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Development of Monitoring System of Electrochemical Reaction by Using Surface Plasm on Resonance

Research Project

Project/Area Number 07555266
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 工業物理化学
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

UOSAKI Kohei  Hokkaido Univ., Graduate School of Science, Professor., 大学院・理学研究科, 教授 (20133697)

Co-Investigator(Kenkyū-buntansha) HENMI Akihide  Irumasofuto company, development project, Chief., 主任
YE Shen  Hokkaido Univ., Graduate School of Science, assitant., 大学院・理学研究科, 助手 (40250419)
KONDO Toshihiro  Hokkaido Univ., Graduate School of Science, assitant., 大学院・理学研究科, 助手 (70240629)
OHTANI Bunsho  Hokkaido Univ., Graduate School of Science, assistant professor., 大学院・理学研究科, 助教授 (80176924)
大澤 雅俊  北海道大学, 触媒化学研究センター, 教授 (00108466)
中林 誠一郎  埼玉大学, 理学部, 助教授 (70180346)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥13,900,000 (Direct Cost: ¥13,900,000)
Fiscal Year 1997: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1996: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1995: ¥9,100,000 (Direct Cost: ¥9,100,000)
Keywordssurface plasmon / Raman Spectroscopy / electrode reaction / self-assembled monolayr / surface structure / 電極表面班応 / 表面プラズモン
Research Abstract

This project was carried out to construct an electrode surface reaction monitoring system utilizing surface plasmon resonance. During the last 3 years, we have constructed 1."Surface Plasmon Rcsonance System" which can measure the thickness of monolayr on the electrode very accurately with relatively high time resolution and 2. "Plasmon Excited Raman Measuring System" which utilizes the enhancement of Raman Scattering by plasmon excitataion. These systems were applied to monitor the self-assembly process of alkanethiols in situ in real time.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] K.Uosaki: "Preparation of Highly Ordered Au(111) Phase on Polycrystalline Gold Substrate by Vacuum Deposition and Its Characterization by XRD,GISXRD, STM/AFM, and Electrochemical Measurement." J.Electroanal.Chem.99. 14117-14122 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "STM Investigation of the Self-Assembly Processof DEcanethiol on Au(111)" Denki Kagaku.65/6. 440-443 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Nakanishi: "Constrauction of Semiconductor Nanoparticle Layers on Gold by Self-Assembly Technique" Jpn.J.Appl.Phys.36/6B. 4053-4056 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "In situ, Real time monitoring of the self-assembly process of decanethiol on Au(111) in liquid phase. A scanning tunneling microscopy investigation" Langmuir. 13/20. 5218-5221 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Nakanishi: "Layer-by-Layer Self-assembly of Composite Films of CdS Nanoparticle and Alkanedithiol on Gold:an X-ray Photoelectron Spectroscopic Characterization" Chem.Phys.Lett.278. 233-237 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "In situ scanning tunneling microscopy observation of the self-assembly process of alkanethiols on gold(111) in solution" Langmuir. 14/4. 855-861 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Nakanishi: "Febrication and Characterization of CdS Nanoparticle Mono-and Multilayers on a Self-Assembled Monolayer of Alkanedithiols on Gold" J.Phys.Chem.B. 102/9. 1571-1577 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Uosaki: "Preparation of Highly Ordered Au (111) Phase on Polycrystalline Gold Substrate by Vacuum Deposition and Its Characterization by XRD,GISXRD,STM/AFM,and Electrochemical Measurement" J.Electroanal.Chem.99. 14117-14122 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "STM Investigation of the Self-Assembly Processof DEcanethiol on Au (111)" Denki Kagaku.65/6. 440-443 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Nakanishi: "Constrauction of Semiconductor Nanoparticle Layrs on Gold by Self-Assembly Technique" Jpn.J.Appl.Phys.36/6B. 4053-4056 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "In situ, Real time monitoring of the self-assembly process of decanethiol on Au (111) in liquid phase. A scanning tunneling microscopy investigation" Langmuir. 13/20. 5218-5221 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Nakanishi: "Layr-by-Layr Self-assembly of Composite Films of CdS Nanoparticle and Alkanedithiol on Gold : an X-ray Photoelectron Spectroscopic Characterization" Chem.Phys.Lett.278. 233-237 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "In situ scanning tunneling microscopy observation of the self-assembly process of alkanethiols on gold (111) in solution" Langmuir. 14-4. 855-861 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Nakanishi: "Febeication and Characterization of CdS Nanoparticle Mono-and Multilayrs on a Self-Assembled Monolayr of Alkanedithiols on Gold" J.Phys.Chem.B. 102/9. 1571-1577 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Yamada: "STMInyestigation of the Self-Assembly Process of Decanethiol on Au (111)" Denki Kagaku.65/6. 440-443 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Nakanishi: "Construction of Semiconductor Nanoparticle Layers on Gold by Self-Assembly Technique" Jpn.J.Appl.Phys.36/6B. 4053-4056 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] I.Yagi: "Reaction Pathway of Four Electron Oxidation of Formaldehyde on Platinum Electrode As Observed by In-Situ Optical Spectroscopy" Surf.Sci.386. 82-88 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Ye: "Redox Induced Orientation Change of aSelf-assembled Monolayer of 11-ferrocenyl-1-undecanethiol on a Gold Electrode Studied by in Situ FT-IRRAS" Langmuir.13/12. 3157-3161 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Sato: "Mass Transport Accompanied with Electron Transfer between the Gold Electrode Modified with 11-Ferrocenylundecanethiol Monol ayer and Redox Species in Solution" J.Electroanal.Chem.434. 117-121 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S. Nakabayasi: "Dissipation Structure of the Electrochemical Hydrodynamic Convection" J. Phys. Chem.100. 714-717 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I. Yagi: "In situ Optical Second Harmonic Generation Studies of Electrochemical Deposition of Tellurium on Polycrystalline Gold Electrodes" J. Electroanal. Chem.401. 95-101 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S. Nakabayashi: "Dissociative Adsorption Dynamics of Formaldehyde on a Platinum Electrode Surfaces ; One-Dimensional Domino?" Chem. Phys.205. 269-275 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I. Yagi: "In situ Optical Second Harmonic Generation Study of Electrochemical Oxidation of Formaldehyde, on a Polycrystalline Platinum Electrode" Chem. Lett. 7号. 529-530 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S. Nakabayashi: "Nonlinear Iron Electrochemical Osillator : Coupling and Photo Effects" J. Electrochem. Soc.143. 2258-2262 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T. Kondo: "Adsorption Behavior of Functionalized Ferrocenylalkane Thiols and Disulfide onto Au and ITO and Electrochemical Properties of Modified Electrodes: Effects of Acyl and Alkyl Groups Attachedto the Ferrocene Ring" J. Electronal. Chem.381. 203-209 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y. Sato: "Electrochemical and Electrogenerated Chemiluminescence Properties of Tris(2,2'-bipyridine)ruthenium(II)tridecanethiol Derivative on ITO and Gold Electrodes" J. Electronal. Chem.384. 57-66 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Uosaki: "Time Dependent Electroluminescence Spectra at n-type Porous Silicon/Electlyte Solution Interface Induced by Hole Injection" Chem. Lett.667-668 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Uosaki: "Preparation of Highly Ordered Au(111)Phase on Polycrystalline Gold Substrate by Vacuum Deposition and Its Characterization by XRD, GISXRD, STM/AFM, and Electrochemical Measurement" J. Phys. Chem.99. 14117-14122 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I. Yagi: "In situ Optical Second Harmonic Generation Studies of Electrochemical Deposition of Tellurium on Polycrystalline Gold Electrodes" J. Electronal. Chem.(in press). (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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