| Project/Area Number |
07455368
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
高分子合成
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| Research Institution | HOKKAIDO UNIVERSITY |
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Principal Investigator |
TABATA Masayoshi Hokkaido Univ., Graduate School of Eng.Assoc.Prof., 大学院・工学研究科, 助教授 (50091476)
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| Co-Investigator(Kenkyū-buntansha) |
YOKOTA Kazuaki Hokkaido Univ., Graduate School of Eng., Prof., 大学院・工学研究科, 教授 (30001217)
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| Project Period (FY) |
1995 – 1997
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| Project Status |
Completed (Fiscal Year 1997)
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| Budget Amount *help |
¥6,400,000 (Direct Cost: ¥6,400,000)
Fiscal Year 1997: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1996: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1995: ¥5,400,000 (Direct Cost: ¥5,400,000)
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| Keywords | Rh complex catalyst / Polyacetyelene / Stereoregurality / Oxgen permeable film / Oxygen permeable coefficient / Cast / Columnar / Pseudohexagonal / Rh錯体触媒 / 酸素富化膜 / 立体特異的 / 酸素透過係類 / キャスト / 擬ヘキサゴナル / ESR / ポリプロピオレート / ヘキサゴナル / シス体 |
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| Research Abstract |
It has been demonstrared that strereoregular polymerization monosubstituted acetylenes were successfully achieved using Rh complex catalysts in the presence of triethylamine or alchohol under fairly mild conditions and the resulting polyacetylenes were carefully characterized using lasr Raman, diffuse reflective UV,NMR,and electron spin resonance (ESR) methods. ^<1-2)> Consequently we found that the Rh complex is a preffered catalyst for formation of cis-transoid polyacetylenes even at room temperature. Acetylene esters bearing n-akllkyl group in the side chain were aslo stereoregularly polymerized to give the corresponding polyacetylene esters' using methanol as the polymerizaion solvent. ^<3)> The ester polymers were found to have a pseudohexagonal structure called columnar as self assembly useful for the oxygen permeable films. ^<4-5,13)> The polyacetylene esters were cast from chloroform and the oxygen permeability was estimated using a so-called GAS PERM,i.e., the separationcoefficient of the ratio, P_<O2>/P_<N2> was ca. alpha=3.4 comparable for other polmers bearing silicon moieties, suggesting that this polymer is promising new materials for oxygen permeable films. Further, the polyacetylenes prepared with Rh complex catalyst was found to be isomerized by compression even at room temperature in order to give the trans isomers involving a large amount of radicals as solitons. ^<4-6)>
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