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Research for the formation and stability of CO_2 hydrate in deep sea

Research Project

Project/Area Number 07640581
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Meteorology/Physical oceanography/Hydrology
Research InstitutionKumamoto Institute of Technology

Principal Investigator

KOBAYASHI Yoshihiro  Kumamoto Institute of Technology, Dept.of Technology, Professor, 工学部, 教授 (00234857)

Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1997: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1996: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1995: ¥900,000 (Direct Cost: ¥900,000)
KeywordsGlobal warming / CO_2 hydrate / CO_2 diffusion / CO_2 injection into sea / CO_2 diffusion coefft / CO_2 / H_2O interface / Density of CO_2 solution / Power generation by CO_2 liquid / CO_2深海投入 / 水和物 / 深海投入
Research Abstract

Theoretical and experimental studies have been carried out on the physical behavior of CO_2 under the high pressure and low temperature corresponding to the deep ocean of 3000m depth level focusing on the liquid CO_2. Simultaneously the studies of the injection system of CO_2 into the deep ocean result in the conceptual design of new sophisticated devices aiming at a satble transfer and injection of CO_2 and CO_2 hydrate. CO_2 directly contacting with sea water will be diffused into sea water or hydrate will be formed at the interface of CO_2/water. In this study a pressure and temperature in the deep sea was produced in the pressure vessel then the following facts were observed at the interface of liquid CO_2 and water (1) Instant formation of hydrate film but very slow growth of it (2) Asseleration of formation by stirring the interface (3) Prompt dissolution of hydrate by collapsing a pressure or temperature from an equilibrium conditions accompanying a rapid temperature decrease (4) Hydrate once formed is very stable unless current shear force is imposed. In a pressure vessel of 50-300atm containing liquid CO_2 and water, three principal coefficients of molecular diffusion in water, mass transfer at interface and density change of CO_2 solution have been calculated by using the CFD program developed for this research analyzing the change of CO_2 concentration distribution with time. Basic research of power plant utilizing the low temperature of liquid CO_2 has also been carried out. Further research in future of (1) Longer range pursuit of hydrate change (2) Diffusion from gas CO_2 (3) Diffusion and hydrate on a particle of liquid CO_2 are kept in mind.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] Yoshihiro Kobayashi: "Physical Behavior of Liquid CO_2 in the Ocean" DIRECT OCEAN DISPOSAL OF CO_2. 165-181 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoshihiro Kobayashi: "Formation of CO_2 Hydrate and Disposal in the Ocean" '95 International Conference on Tech.for Mar.Env.Pres.2. 896-900 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 古林 義弘: "深海底でのCO_2水和物の生成と安定性に関する研究" 日本造船学会論文集. 183(印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 古林 義弘: "地球温暖化対策としてのCO_2深海挙動の基礎研究" 先端技術研究成果報告書(長崎先端技術開発協議会). 12. 100-109 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoshihiro Kobayashi: "Physical behavior of liquid CO_2 in the ocean" Direct Ocean Disposal of CO_2. 165-181 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoshihiro Kobayashi: "Formation of CO_2 hydrate and disposal in the ocean" '95 International Conference on Technology for Marine Environment Preservation. 896-900 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoshihiro Kobayashi: "Research of CO_2 behavior in deep sea for global warming" Advanced Technologies Report, Nagasaki Prefecture. 100-109 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoshihiro Kobayashi: "Studies on the formation and stability of CO_2 hydrate in the deep ocean" Journal of the Society of Naval Architects of Japan. Vol.183 (in print).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary

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Published: 1995-04-01   Modified: 2016-04-21  

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