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Electro-Chemical Reduction of Nitrate in Underground Water and Regeration Waste Water of Ion-exchange resin

Research Project

Project/Area Number 07555173
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Civil and environmental engineering
Research InstitutionYamanashi University

Principal Investigator

NAKAMURA Fumio  Yamanashi University Facul.of Eng.Professor, 工学部, 教授 (60077203)

Co-Investigator(Kenkyū-buntansha) MIYAKE Uusaku  Orugano Co.Dept.Global Env.Head of dept., 地球環境部, 部長(研究職)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1997: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1996: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1995: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsNitrate reduction / Electrolysis / Regeneration waste / Reduction efficiency / 塩素イオンの再生利用 / 交換樹脂再生廃液
Research Abstract

Electro-chemical reduction of Nitrate in underground water and regeration waste water of Ion-exchange resin were investigated in this research.
Research results may be summarized as follows.
(1) Concentration of Cl^-, NO_3^-, SO_4^<2-> in regeration waste water of anion^- exchange resin (IRA-400) was in the order of g/l.
(2) Although the change in concentration of SO_4^<2->, CO_3^<2-> was not found, NO_3^- was reducted only in the camber of cathode, and produced NO_2^-, NH_4^+, N_2, NO,NH_3
(3) Cl^- was oxidized in the anode, and produced Cl_2 and HC10
(4) It was found that main part of gas prodused in cahode was H_2, and O_2 in anode
(5) It was found that reduction rate was proportional to the applied electric current, electrolysis time and electric power, however, it has reached to the maximum at around 5A,90 min and 50 Wh. Therefore, it was estimated that electriccurrent and electrolysis time should be set to 4-5A and 60 min from the viewpoint of reduction efficiency.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 中村 文雄、渡辺 潤一: "硝酸性窒素の電解還元における窒素の挙動" 第46回全国水道研究発表会講演概要集. 4-61. 198-199 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 風間、中村、坂本: "硝酸イオン選択性樹脂による硝酸性窒素汚染地下水の処理" '95年電気化学秋季大会、. 2L09. 253-253 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 和久 広丈, 中村 文雄: "硝酸性窒素の電解還元効率に及ぼす負荷電流、電力量の影響" 土木学会第5回年次学術講演会概要集(7部). VII-219. 436-437 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 中村、風間、坂本: "イオン交換樹脂による硝酸イオンの除去(第1報)" 水道協会雑誌、. 66(11). 15-23 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 風間、中村、坂本: "イオン交換樹脂による硝酸イオンの除去(第2報)" 水道協会雑誌、. 66(12). 9-19 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Nakamura, J.Watanabe: "Behavior of N in the cource of electrolysis of Nitrate" 46th annual conf.of JWWA. 4-6. 198-199 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Kazama, F.Nakamura Y.Sakamoto: "Treatment of underground water by Ntrate selective ion-exchage resin." '95 conf.of Electro-Chemistry. 2L09. 253 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Waku, F.Nakamura: "Effects of electric current and electric power on the reduction of nitrate" 52th annual conf.of JSCE. VII-219. 436-437 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Nakamura, F.Kazama Y.Sakamoto: "Removal of Nitrate-ion by ion-exchang resin (report 1)" Jour.of JWWA. 66 (11). 15-23 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] F.Kazama, F.Nakamura Y.Sakamoto: "Removal of Nitrate-ion by ion-exchang resin (report 1)" Jour.of JWWA. 66 (12). 9-19 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 和久広丈 中村文雄: "硝酸性窒素の電解還元効率に及ぼす負荷電流、電力量の影響" 土木学会第5回年次学術講演会概要集(7部). VII-219. 436-437 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 和久広丈 中村文雄: "硝酸性窒素の電解還元効率に及ぼす電極面積の影響" 土木学会第54回年次学術講演会. (発表予定). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 中村文雄 和久広丈: "硝酸性窒素の電解還元効率に及ぼす付加電流の影響" 全国水道研究発表大会. (予定). (1998)

    • Related Report
      1996 Annual Research Report
  • [Publications] 中村文雄: "電解還元効率に及ぼす硝酸性窒素濃度の影響" 全国水道研究発表大会. (予定). (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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