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Development of electrical conjugated polymers with liquid crystalline and magnetic properties

Research Project

Project/Area Number 07651092
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionUniversity of Tsukuba

Principal Investigator

AKAGI Kazuo  University of Tsukuba, Institute of Materials Science, Professor, 物質工学系, 教授 (20150964)

Co-Investigator(Kenkyū-buntansha) SHIRAKAWA Hideki  University of Tsukuba, Institute of Materials Science, Professor, 物質工学系, 教授 (40016720)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1997: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1996: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1995: ¥800,000 (Direct Cost: ¥800,000)
KeywordsConjugated polymers / Polyacetylene derivatives / Liquid crystallinity / Stable radical group / Magnetic properties / Macroscopic orientation / Spin alignment / Organic ferromagnet / 導電性高分子 / 磁性 / ESR / 高分子液晶 / 二置換ポリアセチレン / ラジカル基 / 配向制御 / 電子スピン共鳴
Research Abstract

Side-chain liquid crystalline (LC) conjugated polymer with stable radical group is expected to afford a parallel spin alignment with aids of spontaneous orientation and externally forced macroscopic alignment of LC side chains. The present study is aimed to achieve a macroscopic spin alignment through LC orientation, For this aim, di-substituted polyacetylene with LC group and stable radical group in side chains is useful, where the intrachain parallel spin alignment can be easily constructed on the basis of topological stereoregularity satisfying Ovchinnikov rule.
Di-substituted polyacetylene was synthesized by introducing both liquid crystalline LC group and stable radical group into side chains. Di-tert-butylphenol derivative, where the hydroxy moiety of the phenyl group was protected by trimethylsilyl group, was adopted as a stable radical precursor. Acetylene monomer substituted with the LC group and the radical precursor was polymerized using metathesis catalyst of TaCI_5-(n-Bu)_4Sn. The polymer synthesized was soluble in organic solvents and showed an enantiotropic smectic phase. ESR spin intensity of the polymer was evaluated after the radical precursor was deprotected and oxidized, Anisotropy in spin intensity, owing to spontaneous alignment of LC side chains, was confirmed.
Next, the mono-substituted polyacetylene copolymer was synthesized, where either the LC group or the radical group was substituted into the unit cell of main chain. The copolymer, in which the ratio of radical group-substituted polyene segment is less than 10 %, showed a smectic phase in 150 - 160゚C.The ESR intensity increased in the LC temperature. This is ascribed to the spin alignment of phenoxy radical electrons within LC domains.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (189 results)

All Other

All Publications (189 results)

  • [Publications] H.Shirakawa: "Synthesis and Characterization of Highly Conducting Polyacetylene" Synthetic Metals. 69. 3-8 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Synthesis and Properties of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 69. 13-16 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Polyacetylene Films Prepared by Intrinsic Non-Solvent Polymerization Method-Mechanical Properties and Electrical Conductivities" Synthetic Metals. 69. 29-30 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Fused State ^<13>C-NMR Study on Liquid Crystalline Polyacetylene Derivatives-Magnetically Forced Alignment and Orientational Behavior" Synthetic Metals. 69. 33-34 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Sakamaki: "Thermodynamic Behavior of Cis-Trans Isomerization in S- and N-type Polyacetylene Films. DSC study" Synthetic Metals. 69. 57-58 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Thermotropic Liquid Crystalline Conjugated Polymers, Poly(cyclohexylphenoxyacetylenes)-Synthesis and Properties" Synthetic Metals. 71. 1899-1990 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Toyoshima: "Synthesis and Properties of Polythiophene Derivatives with Liquid Crystalline Substituents" Synthetic Metals. 69. 289-290 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C.O.Yoon: "Effect of Anisotropy on the Temperature Dependence of Conductivity and Magnetoconductance in Heavily Doped Polyacetylene" Synthetic Metals. 69. 79-80 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshino: "Unique Electrical and Optical Properties of Polyacetylene Derivatives in Liquid Crystal Phase" Synthetic Metals. 69. 49-50 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] E.B.Park: "Positive Thermoelectric Power of Alkali-Metal-Doped Polyacetylene" Synthetic Metals. 69. 61-62 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Electrically Conducting Liquid Crystalline Polymers,Mono-Substituted Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.267. 277-282 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Mizoguchi: "Analysis of the ESR Linewidth in Pristine Trans-Polyacetylene" Phys.Rev.B. 51. 8864-8873 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshino: "Unique Liquid Crystalline Behavior of Conducting Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.261. 637-647 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kyotani: "Isothermal Cis-Trans Isomerization Behavior of Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 581-585 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kyotani: "Thermal Isomerization and Morphology of Various Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 587-593 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Tanabe: "Mechanism of Cis-Trans Thermal Isomerization of Polyacetylene" Macromolecules. 28. 4173-4178 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Morphological Alignment of Liquid Crystalline Conducting Polyacetylene Derivatives" Macromolecular Symposia. 104. 137-158 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystalline Conducting Polymers" Polymer Preprints, National Meeting of American Chemical Society. 37. 62-63 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshino: "Liquid Crystalline Behaviors of Conducting Polyacetylene Derivative with Mesogenic Substituent and Its Mixture with Ferroelectric Liquid Crystal" Jpn.J.Appl.Phys.35. 3964-3970 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Aoki: "Current Progress in Synthesis of Polyacetylene Films" Synthetic Metals. 84. 307-310 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Mutable Morphologies of Polyacetylene Films" Synthetic Metals. 84. 419-420 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Sakamaki: "Relationship between Crystallinity and Electrical Conductivity of Highly Conducting Polyacetylene Films" Synthetic Metals. 84. 365-366 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Ferroelectric Liquid Crystalline Conducting Polymers-Synthesis and Properties of Polyacetylene Derivatives with Chiroptical Liquid Crystalline Groups" Synthetic Metals. 84. 313-316 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Iino: "High Order Structures of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84. 967-968 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and Properties of Photo-Responsible Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84. 373-374 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and Propeties of Small-Bandgap Liquid Crystalline Conjugated Polymers" Synthetic Metals. 84. 385-386 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Toyoshima: "Syntheses and Properties of Poly(thienylenevinylene) Derivatives with Hexyl Grops" Synthetic Metals. 84. 431-432 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and ESR Characterizations of Conjugated Polymers with Nitrogen Atoms" Synthetic Metals. 84. 1683-1684 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Spin Structures and Properties of Paramagnetic Nickel(II)Complexes with Liquid Crystalline β-Diketone Ligands" Synthetic Metals. 85. 1669-1670 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystalline Titanocenes with Catalytic Activity for Polymerizations of Acetylene Derivatives" Synthetic Metals. 85. 1879-1880 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] D.Ichinohe: "Magnetic Properties of Poly(m-aniline)" Synthetic Metals. 85. 1671-1672 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Mizoguchi: "Neutral Soliton Dynamics in t-Polyacetylene-Consistent Picture for Magnetic Resonances" Synthetic Metals. 84. 865-866 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Mizoguchi: "Distribution of Neutral Solitons in t-Polyacetylene-Crystalline and Amorphous Regions" Synthetic Metals. 84. 913-914 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Photo-Responsible Liqued Crystalline Conducting Polymers" J.Photopolym.Sci.and Tech.10. 233-240 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Masuda: "Orientation Analysis of Polyacetylene with Liquid Crystalline Side Chains" J.Mol.Struct.441. 173-181 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Novel Liquid-Crystalline Titanocene Complexes with Catalytic Activity for Polymerizations of Acetylene and Phenylacetylene" Polymer. 39. 3559-3564 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Photoluminescent Conjugated Polymers with Liquid Crystallinities" J.Photopolym.Sci.Tech.11. 249-252 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Small Bandgap Type Liquid Crystalline Conjugated Polymers" Mol.Cryst.Liq.Cryst.316. 201-204 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized with a Chiral Nematic Reaction Field" Science. 282. 1683-1686 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Syntheses and Properties of Polythiophene Derivatives with Phenylalkyl and Liquid Crystalline Groups" Mol.Cryst.Liq.Cryst.318. 157-177 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized under Chiral Nematic Liquid Crystals" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "A family of Liquid Crystalline Polyarylenevinylenes" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystalline Polyacetylene Derivatives with Stable Radical Groups" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Liquid Crystalline Polyaniline Derivatives" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Syntheses of Polyaniline Derivatives with Stable Radical Groups and Their Properties" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Syntheses and Properties of Thiophene and Pyrrole based Liquid Crystalline Small-Bandgap Polymers" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Synthesis and Properties of Helical Polyacetylene" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Chiroptical Titanium Complexes as Catalytically Active Chiral Dopants Available for Asymmetric Acetylene Polymerization" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] X.-M.Dai: "Synthesis and Properties of Novel Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] X.-M.Dai: "Synthesis and Properties of Polythiophene Derivatives with Ferroelectric Liquid Crystalline Substitutents" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.S.Liang: "Synthesis of Polyacetylene Ultra-thin Film" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] J.Oguma: "Synthesis and Properties of Liquid crystalline Poly(p-phenylene) and Poly(p-phenylenevinylene) Derivatives" Synthetic Metals, in press.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] I.Osaka: "Synthesis and Properties of Liquid Crystalline Polythiophene Derivatives" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Matsushita: "Effects of Pressure on The Electrical Resistivity of Doped Polyacetylene" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] X-.M.Dai: "Synthesis and Characterization of Side Chain Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Trans.Mat.Res.Soc.Jpn.(in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Side-Chain Liquid Crystalline Polyacetylene Derivative-Synthesis,Chemical Doping,and Magnetically Forced Alignment" Trans.Mat.Res.Soc.Jpn.(in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and Magnetic Propeties of Polyaniline Derivatives with Stable Radical Group" Trans.Mat.Res.Soc.Jpn.,. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Liquid Crystalline Polyacetylene Derivative Bridged with Metallomesogenic Group" Trans.Mat.Res.Soc.Jpn.(in press).

    • Description
      「研究成果報告書概要(和文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Hilical Polyacetylene Synthesized Under Asymmetric Reaction Field Constructed with Chiral Nematic Liquid Crystals" Mol.Cryst.Liq.Cryst.(in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 赤木 和夫: "液晶性共役系高分子の合成と性質" 高分子論文集. 56. 217-233 (1999)

    • Description
      「研究成果報告書概要(和文)」より
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      1997 Final Research Report Summary
  • [Publications] 赤木和夫: "光・電子機能有機材料ハンドブック" 編集、堀江一之、谷口彬雄 朝倉書店, 20 (1995)

    • Description
      「研究成果報告書概要(和文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: "The Polymeric Materials Encyclopedia. Synthesis,Properties and Applications" J.C.Salamone,Editor,CRC Press,New York, 7 (1996)

    • Description
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: "The Polymeric Materials Encyclopedia. Synthesis,Properties and Applications" J.C.Salamone,Editor,CRC Press,New York, 12 (1996)

    • Description
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Current Trends in Polymer Science" K.L.De Vries et al., Editor,Research Trends,India, 15 (1997)

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      1997 Final Research Report Summary
  • [Publications] H.Shirakawa: "Handbook of Conducting Polymers,2nd Ed." Skotheim,Elsenbaumer,Reynolds,Editor,Marcel Dekker,New York, 12 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 白川 英樹: "機能性超分子の設計と将来展望" 監修、緒方直哉、寺野 稔、由井伸彦,シーエムシー, 8 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Electrical and Optical Polymer Systems: Fundamentals,Methods,and Applications" Wise,Trantolo,Wnek,Editor,Marcel Dekker,New York, 28 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Shirakara: "Synthesis and Characterization of Highly Conducting Polyacetylene" Synthetic Metals. 69. 3-8 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Synthesis and Properties of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 69. 13-16 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Polyacetylene Films Prepared by Intrinsic Non-Solvent Polymerization Method - Mechanical Properties and Electrical Conductivities" Synthetic Metals. 69. 29-30 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Fused State ^<13>C-NMR Study on Liquid Crystalline Polyacetylene Derivatives - Magnetically Forced Alignment and Orientational Behavior" Synthetic Metals. 69. 33-34 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Sakamaki: "Solid State Properties and Thermal Isomerization Behavior in Polyactylene Films" Synthetic Metals. 69. 57-58 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Thermotropic Liquid Crystalline Conjugated Polymers, Poly (cyclohexylphenoxyacetylenes) -Synthesis and Properties" Synthetic Metals. 71. 1899-1990 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Toyoshima: "Synthesis and Properties of Polythiophene Derivatives with Liquid Crystalline Substituents" Synthetic Metals. 69. 289-290 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C.O.Yoon: "Effect of Anisotropy on the Temperature Dependence of Conductivity and Magnetoconductance in heavily Doped Polyacetylene" Synthetic Metals. 69. 79-80 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Tanabe: "Isothermal Cis-Trans Isomerization of Polyacetylene" Synthetic Metals. 69. 45-46 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshino: "Unique Electrical and Optical Properties of Polyacetylene Derivatives in Liquid Crystal Phase" Synthetic Metals. 69. 46-50 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] E.B.Park: "Positive Thermoelectric Power of Alkali-Metal-Doped Polyacetylene" Synthetic Metals. 69. 61-62 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Electrically Conducting Liquid Crystalline Polymers, Mono-Substituted Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.267. 277-282 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
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  • [Publications] K.Mizoguchi: "Analysis of the ESR Linewidth in Pristine Trans-Polyacetylene" Phys.Rev.B. 51. 8864-8873 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Yoshino: "Unique Liquid Crystalline Behavior of Conducting Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.261. 637-647 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] H.Kyotani: "Isothermal Cis-Trans Isomerization Behavior of Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 581-585 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] H.Kyotani: "Thermal Isomerization and Morphology of Various Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 587-593 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
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  • [Publications] Y.Tanabe: "Mechanism of Cis-Trans Tehrmal Isomerization of Polyacetylene" Macromolecules. 28. 4173-4178 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Morphological Alignment of Liquid Crystalline Conducting Polyacetylene Derivatives" Macromolecular Symposia. 104. 137-158 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystalline Conducting Polymers" Polymer Preprints, National Meeting of American Chemical society. 37. 62-63 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Yoshino: "Liquid Crystalline Behaviors of Conducting Polyacetylene Derivative with Mesogenic Substituent and Its Mixture with ferroelectric Liquid Crystal" Jpn.J.Appl.Phys.35. 3964-3970 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Aoki: "Current Progress in Synthesis of Polyacetylene Films" Synthetic Metals. 84, No.1-3. 307-310 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Mutable Morphologies of Polyacetylene Films" Synthetic Metals. 84, No.1-3. 419-420 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Sakamaki: "Relationship between Crystallinity and Electrical Conductivity of Highley Conducting Polyacetylene Films" Synthetic Metals. 84, No.1-3. 365-366 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Ferroelectric Liquid Crystalline Conducting Polymers - Synthesis and Properties of Polyacetylene Derivatives with Chiroptical Liquid Crystalline Groups" Synthetic Metals. 84, No.1-3. 313-316 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Iino: "High Order Structures of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84, No.1-3. 967-968 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and Properties of Photo-Responsible Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84, No.1-3. 373-374 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and Properties of Small-Bandgap Liquid Crystalline Conjugated Polymers" Synthetic Metals. 84, No.1-3. 385-386 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] R.Toyoshima: "Syntheses and Properties of Poly (thienylenvinylene) Derivatives with Hexyl Groups" Synthetic Metals. 84, No.1-3. 431-432 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "synthesis and ESR Characterizations of Conjugated Polymers with Nitrogen Atoms" Synthetic Metals. 85, No.1-3. 1683-1684 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Spin Structures and Properties ofParamagnetic Nickel (II) Complexes with Liquid Crystalline beta-Diketone Ligands" Synthetic Metals. 85, No.1-3. 1669-1670 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystalline Titanocenes with Catalytic Activity for Polymerizations of Acetylene Derivatives" Synthetic Metals. 86, No.1-3. 1879-1880 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] D.Ichinohe: "Magnetic Properties of Poly (m-aniline)" Synthetic Metals. 85, No.1-3. 1671-1672 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Mizoguchi: "Neutral Soliton Cynamics in t-Polyacetylene-Consistent Picture for Magnetic Resonances" Synthetic Metals. 84, No.1-3. 865-866 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Mizoguchi: "Distribution of Neutral Solitons in t-Polyacetylene-Crystalline and Amorphous Regions" Synthetic Metals. 84, No.1-3. 913-914 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Photo-Responsible Liquid Crystalline Conducting Polymers" J.Photoplym.Sci.and Tech.10, No.2. 233-240 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystallne Conducting Polyarylene and Polyarylenevinylene Derivatives-Synthesis and Properties" The Second Symposium on Harmonized Molecular Materials. 19-20 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.masuda: "Orientation Analysis of Polyacetylene with Liquid Crystalline Side Chains" J.Mol.Struct.441 (2-3). 173-181 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] G.Piao: "Novel Liquid-Crystalline Titanocene Complexes with Catalytic Activity for Polymerizations of Acetylene and Phenylacetylene" Polymer. 39, No.15. 3559-3546 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Photoluminescent Conjugated Polymers with Liquid Crystallinities" J.Photopolym.Sci.Tech.11, No.2. 249-252 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Small Bandgap Type Liquid Crystalline Conjugated Polymers" Mol.Cryst.Liq.Cryst.316. 201-204 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized with a Chiral Nematic Reaction Field" Science. 282, No.5394, Nov.27. 1683-1686 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Syntheses and Properties of Polythiophene Derivatives with Phenylalkyl and Liquid Crystalline Groups" Mol.Cryst.Liq.Cryst.318. 157-177 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized under Chiral Nematic Liquid Crystals" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "A family of Liquid Crystalline Polyarylenevinylenes" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Liquid Crystalline Polyacetylene Derivatives with Stable Radical Groups" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Liquid Crystalline Polyaniline Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Syntheses of Polyaniline Derivatives with Stable Radical Groups and Their Properties" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Syntheses and Properties ofThiophene and Pyrrole based Liquid Crystalline Small-Bandgap Polymers" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Synthesis and Properties of Helical Polyacetylene" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Piao: "Chiroptical Tianium Complexes as Catalytically Active Chiral Dopants Available for Asymmetric Acetylene Polymerization" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] X.-M.Dai: "Synthesis and Properties of Novel Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] X.-M.Dai: "synthesis and Properties of Polythiophene Derivatives with Ferroelectric Liquid Crystalline Substitutents" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.S.Liang: "Synthesis of Polyacetylene Ultra-thin Film" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] J.Oguma: "Synthesis and Properties of Liquid crystalline Poly (p-phenylene) and Poly (p-phenylenevinylene) Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] I.Osaka: "Synthesis and Properties of Liquid Crystalline Polythiophene Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Matsushita: "Effects of Pressure on The Electrical Resistivity of Doped Polyacetylene" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] X.M.Dai: "Synthesis and Charactirization of Side Chain Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Side-Chain Liquid Crystalline Polyacetylene Derivative-Synthesis, Chemical Doping, and Magnetically Forced Alignment" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] H.Goto: "Synthesis and Magnetic Properties of Polyaniline Derivatives with Stable Radical Group" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Goto: "Liquid Crystalline Polyacetylene Derivative Bridged with Metallomesogenic Group" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized Under Asymmetric Reaction Field Constructed with Chiral Nematic Liquid Crystals" Mol.Cryst.Liq.Cryst.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Synthesis and Properties of Liquid Crystalline Conjugated Polymers (in Japanese)" Kobunshi Ronbun Shyu. 56, No.4. 217-233 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: Handbook of Origanic Materials with Light and Electronic Functions (in Japanese) "Conducting Polymers". Ed.by K.Horie and Y.Taniguchi, Asakura Syoten, 20 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: The Polymeric Materials Encyclopedia. Synthesis, Properties and Applications, 5 "Liquid Crystalline Polymers, Poly (acetylene) Derivatives". Ed.by J.C.Salamone.CRC Press, (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Polyacetylene Films". Ed.by J.C.Salamone, CRC Press The Polymeric Materials Encyclopedial Synthesis, Properties and Applications, 8, 12 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: Current Trends in Conducting Polymers-Liquid Crystalline Polyacetylene Derivatives. Ed.by K.L.DeVries et al., Research Trands Current Trends in Polymer Science, 2, 15 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] H.Shirakawa: Synthesis ofPolyacetylene. Ed.by, Skotheim, Elsenbaumer, Reynolds, Marcel Dekker, 12 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] H.Shirakawa: Ed.by N.Ogata, M.Terano, N.Yui, CMC Press Desing and Prospect of Functional Supramolecules, (in Japanese). Conducting Supramolecules, 8 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
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      1997 Final Research Report Summary
  • [Publications] K.Akagi: Ed.by D.L.Wise, D.J.Trantolo, G.E.Wnek, Marcel Dekker Electrical and Optical Polymer Systems : Funcdamentals, Methods, and Applications, Chap.28. Advances in Conducting Polymers, 28 (1998)

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      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Akagi: "Ferroelectric Liquid Crystalline Conducting Polymers-Synthesis and Properties of Polyacetylene Derivatives with Chiroptical Liauid Crystalline Groups" Synthetic.Metals. 84(1-3). 313-316 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Akagi: "Liquid Crystalline Titanocenes with Catalytic Activity for Polymerizations of Acetylene Derivatives" Synthetic.Metals. 86(1-3). 1879-1880 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Goto: "Synthesis and Properties of Small-Bandgap Liquid Crystalline Conjugated Polymers" Synthetic.Metals. 84(1-3). 385-386 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] R.Toyoshima: "Syntheses and Properties of Poly(thienylenevinylene)Derivatives With Hexyl Groups" Synthetic Metals. 84(1-3). 431-432 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Goto: "Synthesis and ESR Characterizations of Conjugated Polymers with Nitrogen Aroms" Synthetic Metals. 85(1-3). 1683-1684 (1997)

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      1997 Annual Research Report
  • [Publications] K.Akagi: "Photo-Responsible Liquid Crystalline Conducting Polymers" Journal of Photopolymer Science and Technology. 10(2). 233-240 (1997)

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      1997 Annual Research Report
  • [Publications] K.Akagi(分担): "Current Trends in Polymer Science" Research Trends, 107-124 (1997)

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      1997 Annual Research Report
  • [Publications] K.Akagi(分担): "Electrical and Optical Polymer Systems:Fundamentals,Methods,and Applications" Marcel Dekker, 983-1010 (1997)

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      1997 Annual Research Report
  • [Publications] K.Akagi: "Morphological Alignment of Liquid Crystalline Conducting Polyacetylene Derivatives" Macromolecular Symposia. 104. 137-158 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Akagi: "Liquid Crystalline Conducting Polymers" ACS Polymer Preprints. 37. 62-63 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Yoshino: "Liquid Crystalline Behaviors of Conducting Polyacetylene Derivative with Mesogenic Substituent and Its Mixture with Ferroelectric Liquid Crystal" Jpn.J.Appl.Phys.35. 3964-3970 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Aoki: "Current Progress in Synthesis of Polyacetylene Films" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Akagi: "Mutable Morphologies of Polyacetylene Films" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Sakamaki: "Relationship between Crystallinity and Electrical Conductivitiy of Highly Conducting Polyacetylene Films" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Akagi: "Ferroelectric Liquid Crystalline Conducting Polymers-Synthesis and Proreties of Polyacetylene Derivatives with Chiroptical Liquid Crystalline Groups" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Iino: "High Order Structures of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. (1997)

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      1996 Annual Research Report
  • [Publications] H.Goto: "Synthesis and Propeties of Photo-responsible Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. (1997)

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      1996 Annual Research Report
  • [Publications] H.Goto: "Synthesis and Propeties of Small-Bandgap Liquid Crystalline Conjugated Polymers" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] R.Toyoshima: "Syntheses and Properties of Poly(thienylenevinylene) Derivatives with Hexyl Groups" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Goto: "Synthesis and ESR Characterizations of Conjugated Polymers with Nitrogen Atoms" Synthetic Metals. (1997)

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  • [Publications] G.Piao: "Spin Structures and Properties of Paramagnetic Nickel(II)Complexes with Liquid Crystalline β-Diketone Ligands" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Akagi: "Liquid Crystalline Titanocenes with Catalytic Activity for Polymerizations of Acetylene Derivatives" Synthetic Metals. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Akagi(分担執筆): "The Polymeric Materials Encyclopedia.Synthesis,Properties and Applications,vol.5" CRC Press, 3669-3675 (1996)

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      1996 Annual Research Report
  • [Publications] K.Akagi(分担執筆): "The Polymeric Materials Encyclopedia.Synthesis,Properties and Applications,Vol.8" CRC Press, 5315-5326 (1996)

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      1996 Annual Research Report
  • [Publications] K.Akagi(分担執筆): "Electrical and Optical Polymer Systems:Fundamentals,Methods,and Applications" World Scientific Pub., (1997)

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      1996 Annual Research Report
  • [Publications] Kazuo Akagi: "Side-Chain Liquid Crystalline Conjugated Polymers, Poly(Mono-Substituted Acetylenes)" Trans. Mat. Res. Soc. Jpn.15A. 259-262 (1994)

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      1995 Annual Research Report
  • [Publications] Kazuo Akagi: "Syntheses of Thiophene Derivatives with Liquid Crystalline Substituents" Trans. Mat. Res. Soc. Jpn.15A. 513-516 (1994)

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      1995 Annual Research Report
  • [Publications] Hideki Shirakawa: "Various Factors Affecting the Synthesis of Highly Conducting Polyacetlene" Synthetic Metals. 60. 93-101 (1994)

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  • [Publications] Hideki Shirakawa: "Synthesis of Liquid Crystalline Polyacetylene Derivatives" Mol. Cryst. Liq. Cryst.255. 132-219 (1994)

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      1995 Annual Research Report
  • [Publications] Kazuo Akagi: "Synthesis and Properties of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 69. 13-16 (1995)

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  • [Publications] Kazuo Akagi: "Fused State ^<13>C-NMR Study on Liquid Crystalline Polyacetylene Derivatives-Magnetically Forced Alignment and Orientational Behavior." Synthetic Metals. 69. 33-34 (1995)

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  • [Publications] Ryouichi Toyoshima: "Synthesis and Properties of Polythiophenes Derivatives with Liquid Crystalline Substituents." Synthetic Metals. 69. 289-290 (1995)

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      1995 Annual Research Report
  • [Publications] Katsumi Yoshino: "Unique Electrical and Optical Properties of Polyacetylene Derivatives in Liquid Crystal Phase" Synthetic Metals. 69. 49-50 (1995)

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  • [Publications] Hiromasa Goto: "Thermotropic Liquid Crystalline Conjugated Polymers,Poly(cyclohexylphenoxyacetylenes)-Synthesis and Properties." Synthetic Metals. 71. 1899-1990 (1995)

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      1995 Annual Research Report
  • [Publications] Kazuo Akagi: "Electrically Conducting Liquid Crystalline Polymers, Mono-Substituted Polyacetylene Derivatives." Mol. Cryst. Liq. Cryst.267. 277-282 (1995)

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      1995 Annual Research Report
  • [Publications] Kazuo Akagi: "Polyacetylene Films Prepared by Intrinsic Non-Solvent Polymerization Method-Mechanical Properties and Electrical Conductivities." Synthetic Metals. 69. 29-30 (1995)

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      1995 Annual Research Report
  • [Publications] Kouichi Sakamaki: "Thermodynamic Behavior of Cis-Trans Isomerization in S-and N-type Polyacetylene Films. DSC study." Synthetic Metals. 69. 57-58 (1995)

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  • [Publications] C. O. Yoon: "Effect of Anisotropy on the Temperature Dependence of Conductivity and Magnetoconductance in Heavily Doped Polyacetylene" Synthetic Metals. 69. 79-80 (1995)

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  • [Publications] Yoshikazu Tanabe: "Isothermal Cis-Trans Isomerization of Polyacetylene" Synthetic Metals. 69. 45-46 (1995)

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  • [Publications] E. B. Park: "Positive Thermoelectric Power of Alkali-Metal-Doped Polyacetylene" Synthetic Metals. 69. 61-62 (1995)

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  • [Publications] Kenji Mizoguchi: "Analysis of the ESR Linewidth in Pristine Trans-Polyacetylene" Phys. Rev. B. 51. 8864-8873 (1995)

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  • [Publications] Katsumi Yoshino: "Unique Liquid Crystalline Behavior of Conducting Polyacetylene Derivatives" Mol. Cryst. Liq. Cryst.in press (1995)

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  • [Publications] Hiroko Kyotani: "Isothermal Cis-Trans Isomerization Behavior of Polyacetylene Films" J. Polym. Sci. Part B, Polym. Phys.32. 581-585 (1995)

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  • [Publications] Hiroko Kyotani: "Thermal Isoerization and Morphology of Various Polyacetylene Films" J. Polym. Sci. Part B, Polym. Phys.32. 587 : 593 (1995)

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  • [Publications] Yoshikazu Tanabe: "Machanism of Cis-Trans Thermal Isomerization of Polyacetylene" Macromolecules. 28. 4173-4178 (1995)

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  • [Publications] Kazuo Akagi: "Morphological Alignment of Liquid Crystalline Conducting Polyacetylene Derivatives," Macromolecular Symposia. in press (1996)

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  • [Publications] 赤木,和夫: "導電性ポリアセチレン類の配向制御" 表面. 32. 32-45 (1994)

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  • [Publications] 赤木,和夫: "導電性液晶高分子" 高分子. 43. 741 (1994)

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  • [Publications] 赤木,和夫: "一番導電性の高い高分子は?" 高分子. 44. 456-567 (1995)

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  • [Publications] 赤木,和夫: "液晶性をもつ導電性高分子の開発と展開" 応用物理. 65. 265-269 (1996)

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  • [Publications] Kazuo Akagi: "The Polymeric Materials Encyclopedia. Synthesis, Properties and Applications" Liquid Crystalline Polyacetylene Derivatives CRC Press, Inc. (in press), (1996)

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  • [Publications] Kazuo Akagi: "The Polymeric Materials Encyclopedia.Synthesis, Properties and Applications" Polyacetylene Films CRC Press,Inc. (in press), (1996)

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  • [Publications] 赤木,和夫: "光・電子機能有機材料ハンドブック" 編集代表、堀江一之、谷口彬雄 朝倉書店, 20 (1995)

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Published: 1995-04-01   Modified: 2016-04-21  

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