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Solid Hydrogen under Ultra High Pressure

Research Project

Project/Area Number 07404018
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionOsaka University

Principal Investigator

AMAYA Kiichi  Dep. Mat. Phys, Fac. Eng. Sci., Osaka University, Prof., 大学院・基礎工学研究科, 教授 (80029503)

Co-Investigator(Kenkyū-buntansha) MIYAGI Hiroshi  Dep. Mat. Phys, Fac. Eng. Sci., Osaka University, Ass. Prof., 大学院・基礎工学研究科, 助教授 (10029473)
ISHIZUKA Mamoru  Res. Cent. Mat. Sci. Ext. Cond., Osaka University, Res. Ass., 極限科学研究センター, 助手 (30184542)
KOBAYASHI Tatsuo  Res. Cent. Mat. Sci. Ext. Cond., Osaka University, Ass. Prof., 極限科学研究センター, 助教授 (80205468)
ENDO Shoichi  Res. Cent. Mat. Sci. Ext. Cond., Osaka University, Prof., 極限科学研究センター, 教授 (10001843)
Project Period (FY) 1995 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥29,600,000 (Direct Cost: ¥29,600,000)
Fiscal Year 1998: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1997: ¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 1996: ¥8,200,000 (Direct Cost: ¥8,200,000)
Fiscal Year 1995: ¥14,100,000 (Direct Cost: ¥14,100,000)
KeywordsUltra High Pressure / Solid Hydrogen / Metallization / Electrical Resistance
Research Abstract

Solid hydrogen is electrically insulator at low pressure but it is expected to show conductivity under pressure at Mbar region. Our purpose is to detect, the metallization not, by indirect optical measurement, but by more direct, electrical resistance measurement. First of all, we tried to produce ultra-high pressure and to develop the techniques of electrical and magnetic measurement under the produced pressure. In fact, we developed DAC (diamond anvil cell) specially designed for ultra-high pressure and succeeded to make fine electrodes with 5 μm width on the pressure surface of 30 μm diameter and so, we are ready for electrical resistance measurement of solid hydrogen with volume of 〜 10ィイD1-8ィエD1cc. High pressure of 2.25 Mbar was also successfully produced and that the resistance measurement was performed there. This is now the best, record for high pressure experiment. Secondly, on the technical basis established above, we have succeeded in the study of search for metallization an … More d superconductivity under pressure, starting from alkaline earth metal Ca, Vib group of elements such as sulfur (S) and oxygen. Further, we observed, for the first time, the pressure induced superconductivity of ionic crystal CsI and simple organic crystal of CィイD26ィエD2IィイD24ィエD2OィイD22ィエD2. During the experimental process stated above, however, the expected metallization pressure value has changed from previous 1.5 Mbar to 2.5 Mbar. Now, it is reported that, the solid hydrogen is still transparent even under 3.4 Mbar and remains as insulator electrically. Our theoretical group (Miyagi et al.) also estimates that, molecular dissociation of solid hydrogen takes place at pressures at around 4 Mbar where hydrogen is metallic. So, we have to change our experimental program and to produce higher pressure. But, at present, we expect we can reach metallic hydrogen at, pressures between 2 Mbar and 3 Mbar and at temperature of 1000 ℃ 〜 1500 ℃. Now, we started confinement and pressurization of hydrogen. Present results show the difficulty of stable confinement, because of the diffusion into the surrounding metal. There are several difficulties against the metallization of solid hydrogen but still the new experimental techniques are developed and our reports give belief on the successful finding of metallic hydrogen in near future. Less

Report

(5 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (62 results)

All Other

All Publications (62 results)

  • [Publications] S.Okada et al.,: "Superconductivity of Calcium under High Pressures"J.Phys.Soc.Jpn. 64. 1924-1926 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Takeshita et al.: "Pressure-Induced Superconductivity of SnI_4"J.Phys.Soc.Jpn. 65. 3400-3401 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Shimizu et al.: "Electrical Resistance Measurements of Oxygen under High Pressure"J.Phys.Soc.Jpn. 65. 1527-1528 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Yokota et al.: "Pressure-Induced Supereconductivity of Iodanil"Czechoslovak J.of Phys. 46. S2-817-818 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Okada et al.: "Observation of Superconductivity of Calcium under High Pressure"Czechoslovak J.of Phys. 46. S2-869-870 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Kometani et al.: "Pressure Induced Superconductivity of Sulfur"J.Phys.Soc.Jpn. 66. 2564-2565 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Amaya et al.: "Pressure Induced Superconductivity in Some Simple Systems"Rev.High Pressure Sci.& Technol.. 7. 688-693 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.I.Eremets et al.: "Nanosecond Pulse Laser Heating of Graphite in DAC"Rev.High Pressure Sci.& Technol.. 7. 1013-1015 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.I.Eremets et al.: "High Pressure Methods at Low Temperatures and High Magnetic Field"Rev.High Pressure Sci.& Technol.. 7. 469-474 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Takeshita et al.: "Pressure Induced Superconductivity of SnI_4"Rev.High Pressure Sci.& Technol.. 7. 595-567 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Shimizu et al.: "Oxygen under High Pressure-Temperature Dependence of Electrical Resistance"Rev.High Pressure Sci.& Technol.. 7. 784-786 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.C.Kobayashi et al.: "Enhancement of superconducting transition temprature in CeCu_2Ge_2 under high pressures"J.Phys.Soc.Jpn.. 67. 996-999 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.C.Kobayashi et al.: "Magnetic-to-nonmagnetic transition in the ferromagnetic heavy-fermion compound CeRu_2Ge_2 at high pressures"Phys.Rev.. B57. 5025-5028 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Shimizu et al.: "Superconductivity in Oxygen"Nature. 393. 767-769 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.I.Eremts et al.: "Metallic CsI at Pressures of up to 220GPa"Science. 281. 1333 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Amaya et al.: "Observation of pressure-induced superconductivity in the megabar region"J.Phys.Condens.Matter. 10. 11179-11190 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 天谷喜一他: "極低温・超高圧下の物性実験"圧力技術. 36. 4 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 天谷喜一他: "超高圧下固体酸素の金属化と超伝導"FSST NEWS. 70. 1 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 天谷喜一他: "酸素も超伝導となる"パリティ. 14. 18 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 天谷喜一: "超高圧と酸素の超伝導現象"高圧ガス. 36. 42 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 天谷喜一他: "圧力誘起超伝導"日本物理学会誌. (投稿中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S. Okada, K. Shimizu, T. C. Kobayashi, K. Amaya and S. Endo: "Superconductivity of Calcium under High Pressures"J. Phys. Soc. Jpn.. 65,7. 1924-1926 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N. Takeshita, S. Kometani, K. Shimizu, K. Amaya, N. Hamaya and S. Endo: "Pressure-Induced Superconductivity of SnIィイD24ィエD2"J. Phys. Soc. Jpn.. 65,10. 3400-3401 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Shimizu, K. Suhara, K. Amaya and S. Endo: "Electrical Resistance Measurements of Oxygen under high Pressure"J. Phys. Soc. Jpn.. 65,6. 1527-1528 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T. Yokota, N. Takeshita K. Shimizu, K. Amaya, A. Onodera, I. Shirotani and S. Endo: "Pressure-Induced Superconductivity of Iodanil"Czechoslovak J. of Phys.. 46 Suppl (LT-21, Prague, 1996). S2-817-818 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S. Okada, K. Shimizu, T. C. Kobayashi, K. Amaya and S. Endo: "Observation of Superconductivity of Calcium under High Pressure"Czechoslovak J. of Phys.. 46 Suppl (LT-21, Prague, 1996). S2-869-870 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S. Kometani, K. Shiinizu, M. I. Eremets, M. Kobayashi and K. Amaya: "Pressure Induced Superconductivity of Sulfur"J. Phys. Soc. Jpn.. 66. 2564-2565 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Amaya, K. Shimizu, N. Tpakeshita, S. Kometani, M. I. Eremets, A. Onodera, T. C. Kobayashi, T. Mizutani, M. Ishizuka, S. Endo, M. Takai, N. Hamaya and I. Shirotani: "Pressure Induced Superconductivity in Some Simple Systems"Rev. High Pressure Sci. & Technol.. 7. 688-693 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. I. Eremets, K. Amaya, M. Kobayashi, K. Shimizu, S. Shimomura, O. Stephan, V. Blank and S. Endo: "Nanosecond Pulse Laser Heating of Graphite in DAC"Rev. High Pressure Sci. & Technol.. 7. 1013-1015 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. I. Eremets, K. Amaya, K. Shimizu and T. C. Kobayashi: "High Pressure Methods at LOW Temperatures and High Magnetic Field"Rev. High Pressure Sci. & Technol.. 7. 469-474 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N. Takeshita S. Kometani, M. I. Eremets, K. Shimizu, K. Amaya and N. Hamaya: "Pressure Induced Superconductivity of SnIィイD24ィエD2"Rev. High Pressure Sci. & Technol.. 7. 595-597 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Shimizu, M. I. Eremets, K. Suhara and K. Amaya: "Oxygen under High Pressure-Temperature Dependence of Electrical Resistance"Rev. High Pressure Sci. & Technol.. 7. 784-786 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T. C. Kobayashi, T. Miyazu, N. Takeshita, K. Shimizu, K. Amaya, Y. Kitaoka and Y. Onuki: "Enhancement of superconducting transition temperature in CeCuィイD22ィエD2GeィイD22ィエD2 under high pressures"J. Phys. Soc. Jpn.. 67. 996-999 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T. C. Kobayashi, T. Miyazu, K. Shimizu, K. Amaya, Y. Kitaoka, Y. Onuki, M. Shirase and T. Takabatake: "Magnetic-to-nonmagnetic transition in the ferromagnetic heavy-fermion compound CeRuィイD22ィエD2GeィイD22 ィエD2at high pressures"Phys. Rev.. B57. 5025-5028 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Shimizu, K. Suhara, M. I. Eremets and K. Amaya: "Superconductivity in Oxygen"Nature. 393. 767-769 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. I. Eremets, K. Shimizu, C. Kobayashi and K. Amaya: "Metallic CsI at Pressures of up to 220 Gpa"Science. 281. 1333 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Amaya, K. Shimizu, M. I. Eremets, T. C. Kobayashi and S. Endo: "Observation of pressure-induced superconductivity in the megabar region"J. Phys. Condens. Matter. 10. 11179-11190 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kiichi Amaya, Katsuya Shimizu, Akira Kawai: "Material Research at Very Low and Ultra High Pressure"Journal of High Pressure Institute of Japan. 36. 11 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kiichi Amaya, Katsuya Shimizu: "Metallization and Superconductivity under Ultra-high Pressure"FSST NEWS. No.70. 1 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kiichi Amaya, Katsuya Shimizu: "Superconductivity in Oxygen"Parity. Vol.14 No.05. 18 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kiichi Ainaya: "Ultra-high Pressure and Superconductivity in Oxygen"Journal of High Pressure Gas Safety Institute of Japan. Vol.36 No.7. 42 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kiichi Amaya, Katsuya Shimizu, Naoshi Suzuki: "Pressure-induced Superconductivity"Journal of Physical Society of Japan. (to be published).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.I.Erements et al.: "Nanosecond Pulse Laser Heating of Graphite in DAC" Rev.High Pressure Sci.& Technol.7. 1013-1015 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Amaya et al.: "Pressure Induced Superconductivity in Some Simple Systems" Rev.High Pressure Sci.& Technol.7. 688-693 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Takeshita et al.: "Pressure Induced Superconductivity of SnI_4" Rev.High Pressure Sci.& Technol.7. 595-597 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Shimizu et al.: "Superconductivity in Oxygen" Nature. 393. 767-769 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.I.Eremets: "Metallic CsI at Pressures of up to 220GPa" Science. 281. 1333-1335 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Shimizu et al.: "Oxygen under High Pressure-Temperature Dependence of Electrical Resistance" Rev.High Pressure Sci. & Technol.7. 784-786 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kometani et al.: "Pressure induced superconductioity of Sulfeer" J.Phys.Soc.Jpn.66(to be published). 2564-2565 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Amaya et al.: "Pressure induced superconductioity in Some Sinple Systems" Proc.AIRAPT & HPCJ-38. (to be published). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.I.Eremets et al.: "Nano second pulse laser heating of Graphite in DAC" Proc.AIRAPT & HPCJ-38. (to be published). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.I.Eremets et al.: "High Rressure Methods at Low Temperature and High Magnetic Feld" Proc.AIRAPT & HPCJ-38. (to be published). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Takeshita et al.: "Presure induced Superconductioity of SnI_4" Proc.AIRAPT & HPCJ-38. (to be published). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Suhara et al.: "Oxygen under high Pressure" Proc.AIRAPT & HPCJ-38. (to be published). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Okada et al.: "Superconductivity of Calcium under High Pressures" J.Phys.Soc.Jpn.65. 1924-1926 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N.Takeshita et al.: "Pnessure Induced Superconductioity of SnI_4" J.Phys.Soc.Jpn.65. 3400-3401 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Shimizu et al.: "Electrical Resistance Measurement of Oxygen Under High Pressure" J.Phys.Soc.Jpn.65. 1527-1528 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Okada et al: "Observation of Superconductivity of Calcium under High Pressure" Pnoc.25^<th> Int′l Conf.Low Temp Phys.(1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Yokota,et al.,: "Pnessure Induced Superconductivity of Iodanil" Pnoc.25^<th> Int′l Conf.Low Temp Phys.(1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ishizuka et.al.: "Pressure Induced Ferromagnetism in EuTe" J.Magn.Magn.Meter.(submitted). (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Shimizu et al.: "Electrical Resistance Measurements of Solid Bromine at High Pressures" Proc. of Int´l Conf. High Pressure Science(Warsaw). (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Ishizuka et.al.: "A Change of Magnetison in the Two-Dimensional Heisenberg Ferromagnet K_2CuF_4 Observed at High Pressures" J. Phys. Soc. Jpn. (submitted). (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2020-05-15  

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