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Behavior Analysis of Sulfur in Environment by Means of Isotopic Measurement

Research Project

Project/Area Number 07680565
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionJapan Women's University

Principal Investigator

ARIKAWA Yoshiko  Japan Women's University, Faculty of Science, Professor, 理学部, 教授 (00060666)

Co-Investigator(Kenkyū-buntansha) IMAIZUMI Yukiko  Japan Women's University, Faculty of Science, Research Associate, 理学部, 助手 (10247091)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1996: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1995: ¥2,100,000 (Direct Cost: ¥2,100,000)
Keywordssulfur isotopic measurement / coal / petroleum / selenium / discrimination of sulfur source / infrared spectroscopy / Behavior Analysis / suspended particulate matter / 大気試料 / デルタ値 / 石炭硫黄 / 石油硫黄 / 海水硫酸塩硫黄 / 自然発生源 / 人為発生源
Research Abstract

To discriminate the sources of sulfur compounds in environment and discuss their behavior, isotopic measurement was carried out for the source sulfur which is generated by burning of fossil fuels and environmental sulfur which is included in air and suspended particulate matter. The results shows that sulfur in air is attributed to petroleum and sulfur in suspended particulate matter is attributed to coals. To collect air sample for the isotopic measurement, it takes about 50 days and is required to add absorbing solution once a week. In this project the new method for the collection of air sample was investigated by using activated carbon fiber. Sulfur dioxide in air sample was collected almost : it the efficiency of lO0%. This collection method is also able to shorten the collecting time. Simple qualitative analysis of inorganic components of suspended particulate matter was investigated by infrared spectroscopy. Sample is mixed with carbon and KBr and pressed before analysis. Several main inorganic components, sulfate, ammonium, silicate etc., are possible to be analyzed. Selenium isalso determined for coals and petrolenium to help the discussion to discriminate the sulfur sources. Coals contain more selenium than petroleum. The content of selenium in coals often shows more quantities than sulfur.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] Y.Arikawa: "SIMS Measurement of Sulfur Isotopic Composition in Enviromental Samples" Abstract of Ninth International Conference on Secondary Ion Mass Spectrometry. 233 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "Discrimination of Sulfur Source in Environment by Means of isotopic Measurement" J.Jap.Women'S Univ.,Fac.Science. 35-38 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "Isotopic Measurement of Sulfur and Lead in Environmental Samples by Secondary Ion Mass Spectrometry" Proceedings of 8th Pussian-Japan Joint Symposium on Analytical Chemistry. 106-107 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "SIMS Measurement of Sulfur Isotopic Composition in Environmental Samples" Secondary Ion Mass Spectrometry SIMS. 957-960 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "Investigation of Analytical Methods for Group Elements and their Application to Environmental Chemistry" Collection of Research Findings Commemorating The Iba Science Encouragement Award. 51-62 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "SIMS Measurement of Sulfur Isotopic Composition in Environmental Samples" Abstract of Ninth International Conference on Secondary Ion Mass Spectreometry. 233 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "Discrimination of Sulfur Source in Environment by Means of Isotopic Measurement" J.Jap.Women's Univ., Fac.Science. 35-38 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "Isotopic Measurement of Sulfur and Lead in Environmental Samples by Secondary Ion Mass Spectrometry" Proceedings of 8th Russian -Japan Joint Symposium on Analytical Chemistry. 106-107 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: "Investigation of Analytical Methods for Group Elements and Their Application to Environmental Chemistry" Collection of Research Findings Commemorating The Iba Science Encouragement Award. 51-62 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Arikawa: SIMS Measurement of Sulfur Isotopic Composition in Environmental Samples, Secondary Ion Mass Spectrometry SIMS. John Wiley & Sons, 957-960 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yoshiko Arikawa: "Isotopic Measurement of Sulfur and Lead in Environmental Samples by Secondary Ion Mass Spectrometry" Proc.RJS Analytical Chemistry. 8. 106-107 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Asahara, Y. Arikawa: "A Nickel Oxide Amperometric Detector in HPLC Separation of Thiol Compounds" Journal of Japan Womens Univ. Fac. Sci.3. 45-50 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 蟻川芳子・小沼憲子: "ヨウ素錯体生成に基づくホルムアルデヒドの高感度紫外吸光光度定量" 日本女子大学紀要 理学部. 3. 51-54 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I. Kubo, Y. ARIKAWA: "A Biosensor Based on Thiobacillus Thioparus for Measurement of Thiosulfate and Methanethiol" Can. J. Microbiol.41. 366-371 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 今泉幸子・蟻川芳子: "高圧酸素燃焼法による環境試料中ヒ素の水素化物発生原子吸光分析" 分析化学. 44. 101-105 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I. Karube, Y. Arikawa: "Biosensors for Environmental Control" Trends in Anal. Chem.14. 295-299 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Ikebukuro, Y. Arikawa: "Microbial Toxin Sensor System Using Bioluminescence" Denki Kagaku. 63. 1134-1137 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 蟻川芳子・桐村光太郎: "映画の中の化学" 丸善, 180 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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