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Development of Novel Light Emitting Device Consisting of C60 Polymer

Research Project

Project/Area Number 07555296
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field 高分子構造・物性(含繊維)
Research InstitutionTOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY

Principal Investigator

MIYATA Seizo  TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY,BASE,Professor, 大学院・生物システム応用科学研究科, 教授 (90015066)

Co-Investigator(Kenkyū-buntansha) SHIRASAKI Tomoyuki  Casio Computer Co.Ltd., Ohme Res.Lab., Senior Researcher, 青梅事業所, 主任研究員
山田 裕康  カシオ計算機(株), 青梅事業所, 主任研究員
WATANABE Toshiyuki  TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY,BASE,Assist.Prof., 工学部, 助手 (10210923)
YAMADA Yasuhiro  Casio Computer Co.Ltd., Ohme Res.Lab., Senior Researcher
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥13,100,000 (Direct Cost: ¥13,100,000)
Fiscal Year 1996: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 1995: ¥9,100,000 (Direct Cost: ¥9,100,000)
KeywordsElectroluminescence / Fullerene / C60 / Polymer / Electron transport materials / Co-evaporation
Research Abstract

Organic materials have been expected to be applicable for practical electroluminescent (EL) devices because of their high fluorescence efficiency and semiconducting properties. One of problems for EL devices is short life time. In order to improve this problem we develop novel C60 polymer and co-evaporating technique. For the hole transport layr (HTL), poly (N-vinyl carbazole) PVCz was used. The coumarine 6 was doped into PVCz as an emitting dye. The cell structure was Mg/Tris (8-quinolinolate) aluminum (III) complex (Alq_3) /C60 polymer and PVCz/ITO.The all polymeric layrs were prepared by spin coating. C60 polymer works as a good electron transport layr. In order to improve the metal organic interface, the co-evaporating technique was applied to the preparation of cathode electrode. The 3 nm thick magnesium/Alq_3 composite layr (20 : 1 of weight ratio) was prepared on a C60 polymer. The EL emission threshold of novel EL device is slightly smaller than that of conventional multi-layr EL devices. Brightness and color were uniform over the whole emitting area, and no discharge was found till bias voltage of 12 V.The current and EL intensity of novel EL device is 1.4 and 2 times larger than that of conventional multi-layr EL devices, respectively. The novel EL device shows the highest brightness 25,000 cd/m^2 at the condition of 1000 mA/cm^2. The decay of the emission intensity was also improved by the introduction of co-evaporating metal-organic layr.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] X.T.TaO: "Phase-matched Second-Harmonic Generation in Poled Polymers using Positive Birefringence" J.Opt.Soc.Am.B. 9. 1581-1585 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.S.Nalwa: "2-D Charge-transfer Molecules for Second-order NLO : off-diagonal Orientation" Adv.Mater.7. 754-758 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Abe.: "Nonlinear Optical Properties of Poly(P-phenylene)Derivatives" Nonlinear Opt.15. 259-262 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.T.Tao: "Synthesis and Characterization of Poly (aryl ether Chalcone)S for Second Harmonic Generation" Chem.Mater.8. 1326-1332 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 宮田清蔵: "21世紀に挑戦する高分子材料-光機能性材料研究の最近の動向-" 合成樹脂. 42. 9-14 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Watanabe: "Novel Fabrication Techniques of Electro-luminescent and Photoluminescent Devices" Organic Electroluminescent Devices. 1. 459-482 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.T.Tao: "Metal Complex Polymer for Second Harmonic Generation and Electro luminescent Applications" Appl.Phys.Lett.,. (in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.T.Tao, T.Watanabe, D.C.Zou, H.Ukuda, S.Miyata: "Phase-matched Second-Harmonic Generation in Poled Polymers using Positive Birefringence" J.Opt.Soc.Am.B. 9. 1581-1585 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.S.Nalwa, T.Watanabe, S.Miyata: "2-D Charge-transfer Molecules for Second-order NLO : Off-diagonal Orientation" Adv.Mater. 7. 754-758 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Abe, Y.Kiyohara, M.Rikukawa, K.Sanui, N.Ogata, T.Watanabe, S.Miyata: "Nonlinear Optical Properties of Poly (p-phenylene) Derivatives" Nonlinear Optics. 15. 259-262 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.T.Tao, T.Watanabe, K.Kono, T.Deguchi, M.Nakayama and S.Miyata: "Synthesis and Characterization of Poly (aryl ether chalcone) s for Second Harmonic Generation" Chem.Mater. 8. 1326-1332 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.T.Tao, H.Suzuki, T.Watanabe, S.H.Lee, S.Miyata, H.Sasabe: "Metal Complex Polymer for Second Harmonic Generation and Electroluminescent Applications" Appl.Phys.Lett.(in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Watanabe, H.S.Nalwa, S.Miyata: Organic Electroluminescent Devices, eds.H.S.Nalwa, S.Miyata, " Novel Fabrication Techniques of Electroluminescent and Photoluminescent Devices. Gordon and Breach Publishers, 459-482 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.T.TaO: "Synthesis and Characterization of Poly (aril ether chalcone)s for Second Harmenic Generation" Chem.Mater.8. 1236-1332 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 宮田清蔵: "21世紀に挑戦する高分子材料-光機能性材料研究の最近の動向-" 合成樹脂. 42. 9-14 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Watanabe: "Novel Fabrication Techniques of Electroluminescent and Photoluminescent Devices" Organic Electroluminescent Devices. 1. 459-482 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] X.T.TaO: "Metal Complex Polymer for Second Harmonic Generation and Electroluminescent Applications" Appl.Phys. Lett.(in press). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Abe,M.Rikukawa,K.Sanui,T.Watanabe and S.Miyata: "Synthesis and Nonlinear Optical Properties of Poly(γ-Methyl L-Glutamate)s having Nitrostilbene Dyes as Side Chains(I)" Nonlinear Optics. 14. 91-96 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Talukder,S.Fujita,T.Watanabe and S.Miyata: "Study on Conformations of Polymeric Langmuir-Blodgett Films Prepared by using Kuhn Type and Moving-Wall Type Deposition Systems" Nonlinear Optics. 15. 77-80 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] X.T.Tao,T.Watanabe,H.Ukuda and S.Miyata: "Phase-Matched Second-Harmonic Generation in Poled Polymers by the use of Birefringence" J.Opt.Soc.Am.12. 1581-1585 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.S.Nalwa,T.Watanabe and S.Miyata: "2-D Charge-Transfer Molecules for Second-Order NLO:Off-Diagonal Orientation" Adv.Mater.7. 754-758 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] X.T.Tao,T.Watanabe,H.Sato and S.Miyata: "Polyurea with Large Positive Birefringence for Second Harmonic Generation" Macromolecules. 28. 2673-2643 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Furukawa,K.Ishikawa,T.Watanabe,S.Miyata,J.Watanabe: "Highly-SHG-Active Nematic Liquid Crystal Formed From Aromatic Polyester" Nonlinear Optics. 15. 167-170 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Watanabe,S.Miyata and H.S.Nalwa: "Ferroelectric Polymers" Nonlinear Optical Properties of Ferroelectric Polymers, (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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