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Studies on switching mechanism of ferroelectric polymer liquid crystals by time-resolved optical waveguide spectroscopy

Research Project

Project/Area Number 07651105
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

ITO Shinzaburo  Kyoto Univ, Graduate School of Eng., Associate Professor, 工学研究科, 助教授 (50127049)

Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1996: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1995: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsPolymer Liquid Crystal / Ferroelectric Liquid Crystal / Optical Waveguide / Time-Resolving / optical Switching / Molecular Orientation / Dynamics / 光スイッチ
Research Abstract

1.Development of time-resolved optical waveguide spectroscopy (TROWS)
The switching times of most ferroelectric liquid crystals range from micro-to milli-second, which means one must develop an instrument with a time-resolution faster than microsecond. The first step of this research was conserned with this issue, and the TROWS we made could detect transient optical waveguide mode patterns under the switching every a few tens nanoseconds.
2.Dynamics of flow molecular weight nematic liquid crystals
The new technique using TROWS was applied firstly to the study of low molecular weight nematic liquid crystals. The molecular motion under external electric field was analyzed by a multi-layr approximation, showing that the angle distribution and its time dependence between two stable states of homeotropic and parallel orientations.
3.Studies on transient structures of a ferroelectric liquid crystal
The internal structures of a ferroeletric liquid crystal under a static high-electric feild and und … More er the inversion of its polarity, were investigated.From the analysis of waveguide modes, we found a transient bending motion of the smectic layrs such as bookshelf*chevron*bookshelf, and it was revealed that on the way of switching, the molecules in upper and lower halves between the electrodes take place an unti-symmetrical cone motion synchronized with the bending of chevron structure.
4.Switching mechanism of ferroelectric polymer liquid crystals
Ferroelectric polymer liquid crtstals were investigated on the basis of the knowledge obtained for low molecular weight ones. The transient waveguide patterns clearly showed the existence of bending motion of smectic layrs as well as low molecular weight liquid crystals. Since the polymer main chains locate between smectic layrs, they have little effect on the rotational motion of the mesogenic side chains, which perform a coherent motion among layrs under alternating electric field. These cooperative motions enable the side chains to switch their orientation with a high speed as fast as low molecular liquid crystals. Less

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] S. Ito: "Guided Optical Waves in a Ferroelectric Liquid Crystal Layer : A Birefringence Analysis" Mol.Cryst.Liq.Cryst.264. 99-114 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Mitsuishi: "Time-resolved Optical Waveguide Spectroscopy : Application to a Study of the Switching Process of a Nematic Liquid Crystal" Appl.Phys.Lett.69. 2199-2201 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H. Knobloch: "Command Surface Induced Switching of the Optical Properties of Liquid Crystalline Thin Film Structure" Synthetic Metals. 81. 297-300 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Mitsuishi: "Time-resolved Optical Waveguide Study of the Reorientation in a Nematic Liquid Crystal under Applied Electric Field" J.Appl.Phys.81. 1135-1142 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Mitsuishi: "Optical Switching of a Metal Crad Waveguide with a Ferro-electric Liquid Crystal" Appl.Optics. 36. 9225-9229 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M. Mitsuishi: "Dynamics of the Reorientation of a Ferroelectric Liquid Cryscal under an Electric Field Studied by Time-resolved Optical Waveguide Spectroscopy" MOl.Cryst.Liq.Cryst.308. 1-26 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Ito, F.Kremer, T.Fischer, and W.Knoll: "Guided Optical Waves in a Ferroelectric Liquid Crystal Layr : A Birefringence Analysis of Molecular Orientation on the Swithching Process" Mol.Cryst.Liq.Cryst.Vol.264. 99-114 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Mitsuichi, S.Ito, M.Yamamoto, and W.Knoll: "Time-Resolves Optical Waveguide Spectroscopy : Application to a Study of the Switching Process of a Nematic Liquid Crystal under the Influence of an Electric Field" Appl.Phys.Lett.Vol.69. 2199-2201 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Knobloch, H.Orendi, B.Stiller, M.Buchel, W.Knoll, T.Seki, S.Ito, L.Brehmer: "Command Surface Induced Switching of the Optical Properties of Liquid Crystalline Thin Film Structures" Synthetic Metals. Vol.81. 297-300 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Mitsuishi, S.Ito, M.Yamamoto, T.Fischer, and W.Knoll: "Time-Resolved Optical Waveguide Study of the Reorientation in a Nematic Liquid Crystal under Applied Electric Field" J.Appl.Phys. Vol.81. 1135-1142 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Mitsuishi, S.Ito, M.Yamamoto, T.Fischer, and W.Knoll: "Optical Switching of a Metal Clad Waveguide with a Ferroelectric Liquid Crystal" Appl.Optics. Vol.36. 9225-9229 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Mitsuishi, S.Ito, M.Yamamoto, T.Fischer, and W.Knoll: "Dynamics of the Reorientation of a Ferroelectric Liquid Crystal under an Electric Field Studied by Time-Resolved Optical Waveguide Spectroscopy" Mol.Cryst.Liq.Cryst.Vol.308. 1-26 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Shinzaburo ITO: "Guided Optical Waves in a Ferroelectric Liquid Crystal Layer" Mol.Cryst.Liq.Cryst.264. 99-114 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] Harald Knobloch: "Command Surface Induced Switching of the Optical Properties of Liquid Crystallin Thin Film Structure" Synthetic Metals. 81. 297-300 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Masaya Mitsuishi: "Time-Resolved Optical Waveguide Spectroscopy : Application to a Study of the Switching Process" Appl.Phys.Lett.69. 2199-2201 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Masaya Mitsuishi: "Time-Resolved Optical Wavequide Study of the Reorientation in a Nematic Liquid Crystal under Applied E-fie" J.Appl.Phys.81. 1135-1142 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 伊藤 紳三郎: "Guided Optical Waves in a Ferroelectric Liquid Crystal Layer" Mol. Cryst. Liz. Cryst.264. 99-114 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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