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Estimation of Pollution Mechanisms and Pollutant Sources in Acidrain Using Factor Analysis Accounting Chemical Equilibria.

Research Project

Project/Area Number 07640806
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 分離・精製・検出法
Research InstitutionHyogo University of Teacher Education

Principal Investigator

OZEKI Toru  Hyogo University of Teacher Education Faculty of School Education, Associate Professor, 学校教育学部, 助教授 (70152494)

Co-Investigator(Kenkyū-buntansha) OGAWA Nobuaki  Akita University Faculty of Education, Professor, 教育学部, 教授 (80169193)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1997: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1996: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1995: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsAcid rain / Environmental Chemistry / Pollution Mechanism / Factor Analysis / Meteorological Information / Geographical Environments / Glass Electrode Method / Liquid Junction Potential / 環境分析化学 / 汚染起源解析 / 地上気象情報 / ガラス電極 / 液間電位 / 因子分析法 / ミクロ滴定法 / 溶存炭酸
Research Abstract

(1) Pollutants in rainwater are ascribed to several groups such as sea salt, soil, and so on. In this project, a factor analysis applicable to precipitation data, which accounts chemical equilibria, was developed in order to extract pollutant sources. A method of numerical evaluation of the contribution of the extracted sources was also developed.
(2) During 1995 to 1997, precipitations were collected at the Hyogo University of Teacher Education (HUTE) and at the Akita University ; and their chemical compositions were analyzed. The factor analysis applied to these two data sets demonstrated the difference of the pollutant sources.
(3) In order to know the geographical difference of the chemical composition in small area, the precipitations were collected (A) at seven places around the HUTE.Similar studies were carried out (B) in Akoh city of Hyogo facing to the Seto Inland Sea, and (C) around the Biwa Lake Bridge of Siga Prefecture. The geographical deviations of the concentration of nitrate ion and sulfate ion were small, but that of calcium ion was large. Unusuallarge evolution of magnesium ion was found at a place in Akoh-city.
(4) The separation collector of rainwater and the automatic recorder of atmospheric pressure, temperature, and precipitation amount were developed. The meteorological difference such as shower, low pressure, and front gave the different levels of concentration of ion. As increasing the amount of precipitation, the concentration of pollutant ion decreases.
(5) In evaluating acidity from pH value measured by the glass electrode method, pretty large errors were observed for the precipitations of low ionic strength. The errors were ascribed to the generation of liquid junction potential at the junction of the reference electrode. The high-precision micro-titrator was invented to evaluate the exact acidity ; and the mechanism of the generation of this junction potential was examined.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] Toru Ozeki, et al.: "Evaluation of Sources of Acidity in Rainwater Using a Constrained Oblique Rotational Factor Analysis." Environmetal Sciences and Technology. 29. 1638-1645 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru Ozeki, et al.: "Numerical Evaluation of Contribution of Pollutant Sources Extracted by Constrained Oblique Rotational Factor Analysis for Precipitation Data." Analytical Sciences. 13. 169-176 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 木原 寛, et al.: "パーソナルコンピュータを活用した気象と酸性雨の関係を学ぶための環境教育教材の開発" 兵庫教育大学研究紀要. 17. 25-36 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 尾関 徹, et al.: "制限斜交回転因子分析法を用いた兵庫県社町近隣10km圏内の雨水中の汚染物質の特徴とその地域差に関する研究" 兵庫教育大学研究紀要. 17. 37-47 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuaki Ogawa, et al.: "Chemical Characterization and Evaluation of Pollutant Sources Using a Constrained Oblique Rotational Factor Analysis for Acid Precipitation." Acid Snow and Rain (Proceedings of International Congress of Acid Snow and Rain,1997). 185-190 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuaki Ogawa, et al.: "Chemical Characterization of Acid Snowfoll in the Coast and Inland Area of Akita Prefecture in Japan" Seppyo. 60(印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru Ozeki, Kunichika Koide, and Takashi Kimoto: "Evaluation of Sources of Acidity in Rainwater Using a Constrained Oblique Rotational Factor Analysis" Environ.Sci.Technol.29. 1638-1645 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru Ozeki, Kunichika Koide, Nobuaki Ogawa, Tetsuya Adzuhata, Masahiro Kajikawa, and Takashi Kimoto: "Numerical Evaluation of Contributions of Pollutant Sources Extracted by Constrained Oblique Rotational Factor Analysis for Precipitation Data. Extraction of Features of Precipitations at Hyogo and Akita Areas" Analytical Sciences. 13. 169-176 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Hiroshi Kihara, Toru Ozeki, Fumitomo Nishimura, and Hidekazu Karanishiki: "Development of Teaching Materials Using Personal Computer for Environmental Education to Learn Relation of Acid Rain with Weather Conditions" Hyogo University of Teacher Education Journal. 17. 25-36 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru Ozeki, Ko-ichi Nakamura, Kunichika Koide, and Nobuaki Ogawa: "Characterization of Rainwater Samples Collected at Yashiro Area of Hyogo Prefecture Japan by using Constrained Oblique Factor Analysis" Hyogo University of Teacher Education Journal. 17. 37-47 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuaki Ogawa Masahiro Kajikawa and Toru Ozeki: "Chemical Characterization and Evaluation of Pollutant Sources Using a Constrained Oblique Rotational Factor Analysis for Acid Precipitation in Akita, Japan" Acid Snow and Rain (Proceedings of International Congress of Acid Snow and Rain 1997), Eds.K.Aoyama, K.Katoh, T.Murano, T.Paces & Y.Taguchi, Research Association of Acid Snow & Rain, Niigata University. 185-190 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuaki Ogawa, Tetsuya, Adzuhara and Masahiro Kajikawa: "Chemical Characterization of Acid Snowfall in the Coast and Inland Area of Akita Prefecture in Japan" seppyo. 60 (in press.). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru Ozeki,et al.: "Evaluation of Sources of Acidity in Rainwater Using a Constrained Oblique Rotational Factor Analysis." Environmental Sciences and Technology. 29. 1638-1645 (1995)

    • Related Report
      1997 Annual Research Report
  • [Publications] Toru Ozeki,et al.: "Numerical Evaluation of Contribution of Pollutant Sources Extrated by Constrained Oblique Rotational Factor Analysis for Precipitation Data." Analytical Sciences. 13. 169-176 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 木原寛,et al.: "パーソナルコンピュータを活用した気象と酸性雨の関係を学ぶための環境教育教材の開発" 兵庫教育大学 研究紀要. 第17巻. 25-36 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 尾関徹,et al.: "制限斜交回転因子分析法を用いた兵庫県社町近隣10km圏内の雨水中の汚染物質の特徴とその地域差に関する研究" 兵庫教育大学 研究紀要. 第17巻. 37-47 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Nobuaki Ogawa,et al.: "Chemical Characterization and Evaluation of Pollutant Sources Using a Constrained Oblique Rotational Factor Analysis for Acid Precipitation" Acid Snow and Rain (Proceedings of International Congress of Acid Snow and Rain 1997). 185-190 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Nobuaki Ogawa,et al.: "Chemical Characterization of Acid Snow fall in the Coast and Inland Area of Akita Prefecture in Japan" Seppyo. 60(印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Ozeki、K.Koide、T.Kimoto: "Evaluation of Sources of Acidity in Rainwater Using a Constrained Oblique Rotational Pactor Analysis." Environmental Sciences and Techology. 29. 1638-1645 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] 尾関徹、中村浩一、小出邦親、小川信明: "制限斜交回転因子分析法を用いた兵庫県社町近隣10km圏内の雨水中の汚染物質の特徴とその地域差に関する研究" 兵庫教育大学研究紀要. 第17巻(印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 木原寛、尾関徹、西村文友、唐錦秀和: "パーソナル・コンピュータを活用した気象と酸性雨の関係を学ぶための環境教育教材の開発" 兵庫教育大学研究紀要. 第17巻(印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Ozeki、K.Koide、N.Ogawa、T.Adzuhata、M.Kajikawa、T.Kimoto: "Numerical Evaluation of Contributions of Pollutant Sources Extracted by Constrained Oblique Rotational Factor Analysis for Precipitation Data." Analytical Sciences. (印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Toru Ozeki: "Evaluation of Sources of Acidity in Rain water Using a Constrained oblique Rotational Factor Analysis." Environmental Sciences and Technology. 29. 1638-1645 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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