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Fabrication of PZT thin films using digital-MOCVD method and its application for electronic devices

Research Project

Project/Area Number 07555418
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 電子デバイス・機器工学
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

KUROIWA Koichi  Faculty of Tech., Tokyo University of Agriculture and Technology, Prof., 工学部, 教授 (20170102)

Co-Investigator(Kenkyū-buntansha) KOMATSU Shu-ichi  Toshiba corporation, Researcher, 材料デバイス研究所, 研究主幹
TARUI Yasuo  WASEDA University, Science & Engineering, Prof., 大学院・理工学研究科, 教授 (10143629)
UENO Tomo  Faculty of Tech., Tokyo University of Agriculture and Technology, Lecturer, 工学部, 講師 (90223487)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1997: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1996: ¥2,300,000 (Direct Cost: ¥2,300,000)
KeywordsFerroelectric films / non-volatile memory / PZT / perovskite structure / digital-MOCVD / 強誘電体薄膜 / ペロブスカイト
Research Abstract

Recently, ferroelectric thin films such as Lead based perovskite structure have been actively studied as one of the promising materials for capacitor dielectric films in dynamic random-access memories (DRAMs) and ferroelectric random-access memories (FeRAMs), and for gate insulators in ferroelectric-gate FETs with metal-ferroelectric-semiconductor (MFS) gate structure. In particular, MFS-FET is expected to be one of the leading candidates for the future memory devices because of its non-volatility, high switching speed, high integration without storage capacitors, and so on. However, there have been few satisfactory results regarding fabrication of ferroelectric thin films directly on Si substrates, because there have been difficulties in the formation of ferroelectric/Si interfaces due to interdiffusions and lattice mismatches between them. ln this research. Pb(Zr, Ti)O_3 (PZT)/MgO/Si(0O1) stacked structure, which is one of the principle components of ferroelectric-gate FETs, has been fabricated and characterized. Using both the theta-2theta and the 2-dimensional X-ray diffraction (XRD) method, the fully epitaxial relationship of PZT[100]//MgO[100]//Si[110] has been confirmed in the PZT(001)/MgO(001)/Si(001) stacked structure fabricated with the maximum processing temperature of 480゚C.The fully epitaxial relationship causes no affection on the electrical properties of PZT and Si. Especially for MgO/Si interfaces, itwould make possible to control the surface potential of Si by the gate voltages in ferroelectric-gate FETs.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] Tomo Ueno: "Epitaxial growth of ferroelectric thin films on Si substrates using MgO intermediate layer." Proc. of Korea-Japan joint Workshop of the Deposition and Device Applications of Ferroelectric Thin Films, Taejon, Korea,. 25-30 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 森岡あゆ香: "原子状酸素の高効率生成とSi(100)基板の低温酸化への応用" 応用物理学会薄膜表面分科会特別研究会. 189-192 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junji Senzaki: "Characterization of Pb(Zr,Ti)03 thin films on Si substrates using MgO intermediate layer for metal/ferroelectric/insulator/semiconductor field effect transistor devices." Japanese Journal of Applied Physics. 37. 5150-5153 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junji Senzaki: "Fabrication and characterization of epitaxial MgO thin films on Si substrates." Electroceramics in Japan II. in press.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junji Senzaki: "Electrical prorperties of fully epitaxial PZT/MgO/Si stacked structures for nonvolatile future memory devices." Proc.of Material Research Society. in press.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tomo Ueno: "Epitaxial growth of ferroelectric thin films on Si substrates using MgO intermediate layer." Proc.Of Korea-Japan Joint Workshop of the Deposition and Device Applications of Ferroelectric Thin Films, Taejon, Korea. 25-30 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Ayuka Morioka: "Highly efficient generation of atomic oxygen and its application to low temperature oxidation of Si (100) substrate." The special meeting of the Japan Society of Applied Physics. 189-192 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junji Senzaki: "Characterization of Pb (Zr, Ti) O3 thin films on Si substrates using MgO intermediate layer for metal/ferroelectric/insulator/semiconductor field effect transistor devices." Japanese Journal of Applied Physics. 37. 5150-5153 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junji Senzaki: "Fabrication and characterization of epitaxial MgO thin films on Si substrates." Electroceramics in Japan. II (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junji Senzaki: "Electrical prorperties of fully epitaxial PZT/MgO/Si stacked structures for nonvolatile future memory devices." Proc.of Material Research Society. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tomo Ueno: "Epitaxial growth of ferroelectric thin films on Si substrates using MgO intermediate layer." Proc.of Korea-Japan Joint Workshop of the Deposition and Device Applications of Ferroelectric Thin Films, Taejon,Korea,. 25-30 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 森岡あゆ香: "原子状酸素の高効率生成とSi(100)基板の低温酸化への応用" 応用物理学会薄膜表面分科会特別研究会. 189-192 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Junji Senzaki: "Fabrication of c-axis oriented Pb(Zr,Ti)O_3 thin films on Si(100) substrates using MgO intermediate layer" Japanese Journal of Applied Physics. 35. 4195-4198 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 先崎純寿: "MgO/Si基板上へのPZT薄膜の作製" 第42回応用物理学関係連合講演会講演予稿集. 2. 487 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 先崎純寿: "MgO/Si基板上へのPZT薄膜の作製(2)" 第56回応用物理学会学術講演会講演予稿集. 2. 399 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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