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DEVELOPMENT OF MOLECULAR ACTUATOR BASED ON CONFORMATIONAL TRANSFORMATION

Research Project

Project/Area Number 07651113
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionSAGA University

Principal Investigator

OISHI Yushi  SAGA UNIVERSITY,DEPARTMENT OF APPLIED CHEMISTRY,ASSOCIATE PROFESSOR, 理工学部, 助教授 (70194074)

Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1996: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1995: ¥900,000 (Direct Cost: ¥900,000)
KeywordsMONOLAYER / POLYOXYMETHYLENE / DIPOLE MOMENT / CONFORMATAION / ACTUATOR / AFM
Research Abstract

Recently, development of molecular mashine, acting in a scale of molecular assembly, have started based on usage of probe microsocpy. In this project, we tried to orient uniaxially dipole moments in a polyoxymethylene chain by applying electric field in order to develop a novel actuator (molecular piston).
A benzene solution of polyoxymethylene was spread on water surface to prepare the polyoxymethylene monolayr. The monolayr was prepared by changing the concentration of spread solution, the surface pressure, the compression speed and the subphase temperature. The monolayr was transfeercl onto mica substrate to observe the morphology by an atomic force microscope. The morphologically homogeneous polyoxymethylene monolayr was prepared by the compression speed of 0.8 mm/s the surface pressure of 20 mN/m and at the subphase temperature of 293 K by using the solution with the concentration of 10^3 M.An isolated polyoxymethylene chain was obtained by scanning at stronger applied force. The expansion and contraction behaviors of polyoxymethylene chain will be investigated by applying electric field between cantilever and the substrate.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] Yushi Oishi et al.: "Construction of Two-dimensional Single Crystal of Fatty Acid by Two-step Cooling Crystallization Method" Chemistry Letters. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Effect of Ionic Repulsion among Hydrophilic Groups on Aggregation Structure of Fatty Acid Monolayer on the Water Surtau" Langmuir. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Morphology and Molecular Orientation and Structure of Langmuir-Blodgett Films of Chlorophyll a Studied by Atomic Force Microscopy" Journal of Chemical Society,Faraday Transactions. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Molecular Patterning of a Guanidinium / Orotate Mixed Mondayer through Molecular Recognition with Flavin Adenine Dinucleotide" Langmuir. 13. 519-524 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Atomic Force Microscopic Observation of Random Molecular Arrangement in Dialkyl Guanidinium Monolayer" Chemistry Letters. 857-858 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Two-dimensional Molecular Patterning through Molecular Recognition" Chemistry Letters. 411-412 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tisato Kajiyama and Yushi Oishi: "New Developments in Construction and Functions of Organic Thin Films" ELSEVIER SCIENCE B.V., 38 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Construction of Two-dimensional Single Crystal of Fatty Acid by Two-step Cooling Crystallization Method" Chemistry letters. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Effect of lonic Repulsion among Hydrophilic Groups on Aggregation Structure of Fatty Acid Monolayr on the Water Surface" Langmuir. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Morphology and Molecular Orientation and Structure of Langmuir-Blodgett Films of Chlorophill a Studied by Atomic Force Microscopy and UV-VIS and IR Spectrosecpies" Journal of Chemical Society, Faraday Transactions. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Molecular Patterning of a Guanidinium/Orotate Mixed Monolayr through Molecular Recognition with Flavin Adenine Dinucleotide" Langmuir. 13. 519-524 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Atomic Force Microscopic Observation of Random Molecular Arrangement in Dialkyl Guanidinium Monolayr" Chemistry Letters. 857-858 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al: "Two-dimensional Molecular Patterning through Molecular Recognition" Chemistry Letters. 411-412 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tisato Kajiyama and Yushi Oishi: "New Developments in Construction and Functions of Organic Thin Films" Elsevier Science B.V.(1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yushi Oishi et al.: "Construction of Two-dimensional Single Crystal of Fatty Acid by Two-step Cooling Crystallization Method" Chemistry Letters. (in press).

    • Related Report
      1996 Annual Research Report
  • [Publications] Yushi Oishi et al.: "Effect of Ionic Repulsion among Hydrophilic Groups on Aggregation Structure of Fatty Acid Monolayer on the Water Surface" Langmuir. (in press).

    • Related Report
      1996 Annual Research Report
  • [Publications] Yushi Oishi et al.: "Morphology and Molecular Orientation and Structure of Langmuir-Blodgert Films of Chlorophyll a Studied by Atomic Fone Microscopy and UV-VIS and IR spectroscopies" Journal of Chemical Society,Faraday Transactions. (in press).

    • Related Report
      1996 Annual Research Report
  • [Publications] Yushi Oishi et al.: "Molecular Pattening of a Guanidinium/Orotate Mixed Monolayer through Molecular Recognition with Flavin Adenine Dinucleotide" Langmuir. 13・3. 519-524 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Yushi Oishi et al.: "Atomic Force Microscopic Observation of Random Molecular Arrangement in Dialkyl Guanidinium Monolayer" Chemistry Letters. 857-858 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Yushi Oishi et al.: "Two-dimensional Molecular Patterning through Molecular Recognition" Chemistry Letters. 411-412 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tisato Kajiyama and Yushi Oishi: "New Developments in Construction and Functions of Organic Thin Films" ELSEVIER SCIENCE B.V., 38 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Oishi,et al.: "Exact Evaluation of Transfer Ratio of Monolayer Based on Area-creep Measurements" Langmuir. 11. 366-368 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Oishi,et al.: "Direct Observation of Edge Dislocation in Lignoceric Acid Monolayer Based on Atomic Force Microscopy" Chemistry Letters. 241-242 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Kajiyama and Y.Oishi: "Conformation and Packing of Chains in Ultrathin Polymer Films" Trends in Polymer Science. 3. 30-34 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Oishi,et al.: "Construction of Low-loss Optical Waveguide from Langmuir-Blodgett Films" SPIE Proceding. 2408. 121-128 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Oishi,et al.: "Molecular Aggregation State-photo polymerization Behavior Relationship of Lithium 10,12-Heptacosediynoate Monolayer" Langmuir. 11. 3536-3541 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Kajiyama,et al.: "Classification for Molecular Aggregation Structure of Monolayers on the water surface" Supramolecular Science.

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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