| Project/Area Number |
07650908
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
化学工学一般
|
|---|
| Research Institution | Junior College, Nihon University |
|---|
Principal Investigator |
TOCHIGI Katsumi Junior College, Nihon University, Professor, 教授 (70060027)
|
|---|
| Project Period (FY) |
1995 – 1997
|
| Project Status |
Completed (Fiscal Year 1997)
|
| Budget Amount *help |
¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1997: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1996: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1995: ¥700,000 (Direct Cost: ¥700,000)
|
|---|
| Keywords | Liquid-Liquid Extraction / supercritical Fluid Exstraction / Liquid-Liquid Equilibria / Phenols / ASOG / EOS-Group Contribution Method / Vapor-Liquid Equilibrium / フェノール |
|---|
| Research Abstract |
When the process to separate phenols in wastewater is considered, the extractions by toluene and supercritical carbon dioxide are useful processes. This deals with the experimental and theoretical studies.
When the liquid-liquid equilibria for phenol + water + solvents are considered, the fundamental properties are the relationships between binary mutual solubilities and temperatures. The relation was correlated from the representation of temperature dependence of SILS parameters using quardratic equation.
In order to check the solvent effect of toluene, the liquid-liquid equilibria were measured for phenol + water + toluene system. It was confirmed that toluene is effective solvent.
A EOS-group contribution method was used to predict the solvent effect of supercritical carbon dioxide and it was confirmed the carbon dioxide is useful solvent, too.
|
