| Project/Area Number |
07455309
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
化学工学一般
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| Research Institution | KYUSHU UNIVERSITY |
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Principal Investigator |
MOROOKA Shigeharu Kyushu University, Dept. of Chem. Sci. & Technol., Professor, 工学部, 教授 (60011079)
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| Co-Investigator(Kenkyū-buntansha) |
HAYASHI Jun-ichiro Hokkaido University, Center of Advanced Research of Energy Technology, Associate, エネルギー先端工学研究センター, 助教授 (60218576)
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| Project Period (FY) |
1995 – 1996
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| Project Status |
Completed (Fiscal Year 1996)
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| Budget Amount *help |
¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 1996: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1995: ¥5,400,000 (Direct Cost: ¥5,400,000)
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| Keywords | Coal / Plastic wastes / Flash Pyrolysis / Radical / Solvent Swelling / Coal Structure / Aromatic Compounds / 軽質芳香族 / ラジカル移動 / 軟質芳香族 |
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| Research Abstract |
In the present study, we have proposed a novel flash pyrolysis process of coal by utilizing plastics as radical donors. This process is related to recycle of plastic wastes and is based on an intimate contact of pulverized coal and polyolefins by a light heat-treatment.
(1) Even when polyolefin was impregnated on pulverized coal by mechanical mixing, yields of monomers and light aromatic compounds such as BTX in flash pyrolysis were effectively increased. This suggests that hydrogen and hydrocarbon radicals were transferred from polyolefin to coal in a short reaction period.
(2) Polyolefins, which were pyrolyzed lightly at 360-420ﾟC for 1 hour, were dissolved in THF,and coal-polyolefin composites were produced by adding a pulverized coal in the THF solution of polyolefins. This procedure further enhanced the contact between polyolefin and coal, and increased the production of tar at a higher yield, compared with that obtained by the pyrolysis of each components separately.
(3) When polyolefin was lightly cracked in a nitrogen atmosphere containing a small amount of oxygen, the pyrolysis temperature of polyolefin-coal mixture was decreased at least by 200ﾟC.The CO2 yield was only 2vol%.
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