| Project/Area Number |
07454173
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | OCHANOMIZU UNIVERSITY,FACULTY OF SCIENCE |
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Principal Investigator |
FUKUDA Yutaka OCHANOMIZU UNIV.PROFESSOR, 理学部化学科, 教授 (30021950)
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| Co-Investigator(Kenkyū-buntansha) |
FRANZ Renz 日本学術振興会, 外国人特別研究員
MORI Yukie Ochanomizu University, Research Associate, 理学部, 助手 (90239624)
RENZ Franz Ochanomizu University, Post-doctoral Fello
YAMADA Yasunori Ochanomizu University, Research Assistant
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| Project Period (FY) |
1995 – 1997
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| Project Status |
Completed (Fiscal Year 1997)
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| Budget Amount *help |
¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 1997: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1996: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1995: ¥4,700,000 (Direct Cost: ¥4,700,000)
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| Keywords | Dinuclear complex / Chromotropism / Mixed chelate complex / Lanthanide complex / 多核錯体 / ソルバトクロミズム / サーモクロミズム / テトラケトン / トリケトン / 立体構造制御 |
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| Research Abstract |
As mentioned in the key-words column, we have studied (1) formation of mixed ligand complexes, (2) solution studies of chromotropic behaviors of the complexes obtained, (3) formation of the dinuclear or polynuclear complexes. For the formation of mixed ligand complex, we could explain the important concept as the siutable combination between pi-base and pi-acid intra-molecular inter-ligand interaction (for example, bipy (2,2'-bipyridine or 1,10-phenanthroline) and pyca (catecholate)) by means of stretched thin firm polarized electronic spectra and theoretical calculations. For the chromotropic behaviors of the complexes, we could obtain new type of the triketonate instead of tetraketone which can forms mononuclear complexes of Cu (II) ion with N-alkylate ethylenediamine. They showed solvatochromism, and thermochomism. We have obtained dinuclear and trinuclear Pd (II) complexes with tetraketonate bridging ligand and beta-diketpnate also as the mixed ligand complexes.
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