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Speciation of Organotin (IV) Compounds and Evaluation of Light-Induced Decomposition Reaction

Research Project

Project/Area Number 07454199
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 分離・精製・検出法
Research InstitutionNagoya University

Principal Investigator

FUNAHASHI Shigenobu  Nagoya University, Faculty of Science, Professor, 大学院・数理研究科, 教授 (30022700)

Co-Investigator(Kenkyū-buntansha) AIZAWA Sen-ichi  Shizuoka, University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (60231099)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,800,000 (Direct Cost: ¥7,800,000)
Fiscal Year 1996: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1995: ¥5,300,000 (Direct Cost: ¥5,300,000)
KeywordsOrganotin (IV) / Speciation / Complexation / Triphenyltin (IV) Radical / Alkyltin (IV) Compound / アルキルスズ(IV)化合物
Research Abstract

Results of speciation, equilibrium, and structural characterization of organotin (IV) compounds in aqueous solution are as follows :
1. Hydrolysis and complexation of organotin (IV) compounds in aqueous solution
(1) Equilibrium constants for hydrolysis of dimethyltin (IV), trimethyltin (IV), and triethyltin (IV) ions were determined by potentiometry. Hydroxo-bridged polymers exist. The relation between their structures and polymerization reactions has been clarified.
(2) Equilibrium constans for complexation of dimethyltin (IV) and trimethyltin (IV) with aminopolycarboxylates (EDTA,NTA,EDDA,MIDA,PDA) were determined. Electron donicity of the ligands is important for the structure which affects the chelate formation.
2. Determination of structure of organotin (IV) conpounds
(1) Crystal structures of complexes of dimethyltin (IV) with five aminopolycarboxylates were determined by X-ray analysis. It has been demonstrated that the tin atom is versatile for 3-, 4-, 5-, 6-, and 7-coordinate and that the configuration of the tin is affected by donation of the ligands.
(2) By the EXAFS method, were determined the structures around the central tin atoms for several organotin (IV) compounds in an scidic aqueous solution.
3. Decomposition of organotin (IV) compounds by laser
Decomposed products of methyltin (IV) and tetraphenyltin (IV) by laser were analyzed by ^1H-NMR and the dynamic behavior of triphenyltin (IV) radical produced was observed as a function of water concentration.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (52 results)

All Other

All Publications (52 results)

  • [Publications] S. Kagawa et al.: "Kinetic study on Complexation of Boric Acid with 4-Isopropyltropolone in Nonaqueous Solvents" Inorganica Chimica Acta. 231. 115-119 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S. Aizawa et al.: "Multinuclear Magnetic Resonance Studies on Solvent Exchange of Cobalt (II), Iron (II), and Manganese (II) Ions in Ethylenediamine. Kinetic Chelate Effect and Chelate strain Effect" Inorganic Chemistry. 34. 2042-2047 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Inamo et al.: "Reactivities of Fove-Coordinate Intermediate Generated by Laser Photolysis of Monoligated Chloro (5,10,15,20-tetraphenylporphinato) chromium (III) in Toluene" Bulletin of the Chemical Society of Japan. 68. 2293-2303 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. D. Takagi et al.: "Mechanistic Study of Oxidation Reaction of Hydroquinone, Catecol, and L-Ascorbic Acid by Dicyanobis (1,10-phenanthroline) iron (III) in Dimethyl Sulfoxide" Journal of Molecular Liquids. 65/66. 277-280 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S. Aizawa et al.: "Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel (II) and Palladium (II), [Ni(bpy)_2(CF_3SO_3)_2] and [Pd(triphosphine)(CF_3SO_3)](CF_3SO_3)・C_6H_6, and Characterization of Coordination Ability of CF_3SO_3" Analytical science. 11. 557-562 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S. Aizawa and S. Funahashi: "Characterization of σ and π Donation of Solvents by^<31>PNMR Chemical Shifts of Trigonal-Bipyramidal Palladium (II) Complexes with Tris (2-diphenylphosphinoethyl) phosphine" Analytical Science. 12. 27-30 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S. Aizawa et al.: "Nitrogen-14 NMR Study on Solvent Exchange of Octahedral Cobalt (II) Ion in Neat 1,3-Propanediamine and n-Propylamine at Various Temperatures and Pressures. Tetrahedral-Octahadral Equilibrium of Solvated Cobalt (II) Ion in n-Propylamine As Studied by EXAFS and Electronic Absorption Spectroscopy" Inorganic Chemistry. 35. 1338-1342 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S. Aizawa et al.: "Complexation Equilibria and Structures of Dimethyltin (IV) Complexes with N-Methylimino-diacetate, Pyridine-2, 6-dicarboxylate, Ethylenedi-amine-N, N-diacetate, and Ethylenediamine-N, N, N, N-tetraacetate" Inorganica Chimica Acta. 248. 215-224 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. Yagyu et al.: "Crystal Structures and Acetonitrile Exchange of Palladium (II) Complexes with Bis (3-amino-propyl) amine and Diethyltriamine. Effects of Ion-Pair Formation" Bulletin of the Chemical Society of Japan. 69. 1961-1967 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S. Aizawa et al.: "Mechanistic Studies on Halo-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Palladium (II) Complexes of Tris (2-(diphenylphosphino) ethyl) phosphine with Trimethyl Phosphite in Chloroform at Various Temperatures and Pressures" Inorganic Chemistry. 35. 5163-5167 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y. Inada et al.: "Spectral Evidence and Kinetics for Formation of the Sitting-Atop Complex of Copper (II) Ion with 5, 10, 15, 20-Tetraphenylporphyrin in Acetonitrile" Chemistry Letters. 881-882 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. Yagyu et al.: "Kinetics and Mechanism of Cyclopalladation for [Pd(S)(Bn_2Me dptn)](BF_4)_2(S=Solvent, Bn_2Medptn=N, N″-Dibenzl-N′-methyl-3, 3′-diaminodipropylamine) and its Derivatives" Chemistry Letters. 1107-1108 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Matsumoto et al.: "Oxidation Reaction of L-Ascorbic Acid by Dicyanobis (1, 10-phenenthroline) iron (III) in Demethyl Sulfoxide at Elevated Pressures. Evidence for the Adiabatic Electron Transfer" Inorganica Chimica Acta. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Inamo et al.: "Thermodynamic and Kinetic Studies on Complexation of 5, 10, 15, 20-Tetrakis (4-sulfonato-phenyl) porphine and Its N-Methylated Derivative with Zinc (II) and Cadmium (II) Ions in Aqueous Solution at Various Temepratures and Pressures. Effects of Metal Ion Size and Porphine Ring Deformation on Metal-Ion Incorporation to Porphyrins" Inorganica Chimica Acta. ((in press))

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 舟橋,重信: "詳説無機化学" 講談社サイエンティフィック, 20 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 舟橋,重信: "無機溶液反応の化学" 裳華房(印刷中),

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kagawa et al.: "Kinetic Study on Complexation of Boric Acid with 4-Isopropyltropolone in Nonaqueous Solvents" Inorganic Chimica. 231. 115-119 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa et al.: "Multinuclear Magnetic Resonance Studies on Solvent Exchange of Cobalt (II) , Iron (II), and Manganese (II) Ions in Ethylenediamine. Kinetic Chelate Effect and Chelate Strain Effect" Inorganica Chemistry. 34. 2042-2047 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Inamo et al.: "Reactivities of Five-Coordinate Intermediate Generated by Laser Photolysis of Monoligated Chloro (5,10,15,20-tetraphenylporphinato) -chromium (III) in Toluene" Bulletin of the Chemical Society of Japan.68. 2293-2303 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.D.Takagi et al.: "Mechanistic Study of Oxidation Reaction of Hydroquinone, Catecol, and L-Ascorbic Acid by Dicyanobis (1,10-phenanthroline) iron (III) in Dimethyl Sulfoxide" Journal of Molecular Liquids. 65/66. 277-280 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa et al.: "Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel (II) and Palladium (II), [Ni(bpy)_2(CF_3SO_3)_2] and [Pd(triphosphine)(CF_3SO_3)(CF_3SO_3)-C_6H_6, and Characterization of Coordination Ability of CF_3SO_3^-" Analytical Science. 11. 557-562 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa and S.Funahashi: "Characterization of and pi Donation of Solvents by ^<31>PNMR Chemical shifts of Trigonal-Bipyramidal Palladium (II) Complexes with Tris (2-diphenylphosphinoethyl) phosphine" Analytical Science. 12. 27-30 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa et al.: "Nitrogen-14 NMR Study on Solvent Exchange of Octahedral Cobalt (II) Ion in Neat 1,3-Propanediamine and pi-Propylamine at Various Temperatures and Pressures. Tetrahedral-Octahedral Equilibrium of Solvated Cobalt (II) Ion in n-Propylamine As Studied by EXAFS and Electronic Absorption Spectroscopy" Inorganic Chemistry. 35. 1338-1342 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa et al.: "Complexation Equilibria and Structures of Dimethyltin (IV) Complexes with N-Methylimino-diacetate, Pyridine-2,6, dicarboxylate, Ethylenediamine-N,N-diacetate, and Ethylenediamine-N,N,N', N'-tetraaetate" Inorganica Chimica Acta.248. 215-224 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Yagyu et al.: "Crystal Structures and Acetonitrile Exchange of Palladium (II) Complexes with Bis (3-amino-propyl) amine and Diethyltriamine. Effects of Ion Pair Formation" Bulletin of the Chemical Society of Japan.69. 1961-1967 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa et al.: "Mechanistic Studies on Halo-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Palladium (II) Complexes of Tris (2-(diphenyl-phosphino)ethyl) phosphine with Trimethyl Phosphite in Chloroform at Various Temperatures and Pressures" Inorganic Chemistry. 35. 5163-5167 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Inada et al.: "Spectral Evidence and Kinetics for Formation of the Sitting-Atop Complex of Copper (II) Ion with 5,10,15,20-Tetraphenylporphyrin in Acetonitrile" Chemistry Letters. 881-882 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Yagyu et al.: "Kinetics and Mechanism of Cyclopalladation for [Pd(S)(Bn_2Medptn)(BF_4)_2(S=Solvent, Bn_2Medptn=N,N'-Dibenzyl-N"-methyl-3-3'-diaminodipropylamine) and Its Derivatives" Chemistry Letters. 1107-1108 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Matsumoto et al.: "Oxidation Reaction of L-Ascorbic Acid by Dicyanobis (1,10-phenenthroline) iron (III) in Dimethyl Sulfoxide at Elevated Pressures. Evidence for the Adiabatic Electron Transfer" Inorganica Chimica Acta. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Inamo et al: "Thermodynamic and Kinetic Studies on Complexation of 5,10,15,20-Tetrakis (4-sulfonato-phenyl) porphine and Its-N-Methylated Derivative with Zinc (II) and Cadmium (II) Ions in Aqueous Solution at Various Temepratures and Pressures. Effects of Metal Ion Size and Prophine Ring Deformation of Metal-Ion Incorporation to Porphyrins" Inorganica Chimica Acta. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Aizawa and S.Funahashi: "Characterization of σ and π Donation of Solvents by ^<31>P NMR Chemical Shifts of Trigonal-Bipyramidal Palladium(II) Complexes with Tris(2-diphenylphosphinoethyl)phosphine" Analytical Science. 12. 27-30 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Aizawa et al.: "Nitrogen-14 NMR Study on Solvent Exchange of Octahedral Cobalt(II)Ion in Neat 1,3-Propanediamine and n-Propylamine at Various Temperatures and Pressures. Tetrahedral-Octahedral Equilibrium of Solvated Cobalt(II)Ion in n-Propylamine As Studied by EXAFS and Electronic Absorption Spectroscopy" Inorganic Chemistry. 35. 1338-1342 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Aizawa et al.: "Complexation Equilibria and Structures of Dimethyltin(IV)Complexes with N-Methylimino-diacetate,Pyridine-2,6-dicarboxylate,Ethylenedi-amine-N,N′-diacetate,and Ethylenediamine-N,N,N′,N′-tetraacetate" Inorganica Chimica Acta. 248. 215-224 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Yagyu et al.: "Crystal Structures and Acetonitrile Exchange of Palladium(II)Complexes with Bis(3-amino-propyl)amine and Diethyltriamine. Effect of Ion-Pair Formation" Bulletin of the Chemical Society of Japan. 69. 1961-1967 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Aizawa et al.: "Mechanistic Studies on Halo-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Palladium(II)Complexes of Tris(2-(diphenylphosphino)ethyl)phosphine with Trimethyl Phosphite in Chloroform at Various Temperatures and Pressures" Inorganic Chemistry. 35. 5163-5167 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Inada et al.: "Spectral Evidence and Kinetics for Formation of the Sitting-Atop Complex of Copper(II)Ion with 5,10,15,20-Tetraphenylporphyrin in Acetonitrile" Chemistry Letters. 881-882 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Yagyu et al.: "Kinetics and Mechanism of Cyclopalladation for[Pd(S)(Bn_2Me dptn)](BF_4)_2(S=Solvent,Bn_2Medptn=N,N″-Dibenzyl-N′-methyl-3,3′-diaminodipropylamine)and Its Derivatives" Chemistry Letters. 1107-1108 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Matsumoto et al.: "Oxidation Reaction of L-Ascorbic Acid by Dicyanobis(1,10-phenenthroline)iron(III)in Dimethyl Sulfoxide at Elevated Pressures. Evidence for the Adiabatic Electron Transfer" Inorganica Chimica Acta. (in press).

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Inamo et al.: "Equilibria,Kinetics,and Mechanism of Complexation of 5,10,15,20-Tetrakis(4-sulfonatophenyl)porphine and Its N-Methylated Derivative with Cadmium(II)and Zinc(II)Ions in Aqueous Solution at Various Temepratures and Pressures. Effects of Metal Ion Size and Porphyrin Ring Deformation on Metal Ion Incorporation" Inorganica Chimica Acta. (in press).

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Tsutsui et al.: "EXAFS and Ab Initio Molecular Orbital Studies on the Structure of Solvated Silver(I)Ions" The Journal of Physical Chemistry. (in press).

    • Related Report
      1996 Annual Research Report
  • [Publications] 舟橋重信: "詳説 無機化学" 講談社サイエンティフィック, 20 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 舟橋重信: "無機溶液反応の化学" 裳華房(印刷中),

    • Related Report
      1996 Annual Research Report
  • [Publications] Shuji Kagawa: "Kinetic Study on Complexation of Boric Acid with 4-Isopropyltropolone in Nonaqueous Solution" Inorganica Chimica Acta. 231. 115-119 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Variable-Temperature and-Pressure Multinuclear Magnetic Resonance Studies on Solvent Exchange of Cobalt (II),Iron (II),and Manganese (II) Ions in Ethylenediamine" Inorganic Chemistry. 34. 2042-2047 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hideo D Takagi: "Mechanistic Study of Oxidation Reaction of Hydroquinone,Catechol,and L-Ascorbic Acid by Dicyanobis(1,10-phenanthroline)iron (III) in Dimethyl sulfoxide" Journal of Molecular Liquids. 65/66. 277-280 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel (II) and Palladium (II), [Ni(bpy)_2 (CF_3SO_3)_2] and [Pd (triphosphine) (CF_3SO_3)・C_6H_6,and Characterization of the Coordination Ability of CF_3SO_3" Analytical Science. 11. 557-562 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Masahiko Inamo: "Reactivity of Five-Coordinate Intermediate generated by Laser Photolysis of Monoligated Chloro(5,10,15,20-teraphenylporphinato)chromium (III) in Toluene" Bulletin of the Chemical Society of Japan. 68. 2293-2303 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Characterization of σ and π Donation of Solvents by ^<31>PNMR Chemical Shifts of Trigonal-Bipyramidal Palladium (II) Complexes with Tris (2-diphenylphosphinoethyl)phosphine" Analytical Science. 12. 27-230 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Mitsuru Matsumoto: "Oxidation Reaction of L-Ascorbic Acid by Dicyanobis (1,10-phenanthroline) iron (III) in Dimethyl Sulfoxide at Elevated Pressures.Evidence for the Adiabatic Electron Transfer" Inorganica Chimica Acta. (in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Nitrogen-14 NMR Study on Solvent Exchange of Octahedral Cobalt (II) Ion in Neat 1,3-Propanediamine and n-Propylamine at Various Temperatures and Pressures" Inorganic Chimistry. (in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sen-ichi Aizawa: "Complexation Equilibria and Structures of Dimethyltin (IV) Complexes with N-Methyliminodiacetate,Pyridine-2,6-dicarboxylate,Ethylenediamine-N,N′-diacetate and Ethylenediamine-N,N,N′,N′-tetraacetate" Inorganica Chimica Acta. (in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 舟橋重信: "詳説無機化学" 講談社,

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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