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Development and Pressure Sensitive Adhesive Properties of Gradient Structure Found in Acrylate Adhesive Polymer/Fluoro-copolymer Blends

Research Project

Project/Area Number 07555486
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section試験
Research Field Composite materials/Physical properties
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

AKIYAMA Saburo  Tokyo University of Agriculture and Technology, Faculty of Technology, Professor, 工学部, 教授 (80015049)

Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1996: ¥400,000 (Direct Cost: ¥400,000)
KeywordsBlends / Gradient Structure / Pressure Sensitive Adhesive / Surface Segregation / Morphology / Rate of Solvent Evaporation / Surface Temsion / Silica / 相分離速度 / XPS / FTIR / 相溶性
Research Abstract

In the acrylate adhesive polymer/fluoro-copolymer blends having 20-30 mum thick, surface segregation or gradient structure was prepared by coating from THF solution. The gradient structure found in the immiscible acrylate polymer/fluoro-copolymer blends was confirmed by FT-IR,XPS,and electron microscope. It was judged that the from of gradient structure was strongly influenced by surface tension, miscibility, and rate of solvent evaporation. Furthermore, it was pointed out that the blends forming gradient structure could be utilized as a new type pressure sensitive adhesive tape without backing, Finally, Isummarized the sectional morphology of gradient structure was controlled by various factors, such as blend ratio, annealing, and adding micrograin silica.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (43 results)

All Other

All Publications (43 results)

  • [Publications] 秋山三郎: "廃棄物とアロイ化,相溶化技術" 工業材料. 44. 64-69 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 金容薫,秋山三郎,松田篤: "無水マレイン酸-アリル系相溶化剤によるポリカーボ-ト(PC)/ナイロンアロイに生じる化学反応と相構造" 高分子論文集. 53. 169-175 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 宮古強臣,秋山三郎,張鵬鳴: "ポリブタジエン(PBD)/α-およびβ-ピネンブレンドの相溶性と粘着性" 高分子論文集. 52. 434-439 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 秋山三郎,宮古強臣: "ポリブタジエン(PBD)ゴム/粘着付与剤ピネン系粘着剤の相溶化現象と粘着物性" 日本接着学会誌. 31. 390-397 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久,秋山三郎,〓村知之: "X線光電子分光法によるポリアクリル酸エチル/ポリ(フッ化ビニリデン-co-ヘキサフルオロアセトン)ブレンドの表面解析" 日本接着学会誌. 31. 152-157 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kano,S.Akiyama,T.Kasemura,and S.Kobayashi: "Depth profiling of Acrylate copolymer/fluoro-copolymer immiscible blends" Polym.J.27. 339-346 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kano,S.Akiyama,H.Sano,and H.Yui: "The gradient domain morphology of binary Polyacrylate adhesive/fluoro-copolymer blend film" J.Electron Microsc.44. 344-350 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kano,S.Akiyama,and T.Kasemura: "Surface segregation and miscibility in blends of poly(ethyl acrylate)with poly(vinylidene fluoride-co-heyafluoro acetone)" Int.J.Adhesion and Adhesives. 15. 219-224 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久,秋山三郎,小林茂彦,横山達: "位相変調PAS-FTIR法によるアクリルコポリマー/フッ素コポリマーブレンドのデプスプロファイリング" 日本接着学会誌. 32. 1-5 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kano,S.Akiyama,and Y.Fujita: "Contact Angle of organic liquids on poly(butylacrylate)/poly(vinylidene fluoride-co-hexafluoro acetone)blends" Polym.Networks Blends. 6. 53-59 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久,秋山三郎: "偏析現象・傾斜構造を利用した新しい粘着剤" 新素材. 5No5. 47-51 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久,秋山三郎: "夢の粘着製品・基材のいらない粘着テープ" コンバーテック. 23No6. 14-17 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久,秋山三郎: "赤外分光法によるポリマーアロイの表面・界面分析" 機能材料. 15No11. 33-44 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久,秋山三郎: "表面分析法によるポリマーアロイの表面偏析の解析" 高分子加工. 44. 120-128 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 加納義久: "アクリルコポリマー/フッ素コポリマーブレンドのモルフォロジー" 日本接着学会誌. 32・5. 164-170 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kano: "Estimation of surface tension and surface segregation of Poly (ethyl acrylate) /Poly (vinylidene fluoride-co-hexafluoro acetone) blends" Polymer. 37・20. 4497-4503 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kano: "Surface dynamics of Poly (butyl acrylate) /Poly (vinylidene fluoride-co-hexafluoro acetone) blends by dynamic contact angle" Polym.Networks Blends. 6・4. 153-159 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Akiyama: "Fluoro-acrylate adhesive blends (surface segregation behavior)" Polymeric Materials Encyclopedia. 4・F-G. 2484-2489 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 秋山三郎: "粘着物性解析の最近の動向" 日本接着学会誌. 32・4. 144-151 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 加納義久: "アクリル系粘着剤/フッ素樹脂ブレンドでの表面偏析・傾斜構造とその解析(II)" 接着. 40・7. 298-304 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 加納義久: "アクリル系粘着剤/フッ素樹脂ブレンドでの表面偏析・傾斜構造とその解析(I)" 接着. 40・6. 263-269 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kano: "Controlling gradient domain morphology in blends of acrylate copolymer/fluoro-copolymer by adding micrograin silica" Polym.J.29・2. 158-164 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 加納義久: "粘・接着剤の複合化による機能発現" 日本接着学会誌. 33・1. 2-8 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 秋山三郎: "傾斜構造はなぜ出現するか 高分子粘着フィルムに発現する傾斜構造の実証と解釈" 科学と工業. 71・2. 44-50 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kano: "Poly (butyl acrylate) /Poly (vinylidene fluoride-co-hexafluoro acetone) Blends as Pressure-Sensitive Adhesives" J.Appl.Polym.Sci.63. 307-313 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 秋山三郎: "廃棄物とアロイ化,相溶化技術" 工業材料. 44. 64-69 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 金容薫: "無水マレイン酸-アリル系相溶化剤によるポリカーボネート(PC)/ナイロンアロイに生じる化学反応と相構造" 高分子論文集. 53. 169-175 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 宮古強臣: "ポリブタジエン(PBD)/α-およびβ-ピネンブレンドの相溶性と粘着性" 高分子論文集. 52. 434-439 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 秋山三郎: "ポリブタジエン(PBD)ゴム/粘着付与剤ピネン系粘着剤の相溶化現象と粘着物性" 日本接着学会誌. 31. 390-397 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "X線光電子分光によるポリアクリル酸エチル/ポリ(フッイヒビニリデン-co-ヘキサフルオロアセトン)ブレンドの表面解析" 日本接着学会誌. 31. 152-157 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kano: "Depth profiling of acrylate copolymer/fluoro-copolymer immiscible blends" Polym.J.27. 339-346 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kano: "The gradient domain morphology of binary polyacrylate adhesive/fluoro-copolymer blend film" J,Electron Microsc.44. 344-350 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kano: "Surface Segregation and miscibility in blends of poly(ethyl acrylate)with poly(vinylidene fluoride-)co-hexafluoro acetone)" Int.J.Adhesion and Adhesives. 15. 219-224 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "位相変調PAS-FTIR法によるアクリルコポリマー1フッ素コポリマーブレンドのデプスプロファイリング" 日本接着学会誌. 32. 1-5 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kano: "Contact angle of organic liquids on poly(butyl acrylate)/Poly(vinylidene fluoride-co-hexafluoro acetone)blends" Polym.Networks Blends. 6. 53-59 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "偏析現象・傾斜構造を利用した新しい粘着剤" 新素材. 5.No.5. 47-51 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "夢の粘着製品・基材のいらない粘着テープ" コンバーテック. 23,No.6. 14-17 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "赤外分光法によるポリマーアロイの表面・界面分析" 機能材料. 15No11. 33-44 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 秋山三郎: "粘着物性解析の最近の動向" 日本接着学会誌. (印刷中).

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kano: "Study of interface segregation behavior in acrylate copolymer/fluoro-copolymer blends using FTIR phase-modulated photoacoustic spectroscopy" J.Adhesion. (in press).

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kano: "Estimation of surface tension and surface segregation of poly(ethyl acrylate)/poly(vinylidone fluoride-co-hexafluoro acetone)blends" Polymer. (in press).

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "アクリル系粘着剤/フッ素樹脂ブレンドでの表面偏析・傾斜構造とその解析 I.傾斜構造を利用した新しい粘着テープ" 接着. (印刷中).

    • Related Report
      1995 Annual Research Report
  • [Publications] 加納義久: "アクリル系粘着剤/フッ素樹脂ブレンドでの表面偏析・傾斜構造とその解析 II.相溶ブレンドに発現する表面偏析とその解析" 接着. (印刷中).

    • Related Report
      1995 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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