• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Surface Analysis from Backside of the Surface

Research Project

Project/Area Number 07455333
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業分析化学
Research InstitutionKyoto University

Principal Investigator

KAWAI Jun  Kyoto University, Department of Materials Science and Engineering, Associate Professor, 大学院・工学研究科, 助教授 (60191996)

Co-Investigator(Kenkyū-buntansha) TANABE Teruo  Kyoto University, Department of Materials Science and Engineering, Instructor, 大学院・工学研究科, 助手 (90026237)
ASAKI Zenjiro  Kyoto University, Department of Materials Science and Engineering, Professor, 大学院・工学研究科, 教授 (90026005)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥5,700,000 (Direct Cost: ¥5,700,000)
Fiscal Year 1996: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1995: ¥4,000,000 (Direct Cost: ¥4,000,000)
KeywordsSurface analysis / Non-destructive analysis / 電圧を発生する部分,絶縁体,真空の3条件がそろえば,このような帯電によるX線を発生させる事ができる.従って,小型の電圧発生部を工夫すれば,小型のX線発生装置を作る事ができる.一方で,真空をやぶれば,X線発生は止まるので安全である.放射性同位元素のように法的規制を受けず,しかも,被曝する危険や,廃棄の点で利便性のある放射線源としての応用の可能性もある.
Research Abstract

It is important in analytical chemistry, natural science, or engineering, to study surfaces. In the surface analysis, the surface is irradiated by quanta called probing particle, and the resulted signal emitted from the surface is observed. However, sometimes, the surface cannot probed from the surface, because of the surface is in a hard environment to approach.In such a case, photo-acoustic spectroscopy, supersonic, or transmitted x-rays are used to probe the surface. The development of such a new surface analysis method is the aim of the present research. We have tried synchrotron radiation source x-ray absorption spectroscopy, photo-acoustic spectroscopy, and charge-up and discharge phenomena to develop surface analysis methods. We have obtained the following three important results.
(1) x-ray emission due to charge-up effect.
(2) Field emission of electrons using a new mechanism.
(3) Surface and fine particle chemical analysis using sample current.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] K. Hayashi, S. Kawato…J. Kawai: "Photoelectron spectra enhanced by x-ray total reflection and diffraction from periodic multilayer" Appl. phys. Lett.64. 1921-1923 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 河合潤 北島義典 朝木善次郎: "亜鉛流動焙焼炉焼鉱の硫黄の化学状態" X線分析の進歩. 27. 235-244 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J. Kawai, K. Maeda N. Sakauchi, I. Konishi: "Strong x-rau emission due to electrification" Nucl. Instrum. Methods Phys. Res.B109/110. 206-208 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 田辺晃生,溝口将康 朝木善次郎: "還元拡散法におけるCe-Fe系金属間化合物の生成機構" 資源と素材. 112. 487-490 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K. Hayashi, J. Kawai et al.: "Evaluation of copper phthalocyanine ultra thin film by total reflection x-ray photoelectron spectroscop method" Adv. X-Ray Chem. Anal. Japan. 28. 45-52 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. Amano, J. Kawai et al.: "Characterization of island CuPc/Au multilayer using total reflection x-ray photoelectron spectroscopy" Adv. X-Ray Chem. Anal. Japan. 28. 31-44 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hayashi, S.Kawato, T.Horiuchi, K.Matsushige, Y.Kitajima, and J.Kawai: "Photoelectron spectra enhanced by x-ray total reflection and diffraction from periodic multilayr" Appl.Phys.Lett.68. 1921-1923 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Kawai, Y.Kitajima, and Z.Asaki: "Chemical state of sulfur in calcine of zinc fluidized bed roaster-In connection with the operation of the roaster-" Adv.X-Ray Chem.Anal.Japan.27. 235-244 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Kawai, K.Maeda, N.Sakauchi, and I.Konishi: "Strong X-ray emission due to electrification" Nucl.Instrum.Methods Phys.Res.B109/110. 206-208 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Tanabe, M.Mizoguchi, Z,Asaki: "Formation of Ce-Fe intermetallic compounds by reduction-diffusion process" Shigen-to-Sozai. 112. 487-490 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hayashi, J.Kawai, S.Kawato, T.Horiuchi, K.Matsushige, Y.Kitajima: "Evaluation of copper phthalocyanine ultra thin film by total reflection x-ray photoelectron spectroscopy method" Adv.X-Ray Chem.Anal.Japan. 28. 45-52 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Amano, J.Kawai, K.Hayashi, Y.Kitajima: "Characterization of island CuPc/Au multilayr using total reflection x-ray photoelectron spectroscopy" Adv.X-Ray Chem.Anal.Japan. 28. 31-44 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hayashi,S.Kawato,J.Kawai: "Photoelectron spectra enhanced by x-ray total reflection and diffraction from periodic multilayer" Appl.Phys.Lett.68(14). 1921-1923 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 河合潤,北島義典,朝木善次郎: "亜鉛流動焙焼炉焼鉱の硫黄の化学状態" X線分析の進歩. 27. 235-244 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.Kawai,K.Maeda,N.Sakauchi,I.Konishi: "Strong x-ray emission due to electrification" Nucl.Instrum.Methods Phys.Res.B109/110. 206-208 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 田辺晃生,溝口将康,朝木善次郎: "還元拡散法におけるCe-Fe系金属間化合物の生成機構" 資源と素材. 112. 487-490 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J. Kawai,: "Total reflection x-ray excited photoelectron spectra of copper phthalocyanine thin layer on Si wafer" Appl. Phys. Lett.67. 3889-3891 (1995)

    • Related Report
      1995 Annual Research Report

URL: 

Published: 1995-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi