungsten thin flint The input HF power can easily come to the crucible hung inside cylinder but radiation can not escape through this thin film due to skin depth. Then we have gotten the 3000C in stable for many days contineously.
After successful construction this furnace, we could several high quality single crystals and investigate the many physical properties and made many new discovering.
First of all, We have succeeded to grow high quality single crystal CeP and found most complicated magnetic phase diagrams so far. Neutron diffraction experiment reveals these magnetic structures to be stripe of the double layer with ferromagnmetically alline large magnetic moment and integer layers (this integer are changed to low number successively by applied magnetic fields or pressure bellow 11) with antiferromagnetically allin smaller magnetic moments. De Hass van Alphen effects reveal the electronic structure. NMR and ESR measurement also show micro-mechanism of complicated exchenge interaction.
We also found the electric quadrupole order in TmTe with octapole interaction. During insulator-metal transition in TmTe, strong ferromagnetism appeared and extremely abnormal transport properties are seen.
Other many prominent results are described in the report of this project including 140 publisheed

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] T.Matsumura: "Quadrupolar ordering in TmTe" Physica B. 223 & 224. 385-388 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kumigashira: "High resolution angle-resolved photoelectron spectroscopy of CeBi" Phys.Rev.B. 54. 9341-9345 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Terashima: "Fermi surface and magnetic phases of the low-carrier-density strongly correlated electron system CeP" Phys.Rev.B. 55. 4197-4205 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Kohgi: "One dimensional antiferromagnetic coupling in the low carrier heavy electron system" Phys.Rev.B. 56. R11388-R11391 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Kubota: "Impact of La substitution on the magnetic structure of a low-carrier-density Kondo system: Ce0.9La0.1P" Phys.Rev B. 58. Rapid Comm.1-4 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kumigashira: "High-resolution angle-resolved photoemission study of LaSb" Phys.Rev.B. 58. 7675-7680 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Matsumura, S.Nakamura, T.Goto, H.Shida, T.Suzuki: "Quadrupolar ordering in TmTe" Physica B. 223 & 224. 385-388 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kumigashira, S.-H.Yang, T.Yokoya, A.Chainani, T.Takahasshi, A.Uesawa and T.Suzuki: "High resolution angle-resolved photoelectron spectroscopy of CeBi" Phys.Rev.B. 54. 9341-9345 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Terashima, S.Uji, H.Aoki, W.Joss, Y.Haga, A.Uesawa and T.Suzuki: "Fermi surface and magnetic phases of the low-carrier-density strongly correlated electron system CeP" Phys.Rev.B. 55. 4197-4205 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Kohgi, K.Iwasa, J.-Mignot, A.Ochiai, T.Suzuki: "One dimensional antiferromagnetic coupling in the low carrier heavy electron system" Phys.Rev.B. 56. R11388-R11391 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Kubota, Y.Oohara, and H.Yoshizawa, N.Mori, H.Takahashi, A.Uesawa and T.Suzuki: "Impact of La substitution on the magnetic structure of a low-carrier -density Kondo system : Ce0.9La0.1P" Phys.Rev.B Rapid Comm.58. 1-4 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kumigashira, Hyeong-Do Kim, T.Ito, A.Ashihara, T.Takahashi, T.Suzuki, M.Nishihara, and O.Sakai: "High-resolution angle-resolved photomission study of LaSb" Phys.Rev.B. 58. 7675-7680 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Mori: "Anormalous Tiansport Properties of Yb_4As_3 umder High Pressure" Physica B. 200-232. 630-634 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Naka: "Prewure-Induced Magnetic Tramsition in CeP" Physica B. 239. 245-251 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Matsunura: "Pressure Induced Semiconduc tine to metal Transition in Tuite" Phys.Rev.Letters. 78. 1138-1141 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Takeshita: "Highly Anisotropic Pressure Dependence of the Fermi Ainface of CeSb" Phys.Rov.detters. 78. 1945-1951 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Terashima: "Fermi surface and Magnetic Phsse transition of CeP" Phys.Rev.B. 55. 4197-4205 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] D.X.Lee: "Spin Glass behavior in mechanically Milled Crystalline GdN" Phys.Rev.B. 55. 6467-6472 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Matsumura: "Pressure induced Semiconductor to metal Transition TmTe" Phys.Rev.Lett.78. 1138-1141 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.Tang: "The Valence State of TmTe at High Pressure" Solid State Communication. 100. 571-574

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Kimura: "Optical Study on Heavy Fermion and Mixed Valence in Yb_4As_3" J.Phys.Soc.Japan.65. 3591-3598 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Kohgi: "Magnetic Phase diagram of CeP" J.Phys.Soc.Japan.65. 99-104 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Kobayashi: "The anomaly in the Knight shift of ^<31>P-NMR in CexLa_1-_xP" J.Phys.Soc.Jpn.65. 3343-3350 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] R.Settai: "De Haas-van Alpheir effect of CeSb" Physica B. 216. 310-312 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Suzuki,and M.Ikezawa: "Magnetic Polaron of Gd2S3 Studied by Infrared spectroscopy under Magnetic Field" J.Phys.Soc.Jpn.64. 200-209 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Haga and T.Suzuki: "Pressure effects on Crystal Electric Field Excitations in Ultra Low Carrier Kondo lattice System Cep and CeAs" J.Phys.Soc.Jpn.64. 617-630 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] A.Omino and T.Suzuki: "Evidence of Formation of Magnetic Polaron states in Semimetallic Gd-Monopnictides" Solid State Comm. 93. 319-322 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Haga and T.Suzuki: "Pressure Effects on Transport Properties of Yb4As3" J.Phys.Soc.Jpn. 64. 533-539 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Suzukii and M.Date: "High-Field Magnetic Phase Transition in CeP" J.Phys.Soc.Jpn. 64. 572-580 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] A.Ochiai and T.Suzuki: "Photoemission,x-ray absorption,and inverse photoemission studies of valence-fluctuating Sm3Se4" Phya.Rev.B.51. 2061-2067 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2020-05-15  

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