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Structural control of polynuclear complexes and their chromotropic behaviors

Research Project

Project/Area Number 07454173
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOCHANOMIZU UNIVERSITY,FACULTY OF SCIENCE

Principal Investigator

FUKUDA Yutaka  OCHANOMIZU UNIV.PROFESSOR, 理学部化学科, 教授 (30021950)

Co-Investigator(Kenkyū-buntansha) FRANZ Renz  日本学術振興会, 外国人特別研究員
MORI Yukie  Ochanomizu University, Research Associate, 理学部, 助手 (90239624)
RENZ Franz  Ochanomizu University, Post-doctoral Fello
YAMADA Yasunori  Ochanomizu University, Research Assistant
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 1997: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1996: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1995: ¥4,700,000 (Direct Cost: ¥4,700,000)
KeywordsDinuclear complex / Chromotropism / Mixed chelate complex / Lanthanide complex / 多核錯体 / ソルバトクロミズム / サーモクロミズム / テトラケトン / トリケトン / 立体構造制御
Research Abstract

As mentioned in the key-words column, we have studied (1) formation of mixed ligand complexes, (2) solution studies of chromotropic behaviors of the complexes obtained, (3) formation of the dinuclear or polynuclear complexes. For the formation of mixed ligand complex, we could explain the important concept as the siutable combination between pi-base and pi-acid intra-molecular inter-ligand interaction (for example, bipy (2,2'-bipyridine or 1,10-phenanthroline) and pyca (catecholate)) by means of stretched thin firm polarized electronic spectra and theoretical calculations. For the chromotropic behaviors of the complexes, we could obtain new type of the triketonate instead of tetraketone which can forms mononuclear complexes of Cu (II) ion with N-alkylate ethylenediamine. They showed solvatochromism, and thermochomism. We have obtained dinuclear and trinuclear Pd (II) complexes with tetraketonate bridging ligand and beta-diketpnate also as the mixed ligand complexes.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] F.Jalilehvand et al.: "Copper(II)mixed ligand complex with N-alkylated diamine and a new β-diketonate" Chem.Lett.Vol.1995. 743-744 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Harada et al.: "d-f Metal ion interaction through Fe-CN-Ln bridge between dicyanobis(1,10-phenanthroline)iron(II)complex and LnCl3" Chem.Lett.Vol.1995. 887-888 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yamada et al.: "Electronic stucture of(2,2′-bipyridine)(catecholato)copper(II)" Mol.Cryst.Liq.Cryst.Vol.286. 23-28 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yamada et al.: "Electronic structure of(catecholato)(1,10-phenanthroline)copper(II) : Intramolecular interligand electronic interactions" J.Coord.Chem.,. Vol.38. 1-13 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Jalilehvand et al.: "Syntheses of new copper(II)mixed ligand complexes and their chromotropic properties in solution and in the solid state" J.Chem.Soc.Dalton Trans.Vol.1996. 3251-3256 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Kobayashi et al.: "Syntheses and structure of new dinuclear palladium(II)complexes with 1,1,2,2-tetraacetylethanate and β-diketonate" Chem.Lett.Vol.1996. 663-664 (1966)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Masuda et al.: "Solvent effect on Ultra-fast electron transfer in mixed-valence biferrocene monocation" J.Mol.Liq.Vol.65/66. 397-400 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "Pd(II)-Ln(III)complexes of a dinucleating ligand,N,N′-bis(3-carboxylsalicylidene)ethylenediamine" Synth.React.Inorg.Met.-Org.Chem.Vol.26. 21-30 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "Ni(II)-Ln(III)Complexes of the dinucleating ligand,N,N′-bis(3-hydroxysalicylidene)ethylenediamine" J.Corrd.Chem.Vol.38. 347-354 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "V(IV)-Ln(III)complexes(Ln=La,Eu,or Gd)of the compartmental ligand N,N′-bis(3-hydroxysalicylidene)-ethylenediamine" J.Alloys Comp.Vol.238. 23-27 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Jalilehvand et al.: "Copper (II) mixed ligand complex with N-alkylated diamine and a new beta-diketonate" Chem.Lett.1995. 743-744 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Harada et al.: "d-f Metal ion interaction through Fe-CN-Ln bridge between dicyanobis (1,10-phenanthroline) iron (II) complex and LnC13" Chem.Lett.1995. 887-888 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yamada et al.: "Electronic stucture of (2,2'-bipyridine) (catecholate) copper (II)" Mol.Cryst.Liq.Cryst.286. 23-28 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yamada et al.: "Electronic structure of (catecholato) (1,10-phenanthroline) copper (II) : Intramolecular interligand electronic interactions" J.Coord.Chem.38. 1-13 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Jalilehvand et al.: "Syntheses of new copper (II) mixed ligand complexes and their chromotropic properties in solution and in the solid state" J.Chem.Soc.Dalton Trans.1996. 3251-3256 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Kobayashi et al.: "Syntheses and structure of new dinuclear palladium (II) complexes with 1,1,2,2-tetraacetylethanate and beta-diketonate" Chem.Lett.1996. 663-664 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Masuda et al.: "Solvent effect on Ultra-fast electron transfer in mixed-valence biferrocene monocation" J.Mol.Liq.65/66. 397-400 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "Pd (II) -Ln (III) complexes of a dinucleating ligand, N,N'-bis (3-carboxylsalicylidene) ethylenediamine" Synth.React.Inorg.Met.-Org.Chem. 26. 21-30 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "Ni (II) -Ln (III) complexes of the dinucleating ligand, N,N'-bis (3-hydroxysalicylidene) ethylenediamine" J.Corrd.Chem.38. 347-354 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "V (IV) -Ln (III) complexes (Ln=La, Eu, or Gd) of the compartmental ligand N,N'-bis (3-hydroxysalicylidene) -ethylenediamine" J.Alloys Comp.238. 23-27 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Jalilerand et al.: "Copper(II)Mixed ligand Complex with N-Alkylated Diamine and a New B-Diketonate" Chem.Lett.1995. 743-744 (1995)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Harata et al.: "d-f Metal Ion Interaction throngh Fe-C≡N-Ln Bridge Between Dicyanobis(1,10-phenan throline)iron(II)complex and LnCl_3" Chem.Lett.1995. 887-888 (1995)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yamada et al.: "Electronic Structure of (2,2′-Bipyricline)(catecholato)copper(II)" Mol.Cryst.Lig.Cryst. 286. 23-28 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yamada et al.: "Electronic Structure of (cate cholato)(1,10-phenun ehroline)copper(II):Intra molecular interligand Electronic interactions" J.Cond.Chem.38. 1-13 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] F.Jalilerhvand et al.: "Syneheses of new copper(II)mixed ligand complexes and their chromotropic propersties in solution and in the solid state" J.Chem.Soc.Dalton.Frans.1996. 3251-3256 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Kobayashi et al.: "Syneheses and Structure of new Dinnclean Palladium(II)complexes with 1,1,2,2-Tetra a cetylethanate and B-Diketonate" Chem.Lett.1996. 663-664 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 福岡豊他 編著: "詳説 無機化学" 講談社サイエンティフィック, 292 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 大野公一 他著: "化学入門" 共立出版, 168 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yamada,T.Hoshi,Y.Fukuda: "Electronic Structure of (Catecoholats)(1.10-phenanthroline)copper(II)Intermolecular Interlig and Electronic interactions" J.Coord.Chem.38. 1-13 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] F.Jalilehu and,他4名: "Syntheses of new copper (II)-mixedligand complexes and their chromotropic propenties in solution and in the solid state" J.Chem.Soc.Dalton Trans.1996. 3251-3256 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kobayashi,他4名: "Syneleses and Structure of new dimochear palladium(II)complexes with 1,1,2,2-tetracetylechanate and β-dikefonate" Chemistry Letters. 1996. 663-664 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Harada et al.: "d-f.Metal Lon Interaction through Fe-C≡N-Ln Bridge between Dicyanobis(1.10-phnan throline)iron(11)complex and Lncl_3" Chemistry Letters. 887-888 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] F.Jalilehvand et al.: "Copper(11)Mixed Ligand Complex with an N-Alkylated Diamine and a New β-Diketonates" Chemistry Letters. 743-744 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Kambayashi et al.: "4-and 5-Coordinate Dinuclear Capper(11)Complexes with the Tetraacetylehamediide and an N-Alkylated Diamine or a Triamine" Zeitschrift fiir Naturforschung. 506. 536-544 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Unoura et al.: "Conelation between ^<95>Mo-NMR chemical shifts and rate constants of O-atom transtor reactions of vanious cis-MoO_2(dtc)complexes with PPh3" Inorganica Chimica Acta. 228. 89-92 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Yoshida et al.: "Fhermo-analytical and X-ray Diffractometsic Observations of a Plastically Cvystalline Phase in Mopecnlar Mixed-Lig and Complex" Solid State Communications. 93. 159-162 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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