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Electronic Properties of Carbon- and Nitrogen-Sustituted Nanotubes

Research Project

Project/Area Number 07405039
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業物理化学
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

YAMABE Tokio  Kyoto Univ.Mol.Eng.Professor, 工学研究科, 教授 (80025965)

Co-Investigator(Kenkyū-buntansha) YOSHIZAWA Kazunari  Kyoto Univ.Mol.Eng.Assoc.Prof., 工学研究科, 助教授 (30273486)
MISAKI Yohji  Kyoto Univ.Mol.Eng.Assoc.Professor, 工学研究科, 助教授 (90202340)
TANAKA Kazuyosi  Kyoto Univ.Mol.Eng.Professor, 工学研究科, 教授 (90155119)
御崎 洋二  京都大学, 工学研究科, 助手 (40135463)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥34,600,000 (Direct Cost: ¥34,600,000)
Fiscal Year 1997: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1996: ¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 1995: ¥27,400,000 (Direct Cost: ¥27,400,000)
KeywordsNanoelectronics / Carbon nanotubes / Molecular solenoid / Peierls transition / Superconductive transition / Electron spin resonance
Research Abstract

In this study, we have carried out characteristics of carbon- and nitrogen-substituted nanotubes. Results of this study (19995-1997) are described below.
(1)Although carbon nanotubes and polyacenes are theoretically expected to exhibit metallic properties, there is always a possibility of metal-insulator transition widely observed in one-dimensional systems. Thus, we predicted the electronic properties of carbon nanotubes and polyphenanthrenes. As a result we showed that there is a close correlation between the crystal orbitals near the Fermi level and the metallic properties.
(2)We purified using a heat-treatment method carbon nanotubes, and conducted electron spin resonance and SQUID measurements. Carbon nanotubes are shown to exhibit metallic properties just like graphite from these measurements.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] K.Tanaka et al.: "Bond Alternation in Carbon Nanotubes Including Sigma-Electrons" Int.J.Quantum Chem.63. 637-644 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Ago et al.: "Theoretical Study of Lithium-Doped Amorphous Carbon Materials" Bull.Chem.Soc.Jpn.70. 1717-1726 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshizawa et al.: "Bandgap Oscillation in polyphenanthrenes" J.Phys.Chem.B. 102. 498-506 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Tasaki et al.: "Optical Properties of Carbon Nanotubes" Phy.Rev.B. (in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshizawa et al.: "Vibronic Coupling and Jahn-Teller Effect in Negatively-Charged Benzene and [18] Annulene" J.Chem.Phys.(in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tanaka et al.: "Bond Alternation in Carbon Nanotubes Including Sigma-Electrons" Int.J.Quantum Chem.63. 637-644 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Ago et al.: "Theoretical Study of Lithium-Doped Amorphous Carbon Materials" Bull.Chem.Soc.Jpn.70. 1717-1726 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshizawa et al.: "Bandgap Oscillation in Polyphenanthrenes" J.Phys.Chem.B102. 498-506 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Tasaki et al.: "Optical Properties of Carbon Nanotubes" Phys.Rev.B (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshizawa et al.: "Vibronic Coupling and Jahn-Teller Effect in Negatively-Charged Benzene and [18] Annulene" J.Chem.Phys.(in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tanaka et al.: "Bond Alternation in Carbon Nanotubes Including Sigma-Electrons" Int.J.Quantum Chem.63. 637-644 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Ago et al.: "Theoretical Stuby of Lithium-Doped Amorphous Carbon Materials" Bull.Chem.Soc.Jpn.70. 1717-1726 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Yoshizawa et al.: "Bandgap Oscillation in Polyphenanthrenes" J.Phys.Chem.B. 102. 498-506 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Tasaki et al.: "Optical Properties of Carbon Nanotubes" Phys.Rev.B. (in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Yoshizawa et al.: "Vibronic Coupling and Jahn-Teller Effect in Negatively-Charged Benzene and [18] Annulene" J.Chem.Phys.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Tanaka et al.: "Electronic Property of Polyacene in a Constant Magnetic Field Perpendicular to Condenses Aromatic Ring Plane" Synth.Met.79. 145-148 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Tanaka et al.: "Estimation of Superconducting Transition Temeperature in Metallic Carbon Nanotyubes" Phys.Rev.B. 53. 5129-5132 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Tanaka et al.: "Estimation of Peierls-Transition Temperature in Metallic Carbon Nanotyube" Solid State Commun.97. 303-307 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T. Yamabe: "Recent Development of Carbon Nanotubes" Synehtic Metals. 70. 1511-1518 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Yamabe: "Estimation of Peierls Transition Temperature in Metallic Carbon Nanotube" Solid State Communications. 97. 303-307 (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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