• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Synthesis and Application of Novel Organosulfur Compounds

Research Project

Project/Area Number 08304037
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

OKAZAKI Renji  The University of Tokyo, Graduate School of Science Professor, 大学院理学系研究科, 教授 (70011567)

Co-Investigator(Kenkyū-buntansha) FURUKAWA Naomichi  University of Tsukuba, Tsukuba Advanced Research Alliance Center Professor, 先端学際領域研究センター, 教授 (80015966)
NAKAYAMA Juzo  Saitama University, Faculty of Science Professor, 理学部, 教授 (90092022)
KATO Shinji  Gifu University, Faculty of Engineering Professor, 工学部, 教授 (40021589)
OGURA Katsuyuki  Chiba University, Faculty of Engineering Professor, 工学部, 教授 (60114253)
OHNO Atsuyoshi  Kyoto University, Institute for Chemical Research Professor, 科学研究所, 教授 (70027077)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥8,600,000 (Direct Cost: ¥8,600,000)
Fiscal Year 1997: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1996: ¥5,600,000 (Direct Cost: ¥5,600,000)
KeywordsSulfenic acid / Low-coordinated compound / High-coordinated compound / Asymmetric synthesis / Organic conductor / X-ray crystallography / 有機電導体 / X線結晶解析
Research Abstract

The following 4 subjects were studied. (1) syntheis of organosulfur compounds with novel structures, (2) development of new synthetic methods of organosulfur compounds, (3) synthesis of organic functional materials with sulfur, (4) synthesis of novel organosulfur compounds with bioactivity. The subject (1) : synthesis of stable sulfenic ans selenenic acids with a calixarene skeleton, sulfur-containing polycyclic silicon and germanium compounds, synthesis and X-ray crystallographic analysis of 1,2,5,6-tetrathiocin, synthesis and X-ray crystallography of aromatic trithiols, radical reactions of metalladithiolenes, synthesis of thionic acids and their metal complexes, synthesis and reactions of dithiiranes and their oxides, Pb-S double bond compounds with bulky groups, theoretical study on the stability of organosulfur compounds, hydrolysis of cyclic sulfinic acid esters, synthesis of stable pentacoordinated oxathietanes, hypervalent compounds having a S-Se bond. Tha subject (2) : asymmetric sulfimidation of organosulfur compounds, reactions of beta-sultams, synthetic application of chiral organosulfur compounds, new synthetic methods, of vinyl sulfides. The subject (3) : synthesis of new thienyl pyrroles, organic conductors containing sulfur, electoconductivity of naphthalenes containing sulfur, spin interactions of thienothiophenes, charge transfer complexes of bisethylenedithiotetrathiafulvalenes, selective complexation of silver ion by sulfur-containing macrocycles. The subvject (4) : ring transformation of organosulfur compounds, face selectivity in the electrophilic reactions of sulfinyl compounds, role of methane generating germs in Ni-SR complexes, synthesis of nucleosides containing thiophenes.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] N.Takeda: "Synthesis, structure, and Reactions of the First Rotational Isomers of Stable Thiobenzaldehydes,2,3,4-Tris[bis(trimethylsilyl)methy]thiobenzaldehydes" Chem.Eur.J.3. 62-69 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Yamazaki: "Stereospecific Redox Reaction Direeted by a Sulfinyl Group" Phosporus,Sulfur,and Silicon. 120. 445-446 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Akazome: "Enantioeric Recognition of Alkyl Phenyl Sulfoxides by Crystalline (R)-Phenylglycyl-(R)-phenylglycine" Tetrahedron. 52. 8315-8 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Murai: "Selenothioic Acid S-Esters: Synthesis, Characterization, and Trend for Stability" J.Am.Chem.Soc.119. 8592-8597 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Ishii: "Syntheses and chemical and Physical Properties of thiophenetriptycenes" J.Chem.Soc., Perkin 1. 1277-1286 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Z.Zan: "Exxlusice SIC-1,4-Addition Reaction In The Bromination of 2,5-Bis(Trimethylsily1) Thiophene Monooxide" Heterocycles. 48. 227-234 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Takeda: "Synthesis, Structure, and Reactions of the First Rotational Isomers of Stable Thiobenzaldehydes, 2,4,6-Tris [bis (trimethylsilyl) methyl] thiobenzaldehydes" Chem.Eur.J.3. 62-69 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Yamazaki: "Stereospecific Redox Reaction Directed by a Sulfinyl Group" Phosphorus, Sulfur, and Silicon. 120. 445-446 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Akazome: "Enantiomeric Recognition of Alkyl Phenyl Sulfoxides by Crystalline (R) -phenylglycyl- (R) -phenylglycine" Tetrahedron. 53. 8315-8322 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Murai: "Selnothioic Acid S-Esters : Synthesis, Characterization, and Trend for Stability" J.Am.Chem.Soc.119. 8592-8597 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Ishii: "Syntheses and Chemical and Physical Properties of Thiophenetriptycenes" J.Chem.Soc., Perkin. 1. 1277-1286 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Z.Zan: "Exclusive CIS-1,4-Addition Reaction In The Bromination of 2,5-Bis (trimethylsilyl) thiophene Monooxide" Heterocycles. 48. 227-234 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Takeda: "Synthesis, Structure, and Reactions of the First Rotational Isomers of Stable Thiobenzaldehydes, 2,4,6-Tris[bis(trimethylsilyl)nethyl] thiobenzaldehydes" Chem.Eur.J.3. 62-69 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Yamazaki: "Stereospecific Redox Reaction Directed by a Sulfinyl Group" Phosporus, Sulfur, and Silicon. 120. 445-446 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Akazome: "Enantiomeric Recognition of Alkyl Phenyl Sulfoxides by Crystalline (R) Phenylglycyl-(R)-phenylglicine" Terahedron. 53. 8315-8322 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Murai: "Selenothioic Acid S-Esters : Synthesis, Characterization, and Trend for Stability" J.Am.Chem.Soc.119. 8592-8597 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] A.Ishii: "Syntheses and Chemical and Physical Properties of Thiophenectriptycenes" J.Chem.Soc.,Perkin 1. 1277-1286 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Z.Zan: "Exclusive CIS-1,4-Addition Reaction In The Bromination of 2,5-Bis(Trimethylsilyl) Thiophene Monooxide" Heterocycles. 48. 227-234 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Watanabe: "Cycloaddition and Oxidation Reactions of a Stable Thioaldehyde,(2,4,6-Tri-t-butyl)thiobenzaldehyde." Bull.Chem.Soc.Jpn.69. 719-724 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Ohno: "NADP(P)^+-NAD(P)H Models.86.Nonsteric Stereochemistry in Hydride-Transfer to Sulfinylpyridinium Ion" Bull.Chem.Soc.Jpn.69. 1093-1098 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Tomori: "Practical Synthesis of(S)-3-(p-Nitrobenzyloxycabonylamino)pyrrolidine and Its Related Compounds from L-Aspartic Acid" Heterocycles. 44. 213-225 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Kato: "Thion(RCSOH),Selenon(RCSeOH),and Telluron(RCTeOH)Acids as Predominant Species" J.Am.Chem.Soc.118. 1262-1267 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Ishii: "First Synthesis Reactivities of Isolable Dithiiranes and Their-Oxides" Bull.Chem.Soc.Jpn.70. 印刷中 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Fujihara: "New Cyclic Dichalcogenonio-Selenuranes Induced by Transannular Multichalcogenides Participation" Tetrahedron. 52. 10375-10382 (1996)

    • Related Report
      1996 Annual Research Report

URL: 

Published: 1996-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi