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Gas separation by a Pd-plated alumina membrane for a small-scale emergency atmospheric detritiation system

Research Project

Project/Area Number 07808056
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear fusion studies
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

FUKADA Satoshi  Kyushu University, Faculty of Engineering, Research Associate, 工学部, 助手 (50117230)

Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1996: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1995: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsTritium / Permeation / Emergency detritiation system / Palladium / Hydrogen / Gas separation membrane / Desublimation / 緊急浄化システム
Research Abstract

I conducted an experiment of the hydrogen and water vapor separation by a Pd-plated alumina membrane for a small-scale emergency atmospheric detritiation system (ADS) and carried out numerical simulations of an integrated ADS.The following results were obtained.
(1) Water vapor and hydrogen separation characteristics were numerically simulated for the case of an integrated ADS partially replaced by the gas separation membrane. The counter-current flow was found to be the most promising among the cross flow, counter-current flow, co-current flow and complete mixing flow from a viewpoint of the gas separation efficiency of ADS.Water vapor preferentially permeated near the inlet of the gas separation membrane for the case of the three-component system of water vapor, tritium and nitrogen. The best cut condition was determined.
(2) The water vapor and hydrogen permeabilities of a cellulose-acetate membrane and a polyimido membrane agreed with values reported in the past elsewhere. This results shows a good performance of the experimental apparatus built here.
(3) Electroless Pd plating on Zr_2Fe particles was conducted for the investigation of the hydrogen permeation performance of a Pd film. The Pd plating was stable even in heating up to 800゚C.Hydrogen effectively permeated through the Pd film at around room temperature in oxygen free atmospheres, while hydrogen gas changed to water vapor on Pd film in atmospheres including oxygen.
(4) Mist formation occurred in gas streams at the critical supersaturation condition when water vapor permeating through the gas separation membrane of ADS was cooled for desublimation from the streams.
In order to establishe a small-scale emergency atmospheric detritiation system, the gas separation membrane, the electroless Pd plating technique and the vapor desublimation system was integrally investigated and each system component was proved to perform expected characteristics.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] 深田智他: "Frost formation under different gaseous atmosphere" Journal of Chemical Engineering of Japan. 28. 732-737 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 深田智他: "Analysis of multi-component permeation through gas separation membrane and its applications to atmosphere detritiation system" Fusion Technology. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 深田智他: "Recovery of low-concentration hydrogen from different gas streams with Zr_2Fe particle beds" Fusion Engineering and Design. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Satoshi Fukada et al.: "Frost formation under different gaseous atmosphere" Journal ov Chemical Engineering of Japan. Vol.28. 732-737 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Satoshi Fukada et al.: "Analysis of multi-component permeation through gas separation membrane and its applications to atmosphere detritiation system" Fusion Technology. (in printing). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Satoshi Fukada et al.: "Recovery of low-concentration hydrogen from different gas streams with Zr_2Fe particle beds" Fusion Engineering and Design. (in printing). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Satoshi Fukada et al.: "Frost formation under different gaseous atmosphere" Journal of Chemical Engineering of Japan. 28. 732-737 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] Satoshi Fukada et al.: "Analysis of multi-component permeation through gas separation membrane and is applications to atmosphere detritiation system" Fusion Technology. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Satoshi Fukada: "Recovery of low-concentration hydrogen from different gas streams with Zr_2Fe particle beds" Fusion Engineering and Design. (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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