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Study of Composition・structures at Joined Interface and its properties by Ion-Implantation

Research Project

Project/Area Number 07455251
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

TAKAHASH Heishichiro  Hokkaido University, Center for Advanced Res.of Energy Tech.. Pro., エネルギー先端工学研究センター, 教授 (80001337)

Co-Investigator(Kenkyū-buntansha) WATANABE Seiichi  Hokkaido University, Center for Advanced Res.of Energy Tech. Assis., エネルギー先端工学研究センター, 助手 (60241353)
KINOSHITA Hiroshi  Hokkaido University, Fac.of Eng., Assis., 工学部, 助手 (40177895)
KUROKAWA Kazuya  Hokkaido University, Fac.of Eng., As.Pro, 工学部, 助教授 (00161779)
OHNUKI Soumei  Hokkaido University, Fac.of Eng., Pro., 工学部, 教授 (10142697)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥5,300,000 (Direct Cost: ¥5,300,000)
Fiscal Year 1996: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1995: ¥3,500,000 (Direct Cost: ¥3,500,000)
KeywordsSurface modification / Silicide / Mixing / Oxidation-resistance / Radiation-enhanced diffusion / point defects / Joining interface / Lower-temperature-joining / 耐酸化性 / 促進拡散 / 非晶質 / 二次欠陥
Research Abstract

1) Joining of MoSi_2/graphite : Interfacial reaction between MoSi_2 siliside and graphite in joining processes using a spark plasma sintering equipment was studied, in order to improve the ultra-high temperature resistance. The formation of SiC layr was perfectly suppressed by interposing a titanium foil between MoSi_2 and graphite, and the high strength was achieved by this joining process.
2) Structural change under ion-implantation and the control of Interface : Interfaces such as grain boundary and the surface structures in seramics, semiconductors and steels were studied under ion-implating processes. During ion-implanting the secondary defects were formed, and especially Al_2O_3 was amorphized in the process of mixing from boundary due to increasing dose of ion-implantation.
3) Interfacial structure control between Mo/Si mateials : Diffusions of Mo and Si were enhanced by point defects produced during ion-implantation. Due to this enhanced diffusion the possibility of joining at lower temperature was found.
4) Interfacial structures at Si/Oxide film and defect structure near the interface : Stress generated at interface between oxide and Si accerelates the point defects flow towards the interface and from this it is suggested that the preferential flow of point defects makes relaxation at interfacial stress.
From these results joining at lower temperature is possible by using ion-implantation method, furthermore by combining the a sark plasma sintering the possibility of joining for special alloy system was suggested.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] 黒川 一哉: "放電プラズマ焼結によるMoSi_2/Ti/グラファイト系の界面反応と接合" プラズマ応用化学. 3. 7-12 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 黒川 一哉: "Interfacial Research in Joining of MoSi2 to Graphite by SPS Method" Materials Trans.JIM. 37. 743-747 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 黒川 一哉: "Effect of reinforcing materials on high temperature oxidation behavior of MoSi2-based composites" Proc.13th Inter.Corrosion congress. 1406-1412 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 渡辺 精一: "Theoretical Prediction of Compositional Variation in Alloy under High Irradiation" Proc.for 96 Symposium on Advanced Research of Energy Technology. 371-375 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 高橋 平七郎: "Observation of Point Defevt Production and Clustering by High Voltage Electron Microscopy" Micron. 27. 239-245 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 高橋 平七郎: "超高圧電子顕微鏡法によるイオン・電子線照射下における格子欠陥と溶質原子の相互作用" 日本電子顕微鏡学会シンポジウム論文集. 37-40 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kurokawa: "Joining and Interfacial Reaction in a MoSi_2/Ti/Graphite System by Spark Plasma Sintering." J.of JASPS. Vol.3. 7-12 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kurokawa: "Interfacial Research in Joining of MoSi_2 to Graphite by SPS Method." Materials Trans.JIM.Vol.37. 743-747

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kurokawa: "Effect of reiforcing materials on high temperature oxidation hehavior of MoSi_2-based composites." proc.13th Inter.Corrosion Congress. 1406-1412 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Watanabe: "Theoretical Prediction of Compositional Variation in Alloy under High-Energy Irradiation." Proc.for 96 Symposium on Advanced Reaesrch of Energy Technology.371-375 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takahashi: "Observation of Point Defect Production and Clustreing by High Voltage Electron Microscopy." Micron. Vol.27. 239-245 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takahashi: "Interaction between Solutes and Dfects under Irradiation by Ions/Electrons using HVEM." Proc.of the 41th Symp.of Jpn.Soc.of Electron Microscopy. 37-40 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 黒川一哉: "放電プラズマ焼結によるMoSi_2/Ti/グラファイト系の界面反応と接合" プラズマ応用化学. 3. 7-12 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] 黒川一哉: "Interfacial Research in Joining of MoSi2 to Graphite by SPS Method" Materials Trans. JIM. 37. 743-747 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 黒川一哉,高橋平七郎: "セラミックス/金属界面における反応と構造解析" 日本金属学会誌. (発表予定). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Horibe,K,Kurokawa: "Interfecial Reaction in Joining of MoSi_2 to graphite" Meterials Transaction,JIM. (発表予定). (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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