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Element partitioning and diffusion in silicate high pressure phases

Research Project

Project/Area Number 08454151
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionUNIVERSITY OF TSUKUBA

Principal Investigator

KATO Takumi  Geoscience Inst., UNIVERSITY OF TSUKUBA Assoc.Prof., 地球科学系, 助教授 (90214379)

Co-Investigator(Kenkyū-buntansha) KUROSAWA Masanori  Geoscience Inst., UNIVERSITY OF TSUKUBA Lect., 地球科学系, 講師 (50272141)
SUENO Shigeho  Geoscience Inst., UNIVERSITY OF TSUKUBA Prof., 地球科学系, 教授 (30110513)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥7,500,000 (Direct Cost: ¥7,500,000)
Fiscal Year 1998: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1997: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1996: ¥5,000,000 (Direct Cost: ¥5,000,000)
KeywordsHigh pressure and high temperature experiments / Materials in the Earth's interior / High pressure phase minerals / 地球内部物性 / 地球内部 / 高圧鉱物 / 岩石物性 / 地球化学
Research Abstract

Chemical heterogeneity in the Earth's mantle is produced by the magmatic fractionation near the surface and is ultimately erased out by diffusion in minerals in the deep mantle conditions during subduction and convective circulation processes. Rheological properties of the mantle materials are also determined by the diffusion- controlled micro-mechanism. The major constituents of the lower mantle are orthorhombic silicate perovskite and magnesiowustite. Therefore, studies on diffusion of elements in these minerals provide important constraints on the processes in the lower mantle and, thereby, the whole mantle dynamics. However, properties of diffusion of these minerals are poorly known. We have made high pressure and high temperature experiments to observe reaction between MgSiO_3 perovskite and FeO wustite. Mode and extent of the reaction are used to estimate Mg-Fe inter-diffusion coefficients in ferromagnesian silicate perovskite and magnesiowustatite. High pressure and high temperature experiments have been made by an MA8 type high pressure apparatus driven by 3k ton. The most prominent process of the magmatic differentiation near the surface is the formation of the oceanic crust at the mid oceanic ridges. It returns back into the mantle at the subduction zones after some metamorphic and igneous differentiation. The fate of the subducted oceanic crust is an issue under considerable debate. However, it is conceivable that the chemical characteristics of the oceanic crust would be ultimately lost by the mechanical deformation (thinning) in the convective circulation and the diffusive dissolution. The bulk diffusion coefficients and element partitioning relations revealed in the present studies surely give important constraints on the geochemical evolution and mantle convection.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] T.KATO ET.AL.: "Diffusion processes in the Earth′s lower mantle minerals" Proceedings of The 5th NIRIM International Symposium. 5. 237-240 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.KATO ET.AL.: "In Situ X ray Observation of α-γ,and γ-Perovskite+Periclase Transitions in Mg2SiO4," The Review of High Pressure Science and Technology. 7. 119-121 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.KATO ET.AL.: "Melting experiments on the forsterite-pyrope system at 8 and 13.5 GPa" Physics of the Earth and Planetary Interiors,. 107. 97-102 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.KUBO,T.KATO,ET.AL.: "An in situ X-ray diffraction study of the a-b transformation kinetics of Mg2SiO4" GEOPHYS.RES.LETT.25. 695-698 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.KUBO,T.KATO ET.AL.: "Effect of water on the a-b transformation kinetics in San Carlos Olivine," SCIENCE. 281. 85-87 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.KATO,ET.AL.: "Element partitioning between silicate peroveskites and calsium-rich ultrabsic melt" Physics of the Earth and Planetary Ineteriors. 96. 201-207 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kato, D.Yamazaki, and Y.Deguchi: "Diffusion processes in the Earth's lower mantle minerals" Proceedings of The 5th NIRIM International Symposium on Advanced Materials (ISAM'98). 237-240 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kato, T.Kubo, H.Morishima, E.Ohtani, A.Suzuki, D.Yamazaki, K.Mibe, T.Kikegawa, O.Shimomura: "In Situ X ray Observation of alpha-gamma, and gamma-Perovskite+Periclase Transitions in Mg2SiO4" The Review of High Pressure Science and Technology Volume 7 (1998) Proceedings of International Conference-AIRAPT-16 & HPCJ-38-on High Pressure Science and Technology. 119-121 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kato, N.Nakata, E.Ohtani, and K.Onuma: "Melting experiments on the forsterite-pyrope system at 8 and 13.5 GPa" Physics of the Earth and Planetary Interiors. 107. 97-102 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kubo, E.Ohtani, T.Kato, H.Morishima, D.Yamazaki, A.Suzuki, K.Mibe, T.Kikegawa, and O.Shimomura: "An in situ X-ray diffraction study of the a-b transformation kinetics of Mg2SiO4" Geophys.Res.Lett.25. 695-698 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kubo, E.Ohtani, T.Kato, T.Shinmei, and K.Fujino: "Effect of water on the a-b transformation kinetics in San Carlos Olivine" Science. 281. 85-87 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kato, E.Ohtani, Y.Ito, and K.Onuma: "Element partitioning between silicate peroveskites and calsium-rich ultrabsic melt" Physics of the Earth and Planetary Ineteriors. 96. 201-207 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] D.Yamazaki, T.Kato, E.Ohtani, and M.Toriumi: "Grain growth rate of MgSiO3 perovskite and periclase under lower mantle conditions" Science. 274. 2052-2054 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.KATO, ET.AL.: "MELTING EXPERIMENTS ON FORSTERiTE-PYROPE SYSTEM AT 8 AND 13.5 GPa" PHySiCS OF THE EARTH AND PLANETARY INTERiORS. 107. 97-102 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.KATO, ET.AL.: "DiFFUSiON PROCESSES IN THE EARTHS LOWER MANTLE MiNERALS" PROC.5TH NiRiM INTERNATiONAL SYMP.(ISAN'98). 3. 237-240 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.KUBO, T.KATO, ET.AL.: "EFFECT OF WATER ON THE α-β TRANSFORMATiON KiNTiCS iN SC OLiViNE" SCiENCE. 281. 85-87 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Kurosawa et al.: "Design of a new sample chamber for proton microprobe analysis of mineral samples." Nuclear Instr.Meth.Phys.Res.B142. 599-605 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Kurosawa et al.: "Trace element analysis of mineral samples using PIXE" Ann.Rep.Tandem Accelerator Center, Univ.Tsukuba.66. 94-96 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Sasaki, M.Kurosawa et al.: "Characterization of a magnatic/meteoric transition Zone at the Kakkonda geothermal system, northeast Japan." Proc.9th Water-Rock Interaction. 483-486 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Takaknashi and T.Kato: "High pr essure melting of Mg2SiO4-(Mg,Ca)2Si2O6" Phys.Chem Minerals. (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Kato and N.Nak: "Melting relation of Mg2SiO4-Mg3Al2Si3O12" Phys.Earth Planet.Inter.(1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Kato et al.: "Element partitioning between silicate perovakites and calcic ultrabasic melt" Physics of the Earth and Planetary Interiors. 96. 201-207 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] D.Yamazaki,andT.Kato: "Grain Growth rates of MgSiOX_3 Perovskite and periclase under lower mantle conditions" Science. 274. 2052-2054 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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