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Synthesis, Strucure and Properties of Rare Earth Oxide-Containing Silico phosphate Glasses and Glass Seramics

Research Project

Project/Area Number 07455350
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 無機工業化学
Research InstitutionTOKYO METROPOLITAN UNIVERSITY

Principal Investigator

YAMASHITA Kimihiro  Faculty of Engineering TOKYO METROPOLITAN UNIVERSITY Assistant Professor, 工学部, 助教授 (70174670)

Co-Investigator(Kenkyū-buntansha) HAMAGAMI Jun-ichi  Faculty of Engineering TOKYO METROPOLITAN UNIVERSITY Assistant, 工学部, 助手 (30285100)
SUDA Seiichi  Faculty of Engineering TOKYO METROPOLITAN UNIVERSITY Assistant, 工学部, 助手 (50226578)
松田 元秀  東京都立大学, 工学部, 助手 (80222305)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,400,000 (Direct Cost: ¥7,400,000)
Fiscal Year 1996: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1995: ¥5,600,000 (Direct Cost: ¥5,600,000)
KeywordsRare-Earth Oxide / Silicophosphate / Solid Electolyte / Nasicon / Glass / Glass-Ceramics / Hydroxyapatite / Cerai Ceramics / ナシマン / ナトリウムイオン導電体 / ナ-プシオ / 希土類 / ナミコン / ナ-プオ / イオン伝導 / リン酸塩 / セラミックス
Research Abstract

We have carried out the studies on the synthesis, structure and properties of the rare earth oxide-containing ceramics, which cover the projects of (1) glass and glass-ceramics of Na^+-Ion conducting silicophosphates (Narpsio) , (2) Stabilized zirconia and cerai ceramics, and (3) proton conducting hydroxyapatite and its coating methods.
In project (1), we successfully produced glass-ceramics of fast sodium ion conductors, which are invaluable for application of Na/S secondary batteries. The synthetic method, conduction mechanism, and other fundamental properties were established.
In project (2), rare earth oxide-stabilized zirconia and ceria ceramics were developed as high temperature pH and oxygen sensors. For this research, we have performed the electrophoretic lamination technique which enabled to insert thin zirconia layr into conducting ceria ceramics.
In project (3), we investigated the proton conduction in ceramic hydroxyapatite, which is the well-known bimedical material. Thin film methods were also developed for this prupose. Additionally, we founf that the use of polarization property of the material is effective for crystal growth.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] K.Yamashita: "Hydrothermal Synthesis and Low Temperature Conduction Prperties" Solid State Ionics. 81. 53-60 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda: "The Effects of Sol-Gel Processes on Na^+ Ionic Condactivity" Phosphorus Research Bulletin. 5. 93-98 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita: "Microstructural Effects on Conduction Properties of Na_5YS_<14>O_<12>" Journal of Electrochemical Society. 143・7. 2180-2186 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda: "^<29>Si NMR Analysis of Reactions between Ethoxytrimethylsilane" Journal of Ceramic Society of Japan. 104・6. 476-480 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita: "Composition Effects on Na^+-Ion Conduction Properties" Solid State Ionics. 86-88. 585-588 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Inda: "High Temperature pH Sensitivities of Stabilized Zirconia and Ceria" Solid State Ionics. 86-88. 1121-1124 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Matsuda: "Conduction Properties of Oxide Ion Conductor Ca_<12>Al_<14>O_<33>" Journal of Materials Science Lecters. 15. 933-934 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda: "The Effects of Sodium Ion on Hydrolysis and Condenfation" Journal of Non-Crystalliue Solids. 197. 65-72 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Inda: "Field-Assisted Li^+-Ion Exchange of Na^+-Super Ionic Conductor" Phosphorus Research Balletin. 6. 251-254 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita: "Accerelation and Decerelation of Bone-Like Crestal" Chemistry of Materials. 8・12. 2697-2700 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda: "Synthesis of Na^+ Super Ionic Conductor in the Na_2O-Y_2O_3-P_2O_5-SiO_2" Solid State Ionics. 89. 75-80 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita: "Bonelike Coatings onto Ceramics by Reatlue Sputtering" Journal of American Ceramic Society. 79・12. 3313-3316 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita, M.Greenblatt, K.V.Ramanujachary: "Hydrothermal Synthesis and Low Temperare Conduction Properties of Substituted Ceria Ceramics" Solid State Ionics. 81. 53-60 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda, K.Yamashita, T.Umegaki: "The Effects of Sol-Gel Processes on Na^+ Ionic Conductivity for the Na_2 O-Y_2 O_3 -P_2 O_5 -SiO_2 System" Phos. Res. Bull.5. 93-98 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita, T.Umegaki, M.Tanaka, T.Nojiri: "Microstructural Effects on Conduction Properties of Na_5 YSi_4 O_<12>-Type Glass-Ceramic Na^+ -Fast Ionic Con ductors" J.Electrochem. Soc.143 (7). 2180-2186 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda, K.Yamashita, T.Umegaki: "^<29>Si NMR Analysis of Reactions between Ethoxytrimethylsilane and Alkali Ions" J.Ceram. Soc. Jpn.104 (6). 476-480 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita, T.Kakuta, B.Sakurai, T.Umegaki: "Composition Effects on Na^+ -Ion Conduction Properties and Structure of Narpsio Glass-Ceramics" Solid State Ionics. 86-88. 585-588 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Inda, K.Yamashita, T.Umegaki, M.Greenblatt: "High Temperature pH Sensitivities of Stabilized Zirconia Ceramic Films and Ceria Ceramics" Solid State Ionics. 86-88. 1121-1124 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Matsuda, Y.Inda, W.Hisamatsu K.Yamashita, T.Umegaki: "Conduction Properties of Oxide Ion Conductor Ca_<12> Al_<14> O_<33> Prepared with Solution-Synthesized Powders" J.Mat. Sci. Lett.15. 933-934 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda, M.Iwaida, K.Yamashita, T.Umegaki: "The Effects of Sodium Ion on Hydrolysis and Condensation of Diethoxydimethylsilane" J.Non-Cryst. Solids. 197. 65-72 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Inda, K.Yamashita, T.Umegaki: "Field-Assisted Li^+ -Ion Exchange of Na^+ -Super Ionic Conductor Narpsio : Method and Experiments" Phos. Res. Bull.6. 251-254 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita, N.Oikawa, T.Umegaki: "Acceleration and Deceleration of Bone-like Crystal Growth on Ceramic Hydroxyapatite by Electric Poling" Chem. Mat.8. 2697-2700 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Suda, K.Yamashita, T.Umegaki: "Synthesis of Na^+ Superionic Conductor in the Na_2 O-Y_2 O_3 -P_2 O_5 -SiO_2 System by the Gelation Induced by Moist Air or N_2" Solid State Ionics. 89. 75-80 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita, T.Yagi, T.Umegaki: "Bonelike Coatings onto Ceramics by Reactive Magnetron Sputtering" J.Am. Ceram. Soc.79. 3313-3316 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Yamashita: "Microstructural. Effects On Conduction Properties of Na_5YSi_4O_<12>-Type Glass-Ceramic." Journal of Electrochemical Society. 143・7. 2180-2186 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Yamashita: "Composition Effects on Na^+-Ion Conduction Properties and Structure" Solid State Ionics. 86-88. 585-588 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Inda: "Field-Assisted Li^+-Ion Exchange of Na^+-Superionic Conductor Narpsic" Phosphorus Research Bulletin. 6. 251-253 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Suda: "The Effects of Sodium Ion on Hydrolysis and Condensation" Journal of Non-Crystalline Solids22GD04:197. 65-72 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Suda: "^<29>Si NMR Analysis of Reactions Between Ethoxytrinethylsilane" Journal of Ceramic Society of Japan. 104・6. 476-480 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I.Inda: "High Temperature pH Sensitivities of Stabilized Zirconia" Solid State Ionics. 86-88. 1121-1124 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Matsuda: "Conduction Properties of Oxide Ion Conductor Ca_<12>Al_<14>O_<33>" Journal of Materials Science Letters. 15. 933-934 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Yamashita: "Bonelike Coatings on to Ceramics by Reactive Magnetron Sputtering" Journal of American Ceramic Society. 79・12. 3313-3316 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Yamashita: "Acceleration and Deceleration of Bone-Like Crystel Growth" Chemisry of Materials. 8・12. 2697-2700 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N.Oikawa: "Removal of Ambient Hydrogen Isotope by Apatite Ceramics" Proc.Int'l Enviroment.Issue Ceram.236-241 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] N.Wada: "Effects of Divaleut Cations upon Nucleations of Double Diffusion" J.Crystal Growth. 148. 297-304 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Yamashita: "Thermal Instability and Proton Canductivity of Ceramic Hydroxyapatite" J.Amer.Ceram.Soc.78. 1191-1197 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 丁 旭豊: "電気泳動法によるアルミナセラミックスへのリン酸カルシウムのコーティング" 日本セラミックス学術論文誌. 103. 119-121 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Yamashita: "Proton Conduction in Sodium-Substituted Calcium Hydroxyapatite" Inorg.Mat.2. 101-104 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Yamashita: "Hydrothermal Synthesis and Low Temperoture Condaction Properties of・・・" Solid State Ionics. 81. 53-60 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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