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新高分子・ナノ組織体

Research Project

Project/Area Number 08246105
Research Category

Grant-in-Aid for Scientific Research on Priority Areas (A)

Allocation TypeSingle-year Grants
Research InstitutionThe Institute of Physical and Chemical Research (1999)
Kyushu University (1996-1998)

Principal Investigator

国武 豊喜  理化学研究所, 時空間機能材料研究グループ, グループディレクター(研究職) (40037734)

Co-Investigator(Kenkyū-buntansha) 高橋 成年  大阪大学, 産業科学研究所, 教授 (70029875)
中浜 精一  東京工業大学, 工学部, 教授 (90016410)
戸嶋 直樹  山口東京理科大学, 基礎工学部, 教授 (50011010)
東村 敏延  滋賀県立大学, 工学部, 教授 (20025860)
西出 宏之  早稲田大学, 理工学部, 教授 (90120930)
Project Period (FY) 1996 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥94,500,000 (Direct Cost: ¥94,500,000)
Fiscal Year 1999: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1998: ¥31,300,000 (Direct Cost: ¥31,300,000)
Fiscal Year 1997: ¥28,900,000 (Direct Cost: ¥28,900,000)
Fiscal Year 1996: ¥31,300,000 (Direct Cost: ¥31,300,000)
Keywords新高分子 / ナノ組織体 / 重合規制 / 精密重合 / キラル高分子 / 有機薄膜 / クラスター / 触媒 / リビング重合 / 立体選択性
Research Abstract

1)特定領域研究「新高分子・ナノ組織体」の3年間にわたる研究成果を、各班および研究分野ごとにまとめ、その内容を検討した。個々の総括班員の間で打ち合わせを行うと共に、全班員による検討会(総括班会議)を2回開催し、総括した。
2)これらの検討会により、研究内容についてチェック・アンド・レビューを実施し、プロジェクト研究として総括し、特定領域研究「新高分子・ナノ組織体」の研究成果を730ページの研究成果報告書としてまとめた。また、本研究成果を(社)高分子学会発行のPolymer Journal誌に"New Polymers and Their Nano-Organized Systems"特集号としてまとめ、第31巻11-2号として平成11年11月15日に発行した。さらに、別予算であるが、300余頁の英文学術書"Precision Polymers and Nano-Organized Systems"を講談社により平成12年2月に発行する。
3)上記の成果とりまとめの結果に基づき、特定領域研究「新高分子・ナノ組織体」の成果を公開するシンポジウムを、第7回公開シンポジウムとして平成11年10月25日に東京の日本化学会化学会館ホールで開催し、外国人2人を含む10件の講演を行った。また、別予算であるが「大学と科学」公開シンポジウムとして「分子がつくるナノの不思議」と題した公開シンポジウムを、平成11年11月29-30日に大阪の千里ライフサイエンスセンターで開催した。

Report

(4 results)
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (77 results)

All Other

All Publications (77 results)

  • [Publications] I.Ichinose and T.Kunitake: "Polymerization-Induced Adsorption : A Preparative Method of Ultrathin Polymer Films"Advanced Materials. 11(5). 413-415 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Yonezawa, H.Matsune, and T.Kunitake: "Layered Nanocomposite of Close-Packed Gold Nanoparticles and TiO_2 Gel Layers"Chemistry of Materials. 11(1). 33-35 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Lvov, K.Ariga, M.Onda, I.Ichinose, and T.kunitake: "A Careful Examination of the Adsorption Step in the Alternate Layer-by-Layer Assembly of Linear Polyanion and Polycation"Colloids & Surfaces. 146. 337-346 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] P.Lu, T.Teranishi, K.Asakura, M.Miyake, and N.Toshima: "Polymer-Protected Ni/Pd Bimetallic Nano-Clusters : Preparation, Characterization and Catalysis for Hydroganetion of Nitrobenzene"Lournal of Physical Chemistry B. 103(44). 9673-9682 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N.Toshima and K.Hirakawa: "Polymer-Protected Bimetallic Nanocluster Catalysts Having Core/Shell Structure for Accelerated Electron Transfer in Visible-Light-Induced Hydrogen Generation"Polymer Journal. 31(11-2). 1127-1132 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Shiraishi and N.Toshima: "Colloidal Silver Catalysts for Oxidation of Ethylene"Journal of Molecular Chatalysis A, Chemistry. 141(1-3). 187-192 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ishizone, K.Sugiyama, Y.Sakano, H.Mori, A.Hirao, and S.Nakahama: "Anionic Polymerizations of Perfluoroalkyl Methacrylates and Synthesis of Well-Defined ABC Triblock Copolymers of Methacrylates Containing Hydrophilic Hydrophobic and Perfluoroalkyl Groups"Polymer Journal. 31(11-2). 983-988 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Kobayashi, S.Okuyama, T.Ishizone, and Nakahama: "Stereospecific Anionic Polymerization of N,N-Dialkylacrylamides"Macromolecules. 32. 6466-6477 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Senshu, S.Yamashita, H.Mori, M.Itoh, A.Hirao, and S.Nakahama: "Time-Resolved Surface Rearrangements of Poly(2-hydroxyethyl methacrylate-block-isoprene) in Response to Enviornmental Change"Langmuir. 15. 1754-1762 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ishizone, K.Yoshimura, E.Yanase, and S.Nakahama: "Controlled Anionic Polymerization of tert-Butyl Acrylate with Diphenylmethylpotassium in the Presence of Triethylborane"Macromolecules. 32. 955-957 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Onitsuka, S.Yamamoto, and S.Takahashi: "A Novel Organometallic Macrocycle Composed of a Tetranuclear Palladium Acetylide"Angew. Chem. Int. Ed.. 38. 174-176 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Onitsuka, M.Fujimoto, N.Ohshiro, and S.Takahashi: "Convergent Route to Organometallic Dendrimers Composed of Platinum-Acetylide Units"Angew. Chem. Int. Ed.. 38. 689-692 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Takei, K.Onitsuka, and S.Takahashi: "Nonproportional Effects of Optical Purity of Chiral Aryl Isocyanide Monomers Possessing(d) or (I)-Methoxycarbonyl Groups on Induction of Screw-Sense in Poly(aryl isocyanide)s"Polymer Journal. 31. 1029-1032 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Takei, K.Yanai, K.Onitsuka, and S.Takahashi: "Screw-Sence Selective Polymerization of Aryl Isocyanides Initiated by Pd-Pt m-Ethynediyl Dinuclear Complex : Novel Method for Synthesis of Single-Hande dHelical Poly(isocyanide)s Using Block Copolymerization Technique"European Journal of Chemistry. 6(in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Nishide, M.Takahashi, J.Takashima, and E.Tsuchida: "Synthesis and Ferromagnetic Spin Alignment in Poly(4-oxyphenyl-1, 2-phenyleneethynylene)s"Polymer Journal. 31(11-2). 1171-1174 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Nishide, M.Takahashi, J.Takashima, Y-J. Pu, and E.Tsuchida: "Acyclic and Cyclic Di- and Tri(4-oxyphenyl-1, 2-phenyleneethynylene)s : Their Synthesis and Ferromagnetic Spin Interaction"Journal of Organic Chemistry. 64(20). 7375-7380 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Nishide, T.Maeda, K.Oyaizu, and E.Tsuchida: "High-Spin Polyphenoxyl Based on Poly(1, 4-phenyleneethynylene)"Journal of Organic Chemistry. 64(19). 7129-7134 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Takahashi, T.Nakazawa, E.Tsuchida, and H.Nishide: "Poly(4-diphenylaminium-1, 2-phenylenevinylene) : A High-Spin and Durable Polyradical"Macromolecules. 32(19). 6383-6385 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Terada, S.Kanaoka and T.Higashimura: "Living Cationic Polymerization of n-butyl Propenyl Ether"Journal of Polymer Science : Part A ; Polymer Chemistry. 32(1). 229-236 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] E.Tsuchida: "Synthesis of Semicrystalline Aromatic Poly(thioether thioether ketone)s (PTTK and PTBTK) and Their Copolymers with Ether Analogues"Macromolecules. 32(2). 315-321 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Aoki, K.Nakamura, K.Sanui, A.Kikuchi, T.Okano, Y.Sakurai, and N.Ogata: "Adenosine-Induced Changes of the Phase Transition of Poly(6-(acryloxymethyl)uracil) Aqueous Sollution"Polymer Journal. 31(11-2). 1185-1188 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Kunitake: "Functionality of Molecular Systems 2"Springer-Verlag. 245(31-42) (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 戸嶋 直樹: "季刊化学総説42「無機有機ナノ複合物質」"学会出版センター. 203(145-160) (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 蒲池 幹治、遠藤 剛: "ラジカル重合ハンドブック"エス・ティー・エス社. 759 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Ichinose: "Formation Process of Ultrathin Multilayer Films of Molybdenum Oxide by Altermate Adsorption of Octamolybdate and Linear Polycations" Langmuir. 14・1. 187-192 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Yonezawa: "Growth of Gold Nanoparticles on an Alogned Ammonium Surface" Adv.Mater. 10・5. 414-416 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ishizone: "Controlled Anionic Polymerization of teyi-Butyl Acrylate with Diphenylmethyl Anions in the Presence of Dialkylzine" Macromolecules. 31・25. 8706-8712 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Sugiyama: "Synthesis and Characierization of ABC Triblock Copolymers Containing Poly(perflouroalkyl methacrylate)Segments" Polymer Preprints,ACS. 39・2. 839-840 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Takahashi: "Screw-Sense-Selective Polymerization of Isocyanides Initiated by Organotransition Metal Complexes" Proc.Japan Acad.74・2. 25-30 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.Takei: "Polymerization of Aryl Isocyanides by Cyclopentadienylnickel-Alknyl Complexes" J.Organometal.559. 91-96 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Toshima: "Bimetallic Nanoparticles-Novel Materials Chemical and Applications" New J.Chem.22・11. 1179-1201 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Hashimoto: "Small-Angle X-ray Scattering Analysis of Polymer-Protected Platinum,Rhodium,and Platinum/Rhodium Colloidal Dispersions" J.Chem.Phys.109・13. 5627-5638 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Nishida: "Average Octet Radical Polymer" Angew.Chem.Int.Ed.37. 2400-2402 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Nishida: "High-Spin Polyphenoxyls Attached to Star-Shaped Polymres" J.Org.Chem.63. 7399-7407 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 緒方直哉: "膜による光学分割" 膜. 23・6. 280-287 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] A.Hashizume: "Radical Homo- and Copolymenzation of(2Z)-4-{1-(5-Methyl-2-pyrazolynyl)}-4-oxo-2-butenoic Acid,an Acyclic Z-1,2-Disubstituted Vinyl Compound" Macromolecules. 31・19. 6712-6714 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.P.Tonge: "ESR Measurements of kp for Styrene Free Radical Polymerization" Polymer. 39・11. 2305-2313 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] A.Haryono: "Synthesis and Nucleophilic Dealklation of Poly{alkyl-(4-(phenylthio)phenyl)-sulfonium Tritluoromethancesulfonate}s" Macromolecules. 31・4. 1202-1207 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Komatsu: "Monolayer Assemblies Made of Octopusporphyrins with Pyridinium Headgroups:Electron Transfer Reactions in Noncovalent Porphyrin-Quinone Platelets in Aqueous Media" J.Phys.Chem.B.102・35. 6759-6765 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 片岡一則: "Minimized Platelet Interaction with PolyHEMA-block-poly(4-bis(trimethylsilyl)-methylstrene)Hydrogel Showing Anomalously High Free Water Content" J.Biomater.Sci.,Polymer Ed.9・2. 111-129 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 鶴田禎二: "高分子の基礎科学(主として化学の側から)" 高分子増刊(日本の高分子化学技術史). 47・6. 66-69 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Sato: "A“Green"Route to Adipic Acid:Direct Oxidation of Cyclohexenes with 30% Hydrogen Peroxide" Science. 281. 1645-1646 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Bjorkman: "Synthesis of^<11>C/^<13>C-Labelled Prostacyclins" Acta Chem.Scand.52. 635- (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kanaoka: "The Propagating Species in Living Cationic Polymerization:Living Nature and Steric Structure of Polymers" Macromol.Symp.132. 75-84 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Toyoki Kunitake: "Functionality of Molecular Systems 2" Springer-Verlag, 245 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Toshima: "Nanostructured Materials in Biological and Artificial Systems" Elsevier.Oxford, 271 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Kamachi: "Controlled Radical Polymerization" American Chemical Society, 24 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Eishun Tsuchida: "Bood Substitutes(Present and Future Perspectives)" Elsevier(Amsterdam), 456 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] I.Ichinose: "A Surface Sol-Gel Process of TiO_2 and Other Metal Oxide Films with Molecular Precision" Chem.Mater.9・6. 1296-1298 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] I.Ichinose: "Controlled Growth of Polypyrrole ThinFilms by Polymerization Induced Adsorption" Chem.Lett.1998・1. 19-20 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Nakahama: "Polymerization of N,N-Dialkylacrylamides with Anionic Initiators Modified by Diethylzinc" J.of Maceomolecular Science,Pure Appl.Chem.A34・10. 1845-1855 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Ishizone: "Anionic Polymerization of Monomers Containing Functional Groups.10.Anionic Polymerization of N-Aryl-n-(4-vinylbenzylidene)amines" Macromolecules. 30. 6458-6466 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] F.Takei: "Polymerization of Aryl Isocyanides by Cyclopentadienylnickel-alkynyl Complexes" J.Organomet.Chem.in press (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Onitsuka: "Synthesis of Transition Metal-Poly(yne)Polymers Possessing Chiral Acetylene Bridges" Chem.Commun.in press (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Toshima: "Polymer-Protected Pt/Ru Bimetallic Cluster Catalysts for Visible-Light-Induced Hydrogen Generation from Water andElectron Transfer Dynamics" Appled Surface Science. 121/122. 534-537 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Wang: "Preparation of Pd-Pt Bimetallic Colloids with Controllable Core/Shell Structures" J.Phys.Chem.B. 101 27. 5301-5306 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Nishide: "Poly(1,2-phenylenevinylene)s Bearing Nitronyl Nitroxide and Galvinoxyl at the 4-Position: pi-Conjugated and Non-Kekule-Type Polyradicals with Triplet State" Macromolecules. 30. 3986-3991 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 西出宏之: "高スピンポリマー" 高分子. 46. 342-347 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Ogata: "A Marriage between Natural and Synthetic Polymers: Novel Temperature-Sensitive Bioconjugate" Journal of Controlled Release. 48・2-3. 149-155 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] A.Hashidzume: "Polymerization of an Azastyrene Derivative.2.Copolymerization of 2,6-Diisopropyl-N-methyleneaniline with Maleic Anhydride" Macromolecules. 30・14. 4232-4234 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Kataoka: "Minimized Platelet Interaction with Poly HEMA-block-4-bis(trimethylsilyl)methylstyrene Hydrogel" Journal of Biomaterials Sci.-Polym.Ed.9・2. 111-129 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 鶴田禎二: "高分子生成反応の開拓と解析" 化学と工業. 51・1. 6-8 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Sato: "Organic Solvent-and Halide-Free Oxidation of Alcohols with Aqueous Hydrogen Peroxide" J.Am.Chem.Soc.119. 12386-12387 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Suzuki: "Δ^7-Prostaglandin C_1.A Primary Metabolite of Antitumor Δ^7-Prostaglandin A_1 in the Sera" Tetrahedron. 53. 17009-17014 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] J.Lu: "Living Cationic Isomerization of β-Pinene 1.Inintiation with HCl-2-Chloroethyl Vinyl Ether Adduct/TiCl_3(OiPr)in Conjugattion with n-Bu_4NCl" Macromolecules. 30・1. 22-26 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] J.Lu: "Living Cationic Isomerization Polymerization of β-Pinene 2.Synthesis of Block and Random Copolymers with Styrene or p-Methylstyrene" Macromolecules. 30・1. 27-31 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Takemoto: "Functional Monomers and Polymers" Marcel Dekker,Inc., 552 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Kobayashi: "Catalysis in Precision Polymerization" John Wiley & Sons, 480 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yuri Lvov: "Formation of Ultrathin Multilayer and Hydrated Gel.from Montmorillonite and Linear Polycations" Langmuir. 12・12. 3038-3044 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Sugiyama: "Synthesis of End-functionalized Polymer by Means of Living Anionic Polymerization.Reaction of Anionic Living Polymers with Perfluoroalkyl Halides" Macromol.Chem.Phys.197. 3149-3165 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] F. Takei: "Screw-Sense-Selective Polymerization of Isocyanides by Dinuclear μ-Ethynediyl Complexes" Angew.Chem.Int.Ed.Engl.35・13/14. 1554-1556 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Yuan Wang: "Nanoscopic Naked Cu/Pd Powder as Air-Resistant Active Catalyst for Selective Hydration of Acrylonitrile to Acrylamide" J.Phys.Chem.100・50. 19533-19537 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Hiroyuki Nishide: "Poly(phenylenevinylene)-Attached Phenoxyl Radicals" J.Amer.Chem.Soc.118・40. 9695-9704 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y. Tabuchi: "Electrical Properties of Conductive Langmuir-Blodgett Film of Head-to-Tail Poly(3-hexylthiophene)" Thin Solid Filmn. 284/285. 636-639 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y. Kishimoto: "An Efficient Rhodium(I) Initiator for Stereospecific Living Polymerization of Phenylacetylenes" Macromolecules. 29. 5054-5055 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] J. Lu: "Living Cationic Isomerization Polymerization of β-Pinene. 1. Initiation with HCl-2-Chloroethyl Vinyl Ether Adduct/TiCl_3(OiPr) in Conjugation with nBu_4NCl" Macromolecules. 30・1. 22-26 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] T. Tsuruta: "Contemporary Topics in Polymeric Materials for Biomedical Applications" Advances in Polymer Science. 126. 1-51 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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