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Preparation and evaluation of novel transmitting conducting oxide thin films for electron beam lithography

Research Project

Project/Area Number 07555668
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field 無機工業化学
Research InstitutionOkazaki National Research Institutes

Principal Investigator

HOSONO Hideo  Okazaki National Resarch Institutes Associate professor of Institute for Molecular Science, 分子科学研究所, 助教授 (30157028)

Co-Investigator(Kenkyū-buntansha) YAMAGATA Shigeru  Group Leader of Sin-etsu Ouartz Glass Ltd., 技術研究所, 室長
HISHITA Shun-ichi  Senior Researcher of National Research Institute for Inorganic Materials, 無機材質研究所, 主任研究官
UEDA Naoyuki  Okazaki National Resarch Institutes, Research Assocuate of Institute for Molecul, 分子科学研究所, 助手 (00261123)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1996: ¥2,000,000 (Direct Cost: ¥2,000,000)
Keywordstransparent conductor / oxides / conductors / wide gap oxides / thin films / 薄膜 / ワイドギャップ半導体
Research Abstract

The purpose of the present project was to prepare novel transpatrent conducting oxide thin films for electron beam lithography and to evaluate their optical transport properties.
The primary results obtained are summarized as follows :
(1) Highly electriconducting beta-Ga_2O_3 single crystal with the band gap of 4.8eV was sucessfully prepared by floating zone technique under a controlled atmosphere. Anisotropy of conductivity and optical band gap was reasonablly explained by atomic arrangement. The maximum conductivity at 300 K was 40 Scm^<-1> along b-axis.
(2) Rf-sputtered thin films of MgIn_2O_4 with spinel type structure could be converted from insulating into highly conducting by doping of carrier electrons utilizing ion implantation of Li+or H^+. Efficiency of carrier generation was -20% in as-implanted state but could be increased to -80% by appropriate post annealing heat treatment of the implanted specimens.
(3) Transparent conducting amorphous oxides were found. DC conductivity of amorphous thin films of CdO-GeO<@D22@>D2 was drastically increased from 10<@D1-9@>D1 to 10<@D12@>D1 Scm<@D1-1@>D1 without accompanying a significant decrease in visible transmission at 300 K by implanting H<@D1(]SY.+-。[)@>D1 or Li+ to a fluence of 2 x10<@D116@>D1 cm<@D1-2@>D1 at 70 keV.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] H・Hosono et al.: "conversion of insulating thin films of MgIn_2O_4 into transparent conductors by ion implantation" Nucl.Instr.Meth.B. 106. 517-521 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H・Hosono et al.: "Amorphous transparent electroconductor 2CdO・GeO_2" Applied physics Letters. 67. 2663-2665 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H・Hosono et al.: "Novel oxide amorphous semiconductors : transparent conducting amorphous oxides" J.Non-Cryst Sol.203. 334-344 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N・Ueda et al.: "Novel transparent semiconductor : MgIn_2O_4" Solid State Phenomena. 51-52. 317-322 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H・Hosono et al.: "Fast Proton Conducting Glasses" J.Applied Physics. 81. 1296-1301 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N・Ueda et al.: "Synthesis and control of UV-transmitting β-Ga_2O_3 single crystel" Applied Physics Letters. (発表予定). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hosono, H.Unno, H.Kawazoe, N.Matsunami and H.Tanoue: "Conversion of insulating thin films of MaIn_2O_4 into transparent conductors by ion implantation" Nucl.Instr.Mch.B106. 51 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hosono, N.Kikuchi, N.Ueda, H.Kawazoe and K.Shimidzu: "Amorphous transparent electroconductor 2CdO・GeO_2 : Conversion of amorphous insulating vadmium germanate by ion implantation." Appl.Phys.Lett.67. 2663 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Ueda, H.Hosono and H.Kawazoe: "Novel transparent Semiconductor : MgIn_2O_4" Solid State Phenomena. 5. 317 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hosono, M.Yasukawa and H.Kawazoe: "Novel oxide amorphous semiconductors : transparent conducting amorphous oxides" J.Non-cryst.Sol.203. 334 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Kikuchi, H.Hosono, H.Kawazoe, K.Oyoshi and S.Hishita: "Transparent, conducting, amorphous oxides : effect of chemical composition on electrical and optical propertries of cadmium germanates" J.Amer.Ceram.Soc.80. 22 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Kikuchi, N.Ueda, H.Hosono, H.Kawazoe, and H.Tanoue: "High efficiency-carrier-generation in Li^+-implanted MgIn_2O_4 thin films" J.Ceram.Soc.Jpn.105. 275 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Ueda, H.Hosono, R.Waseda and H.Kawazoe: "Synthesis and control of conductivity of ultra-violet transmitting beta-Ga_2O_3 single crystal" Applied Physics Letters. (accepted for publication.).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hosono et al.: "Conversion of insulating thin films of MgIn_2O_4 into transparent conductors by ion implantation" Nucl.Instr.Meth.B. 106. 517-521 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Hosono et al.: "Amorphous transparent electroconductor 2CdO・GeO_2" Applied Physics Letters. 67. 2663-2665 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Hosono et al.: "Novel oxide amorphous semiconductors : transparent conducting amorphous oxides" J.Non-Cryst.Sol.203. 334-344 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N.Ueda,H.Hosono et al.: "Novel transparent Semiconductor : MgIn_2O_4" Solid state phenomena. 51-52. 317-322 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Hosono et al.: "Fast Proton Conducting Glasses" J.Applied Physics. 81. 1296-1301 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] N.Ueda,H.Hosono et al.: "Synthesis and control of UV-transmitting β-Ga_2O_3 single crystal" Applied Physics Letters. (発表予定). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Hosono: "Amorphous transpatent electrconductor 2CdO・GeO_2" Applied Physics Letters. 67. 2663-2665 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Hosono: "Conversion of insalating thin films of MgIn_2O_4 into transparent Cgnductors by ion implantation" Naclear Instruments and Methods. B106. 517-521 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Hosono: "New amorphous semiconductor:2CdO・PbO^x" Applied Physics Letters. 68. 661-663 (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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