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Development of functional interfaces in materials and its structural study with a use of high-resolution transmission electron microscopy.

Research Project

Project/Area Number 07650810
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

KONNO Toyohiko  Tohoku Univ.Institute for Materials Research Research Associate, 金属材料研究所, 助手 (90260447)

Co-Investigator(Kenkyū-buntansha) SUZUKI Kenji  Tohoku Univ.Institute for Materials Research Professor, 金属材料研究所, 教授 (10005861)
SUMIYAMA Kenji  Tohoku Univ.Institute for Materials Research Associate Professor, 金属材料研究所, 助教授 (70101243)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1996: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1995: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsFunctional Materials / Interfacial Structure / Non-equilibrium Alloy / Ferromagnetic Materials / Transmission Electron Microscopy / 電気抵抗
Research Abstract

We established a reproducible method to create oxygen deficient EuO thin films whose Curie temperature is about 150K.It is essential to control the reaction kinetically, not thermodynamically, in order to make such a film. We also prepared a granular film where EuO clusters are dispersed in a ferromagnetic Fe matrix. This composite film exhibits non-saturating magnetization curve at 5K,indicating that the magnetic moments of EuO and Fe align non-colinearly.
In addition, we synthesized non-equilibrium Fe-Eu alloy thin films by evaporation technique. Though the phase diagram of the system shows that Fe and Eu are immiscible even in the liquid state, our X-ray diffraction and transmission electron microscopy measurements indicated that they do form metastable alloys. The Fe-rich side of the alloy displays a ferrimagnetic character, while Eu-rich alloys exhibits a metamagnetic behavior. Longitudinal magnetoresistance of the latter has an irreversible positive component, while transverse magenetoresistance has a negative one. These transport behavior is thought to arise from breakdown of the helical order of Eu metal by the Fe impurity.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (33 results)

All Other

All Publications (33 results)

  • [Publications] G.-F.Hohl: "Super pavamagnetic Fe Clustevs in Ag Matric Produced by Spubter-Crar Aggregutoon" Appl.Phys.Lett.66. 385-387 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sumiyama: "GMR in Fe cluster dispersed FelAg granular alloy films" J.Magn.Magn.Mater.140-144. 563-564 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sumiyama: "Structural Evolution and Magnetic Properties of Nano-Granular Metallic Alloys" J.Non-Cryst,Solid. 192-193. 539-545 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.T.Reetz: "Nanostructured Metal Oxide Clusters by Oxidation of Stabilized Metal Clusters with Air." Angew.Chem Int.Ed.Engl.35. 2092-2094 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.J.Konno: "Synthesis and Magnetic Properties of Non-Equilibrium Eu-rich EuO Thin Films" Jpn.J.Appl.Phys.35. 6052-6056 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Wakoh: "Comparative GMR Study of Fe/Cu Granular Films Deposited by Co-evaporation and Cluster Beam Techniques" Maler.Sci.Eng.A217/218. 326-330 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.J.Konno: "Structure and Magnetic Properties of Fe/EuO Granular Films." Maler.Sci.Eng.A217/218. 331-335 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sumiyama: "Structural difference between Fe/Cu and Fe/Ag granular films produced by a cluster beam method" Mater.Sci.Eng.A217/218. 340-343 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Yamamuro: "Evaluation of Fe-Ag Granular Materials by HRTEM and Magnetogranulometry" Mater.Sci.Eng.A217/218. 336-339 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Sherit El-Escandarany: "Synthesis of Full-Density Nanocrystalline Tungsten Carbide by Reduction of Tungstic Oxide at Room Temperatuve" Met.Trans.A. 27A. 4210-4213 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Ogawa: "Magnetic and Transport Properties of Non-equilibrium bcc Eu-Fe Alloys." Physica B. (in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] G.-F.Hohl, T.Hihara, M.Sakurai, T.J.Konno, K.Sumiyama, F.Hensel and K.Suzuki: "Superparamagnetic Fe Clusters in Ag Matrix Produced by Sputter-Gas Aggregation" Appl.Phys.Lett.66. 385-387 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sumiyama, S.A.Makhlouf, S.Yamamuro, Y.-F.Xu, T.J.Konno, K.Wakoh, T.Hihara and K.Suzuki: "GMR in Fe cluster dispersed Fe/Ag granular alloy films" J.Magn.Magn.Mater.140-144. 563-564 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sumiyama, K.Suzuki, S.A.Makhlouf, S.Yamamuro, K.Wakoh, T Kamiyama, S.Yamamuro, T.J.Konno, Y.-F.Xu, M.Sakurai and T.Hihara: "Structural Evolution and Magnetic Properties of Nano-Granular Metallic Alloys" J.Non-Cryst.Solid. 192-193. 539-545 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.T.Reetz, S.A.Quaiser, M.Winter, J.A.Becker, R.Schafer, U.Stimming, A.Marmann, R.Vogel and T.Konno: "Nanostructured Metal Oxide Clusters by Oxidation of Stabilized Metal Clusters with Air" Angew.Cnem.Int.Ed.Engl.35. 2092-2094 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.T.Reetz, S.A.Quaiser, M.Winter, J.A.Becker, R.Schafer, U.Stimming, A.Marmann, R.Vogel and T.Konno: "Nanostructured Metal Oxide Clusters by Oxidation of Stabilized Metal Clusters with Air" German version : Angew.Cnem.108. 2228-2230 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.J.Konno, N.Ogawa, K.Wakoh, K.Sumiyama and K.Suzuki: "Synthesis and Magnetic Properties of Non-Equilibrium Eu-rich EuO Thin Films" Jpn.J.Appl.Phys.35. 6052-6056 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Wakoh, T,Hihara, T.J.Konno, K.Sumiyama and K Suzuki: "Comparative GMR Study of Fe/Cu Granular Films Deposited by Co-Evaporation and Cluster Beam Techniques" Mater.Sci.Eng.A217/218. 326-330 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.J.Konno, N.Ogawa, K.Wakoh, K.Sumiyama and K.Suzuki: "Structure and Magnetic Properties of Fe/EuO Granular Films" Mater.Sci.Eng.A217/218. 331-335 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Sumiyama, T.Hihara, S.A.Makhlouf, K.Wakoh, M.Sakurai, Y.Xu.T.J.Konno, S.Yamamuro and K Suzuki: "Structural difference between Fe/Cu and Fe/Ag granular films produced by a cluster beam method" Mater.Sci.Eng.A217/218. 340-343 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Yamamuro, T.Hihara, K Wakoh, T.J.Konno, K.Sumiyama and K Suzuki: "Evaluation of Fe-Ag Granular Materials by HRTEM and Magnetogranulometry" Mater.Sci.Eng.A217/218. 336-339 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Sherif El-Eskandarany, M.Omori, M.Ishikuro, T.J.Konno, K.Takada, K.Sumiyama, T.Hirai and K Suzuki: "Synthesis of Full-Density Nanocrystalline Tungsten Carbide by Reduction of Tungstic Oxide at Room Temperature" Met.Trans.A.27A. 4210-4213 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Ogawa, K.Sumiyama, T.J.Konno, H.Katoh, K.Wakoh and K.Suzuki: "Magnetic and Transport Properties of Non-Equilibrium bcc Eu-Fe Alloys" Physica B. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T. J. Konno: "Structure and magnetic properties of Fe/EuO grunular films" Materials Science and Engineering A. 217/218. 331-335 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Wakoh: "Comparative GMR study of Fe/Cu granular films, deposiled by co-evaporution and clusten beum techniques" Materials Science and Engineering A. 217/218. 326-330 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S. Yamamuro: "Evaluation of Fe-Ag granular materials by HRTEM and magnetoganulometry" Materials Science and Engineering A. 217/218. 336-339 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T. J. Konno: "Synthesis and magnetic properfies of non-equilibrium Eu-rich Euo thin films" Japanese Journal of Applied physics. 35. 6052-6056 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Sherif El-Eskandaruny: "Synthesis of Full-Density, Nanocrystalline Tungsten Carbide by Reduction of Tungstic Dxide at Room Temperature" Metallurgical and Malevials Transactions A. 27. 4210-4213 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] N. Ogawa: "Magnetic and transport properties of non-equilibrium bcc Eu-Fe alloys" Physica B. (印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Sumiyama: "Structural evolution and magnetic properties of nano-granular metallic alloys" Journal of Non-Crystalline Solids. 192 & 193. 539-545 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. J. Konno: "Structure and magnetic properties of Fe/EuO granular films." Materials Science and Engineering. (印刷中).

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Wakoh: "Comparative GMR study of Fe/Cu granular films deposited by cluster beam and co-evaporation techniques" Materials Science and Engineering. ((印刷中))

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Yamamuro: "Evaluation of Fe-Ag granular materials by HRTEM and magnetogranulometry" Materials Science and Engineering. (印刷中).

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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