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Enhancement of Critical Current Density of Hg-Based High Tc Superconductors and their application

Research Project

Project/Area Number 07555656
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field Structural/Functional materials
Research InstitutionThe University of Tokyo

Principal Investigator

KISHIO Kohji  The University of Tokyo, Graduate School of Engineering, Professor, 大学院・工学系研究科, 教授 (50143392)

Co-Investigator(Kenkyū-buntansha) SATO Ken-ichi  Sumitomo Electric Industries, LTD,Osaka Research Laboratories, 大阪研究所, 研究部長
SHIMOYAMA Jun-ich  The University of Tokyo, Graduate School of Engineering, Research Associate, 大学院・工学系研究科, 助手 (20251366)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1996: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsHigh T_c Superconductor / Hg-based / Critical Current Density / Irreversibility Field / 高温超電導材料 / 酸化物超伝導体 / 水銀系酸化物超伝導体 / 超電導線材 / 安定化 / 化学ド-ピング / 磁束ピニング / 水銀系超伝導体 / 材料化 / 超伝導線材 / 磁束ピニング特性 / シース・テープ材 / プロセッシング
Research Abstract

It has been over ten years since the discovery of high T_c superconductors. And as a result of numerous researches and developments, some practical and commercial use of them have begun, i.e., coils and power lead cables for the liquid-helium-free superconducting magnets. Superconducting oxide materials developed so far, such as Bi-based tapes, however, don't have good pinning properties and high critical current density at high temperature and under high field. Therefore, their applications for high current and field are considered to be difficult, and developments of wire materials based on different systems are crucial.
Hg-based oxide superconductor has the record high T_c,135K,but is difficult to make by the traditional synthesis method and considered to be chemically unstable, So we have concentrated our research efforts to intensify their stability by chemical modifications and increase their critical current density for practical use. Also, we have tried to enhance the flux pinning properties and the critical current density of the Bi-based superconductors.
As a result, we have clarified that Re substitution for Hg site increases the chemical stability, and at the same time, the irreversibility field is increased, too. Also, in the course of collaborations with Kyoto University group, we have found the remarkable improvement of the flux pinning properties of the Bi-based superconductors by Pb heavy doping.
We are still continuing our researches to develop the next-generation wire materials based mainly on the Hg- and Bi-systems, in which we have succeeded in chemical stabilization and pinning property enhancement in this research project, and to establish the processing procedures of the long wires for various applications at liquid nitrogen temperature.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] A.Yoshikawa: "Crystal growth of (Hg,Re) Ba_2 Can_<-1> Cun Og." Chinese Journal of Low Temp.Phys.19. 32-35 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Komori: "Jhermoelectric Power of Re-doped Hg 1223 Compounds" Physica C. 282-287. 1269-1270 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] I.Chong: "High Critical Current Deusity in the Hearily Pb-Doped Bi_2 Sr_2 Ca Cu_2 O_8tδ Superconductor." Science. 276. 770-773 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Shimoyama: "Strong Flux Pinning up to Liquid Nitrogen Temperature Discorered in Heavily Pb-Doped and Oxygen Controlled Bi2212 Single Crystals" Physica C. 281. 69-75 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kishio: "Extremely Large Enhancement of Flux Pinning Strength in the Heavily Pb-Doped Bi2212 Single Crystals." Proceedings of ISTEC Workshop'97. 105-107 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Yoshikawa, H.Sumioka, J.Shimoyama, J.Akimoto, H.Horiuchi, Y.Oosawa, K.Kitazawa and K.Kishio.: ""Crystal growth of (Hg, Re) Ba_2Ca_<(n-1)>Cu_nO_y"" Chinese Journal of Low.Temp.Phys.19. 32-35 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Komori, H.Sumioka, A.Yoshikawa, J.Shimoyama, H.Ikuta and K.Kishio.: ""Thermoelectric Power of Re-doped Hg1223 Compounds."" Physica C. 282-287. 1269-1270 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] I.Chong, Z.Hiroi, M.Izumi, J.Shimoyama, Y.Nakayama, K.Kishio, T.Terashima, Y.Bando and M.Takano.: ""High Critical Current Density in the Heavily Pb-Doped Bi_2Sr_2CaCu_2O_<8+delta> Superconductor : Generation of Novel Pinning Centers."" Science. 276. 770-773 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] J.Shimoyama, Y.Nakayama, K.Kitazawa, K.Kishio, Z.Hiroi, I.Chong and M.Takano.: ""Strong Flux Pinning up to Liquid Nitrogen Temperature Discovered in Heavily Pb-Doped and Oxygen Controlled Bi2212 Single Crystals."" Physica C. 281. 69-75 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kishio, J.Shimoyama, Y.Nakayama, K.Kitazawa, Z.Hiroi, I.Chong and M.Takano.: ""Extremely Large Enhancement of Flux Pinning Strenght in the Heavily Pb-Doped Bi2212 Single Crystals."" Proc.of ISTEC Workshop'97. 105-107 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kishio: "Chemical Stabilization and Fux Pinning in Hg-Based Superconductors" Advances in Superconductivity. VIII. 279-284 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] O.Chmaissem: "Crystal Structures of Hg-Sr-Ca-Cu-O Superconductors with Enhanced Flux Pinning:(Hg_<1-x>Re_x)Sr_2Ca_<n-1>Cu_nO_<n+2+δ>" Physical Review. B53. 14647-14655 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kishio: "Chemical Doping and Improved Flux Pinning in Hg-based Superconductors" J.Low Temp.Phys.105. 1359-1365 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J.L.Tallon: "A New Approach to the Design of High-Tc Superconductors:Metallized Interlayers" J.Low Temp.Phys.105. 1379-1384 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 下山淳一: "複合材料としての高温超伝導実用材料" セラミックス. 31. 223-228 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 岸尾光二: "銅酸化物超伝導体の研究展開-物質と化学の立場から-" 応用物理. 66(印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kishio: "Coherence in Superconductors" World Scientific Publishing Company, 442 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Kishio: "Critical Currents in Superconductors" World Scientific Publishing Company, 515 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J. Shimoyama: "Chemica Stabilization and Irreversibe Magnetic Behavior of HgM_2Ca_<n-1>Cu_nO_y with M=Sr(Ba) and n=1 to 3" Advances in Superconductivity. VII. 287-290 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Yamaura: "High Pressure Synthesis and Superconductivity of a Ba-free Mercury-Based Superconductor(Hg_<0.75>Re_<0.25>)Sr_2Ca_2Cu_3O_y" Physica C. C246. 351-356 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Z. Hiroi: "Microscopic Segregation in Intergrowth Layer of (Hg,Re)Ba_2Ca_<n-1>Cu_nO_y" Physica C. 印刷中. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Kishio: "Chemical Stabilization and Fux Pinning in Hg-Based Superconductors" Advances in Superconductivity. 印刷中. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 岸尾光二: "酸化物高温超伝導体発見からの10年:異方性と磁束ピンニングの化学的制御" まてりあ. 34. 1368-1373 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Kishio: "Coherence in Superconductors" World Scientific Publishing Company, 300 (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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