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A development of photolysis system for NO_2 measurement on board the aircraft

Research Project

Project/Area Number 07554079
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field Space and upper atmospheric physics
Research InstitutionNagoya University

Principal Investigator

KOIKE Makoto  Nagoya Univ., Solar-Terr.Env.Lab., Research Associate, 太陽地球環境研究所, 助手 (00225343)

Co-Investigator(Kenkyū-buntansha) TAMARU Takashi  Institute of Aircraft Engineering, Head Scientist, 航空技術研究所, 研究室長
MURATA Isao  Tohoku Univ., Dep.of Science, Research Associate, 理学研究科, 助手
NISHINO Masanori  Nagoya Univ., Solar-Terr.Env.Lab., Research Associate, 太陽地球環境研究所, 講師 (70023679)
KONDO Yutaka  Nagoya Univ., Solar-Terr.Env.Lab., Professor, 太陽地球環境研究所, 教授 (20110752)
NAKAJIMA Hideaki  Nagoya Univ., Solar-Terr.Env.Lab., Research Associate, 太陽地球環境研究所, 助手 (20217722)
塩川 和夫  名古屋大学, 太陽地球環境研究所, 助手 (80226092)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1996: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsReactive nitrogen / Nitrogen dioxide / Nitric oxide / Photolysis converter / Aircraft measurement / Tropospheric ozone / 総反応性窒素酸化物
Research Abstract

NO_x (NO+NO_2) plays a critical role on the phtochemical ozone (03) production in the troposhere. In this study, a prototype system for NO_2 detection has been developed for a future application on the aircraft measurement.
The UV Photolysis system to convert NO_2 into NO is the key of the instrument, beause the NO detection system has been already developed. We have used a metal halogen lamp as a light source. We have also used a photolysis cell of which wall was coated with reflective aluminum to increase the photolysis rate in the cell. We have also developed a Teflon valve to control a pressure inside the photolysis cell. As a result, a conversion efficiency of about 50% was obtained with a residence time inside of the cell of 1-2 sec. A conversion efficiency can be higher when pressure inside the cell is kept higher, however other molecules such as N_2O_5 was found to also be photodissociated. In addition, Uv in the wavelength shorter than 320nm should be cut using optical filter to prevent the photodissociation of HNO_3. Based on these results, we plan to develop a NO_2 detection system which can be used on board the aircraft.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] M. Koike: "Aircraft measurements of total reactive nitrogen and ozone over the western Pacific in winter" Atmos. Environ.30. 1631-1640 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Koike: "Ratios of reactive nitrogen over the Pacific during PEM-West A." J. Geophys. Res.101. 1829-1851 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Koike: "Correlations of NO_y with O_3 over the Western Pacific during PEM-West B" Proceedings for Quadrennial Ozone Symposium in press. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y. Kondo: "Reactive nitrogen over the Pacific ocean during PEM-West A" J. Geophys. Res.101. 1809-1828 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Koike: "Reactive nitrogen and its correlation with O_3 and CO over the Pacific in winter and early spring" J. Geophys. Res. in press. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Koike, Y.Kondo, S.Kawakami, H.Nakajima, G.L.Gregory, G.W.Sachse, H.B.Singh, E.V.Browell, J.T.Merrill, and R.E.Newell: "Reactive nitrogen and its correlations with O_3 and CO over the Western Pacific during PEM-West B" J.Geophys.Res.(in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Koike, Y.Kondo, S.Kawakami, H.Nakajima, G.L.Gregory, G.W.Sachse, H.B.Singh, E.V.Browell, J.T.Merrill, and R.E.Newell: "Correlations of NO_y with O_3 and CO over the Western Pacific during PEM-West B" Proceedings for Quadrennial Ozone Symposium. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Koike, Y.Kondo, S.Kawakami, H.Nakajima, M.Ieda, M.Kanada, N.Toriyama, and H.Nakane: "Aircraft measurements of total reactive nitrogen and ozone over the western Pacific in winter" Atmos.Environ.30. 1631-1640 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Koike, Y.Kondo, S.Kawakami, H.B.Singh, H.Ziereis, and J.T.Merrill: "Ratios of reactive nitrogen over the Pacific during PEM-West A." J.Geophys.Res.101. 1829-1851 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kondo, H.Ziereis, M.Koike, S.Kawakami, G.L.Gregory, G.W.Sachse, H.B.Singh, D.D.Davis, and J.T.Merrill: "Reactive nitrogen over the Pacific ocean during PEM-West A" J.Geophys.Res.101. 1809-1828 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Koike: "Aircraft measurements of total reactive nitrogen and ozone over the western Pacific in winter" Atmos.Environ.30. 1631-1640 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Koike: "Ratios of reactive nitrogen over the Pacific during PEM-West A." J.Geophys.Res.101. 1829-1851 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Koike: "Correlations of NO_y with O_3 and CO over the Western Pacific during PEM-West B" Proceedings for Quadrennial Ozone Symposium. (in press). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kondo: "Reactive nitrogen over the Pacific ocean during PEM-West A" J.Geophys.Res.101. 1809-1828 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Koike: "Reactive nitrogen and its correlation with O_3 and CO over the Pacific in winter and early spring" J.Geophys.Res.(in press). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Koike,M.,: "Ratio of reactive nitrogen species over the Pacific during PEM-West A" J.Geophys.Res.101. 1829-1851 (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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